GB647111A - Production of polymeric hydrocarbons - Google Patents
Production of polymeric hydrocarbonsInfo
- Publication number
- GB647111A GB647111A GB1510948A GB1510948A GB647111A GB 647111 A GB647111 A GB 647111A GB 1510948 A GB1510948 A GB 1510948A GB 1510948 A GB1510948 A GB 1510948A GB 647111 A GB647111 A GB 647111A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vapours
- production
- xylene
- condensation
- walls
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/025—Polyxylylenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/34—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
- C08G2261/342—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3424—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms non-conjugated, e.g. paracyclophanes or xylenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
In the production of polymeric p-phenylene ethylene by condensation of the vapours from the pyrolysis of p-xylene, condensation is effected in the presence of an organic liquid boiling above 250 DEG C. The liquid may be at 30-50 DEG C. and contain a substance known to polymerize vinyl compounds. In examples: (1) p-xylene is passed at 15 mm. through a cylindrical vessel at 940 DEG C., with a contact time of 0.309 sec., and the vapours led through a conduit heated to 100 DEG C., into a vessel containing dibutyl phthalate at 40 DEG C.; (2) and (3) benzoyl peroxide or azo-bis-isobutyronitrile is dissolved in the dibutyl phthalate; (4) the vapours obtained as in (1) are passed into a tube down the walls of which paraffin slowly flows, a film of polymer forming on the walls.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1510948A GB647111A (en) | 1948-06-04 | 1948-06-04 | Production of polymeric hydrocarbons |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1510948A GB647111A (en) | 1948-06-04 | 1948-06-04 | Production of polymeric hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
GB647111A true GB647111A (en) | 1950-12-06 |
Family
ID=10053195
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1510948A Expired GB647111A (en) | 1948-06-04 | 1948-06-04 | Production of polymeric hydrocarbons |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB647111A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2757146A (en) * | 1952-09-08 | 1956-07-31 | Du Pont | Pyrolysis polymers from p-methyl quaternary benzylammonium hydroxides |
US2777005A (en) * | 1953-10-14 | 1957-01-08 | Kellogg M W Co | Polymerizable cyclic compounds |
US3084146A (en) * | 1957-04-24 | 1963-04-02 | Minnesota Mining & Mfg | Aromatically unsaturated compounds and preparation thereof |
-
1948
- 1948-06-04 GB GB1510948A patent/GB647111A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2757146A (en) * | 1952-09-08 | 1956-07-31 | Du Pont | Pyrolysis polymers from p-methyl quaternary benzylammonium hydroxides |
US2777005A (en) * | 1953-10-14 | 1957-01-08 | Kellogg M W Co | Polymerizable cyclic compounds |
US3084146A (en) * | 1957-04-24 | 1963-04-02 | Minnesota Mining & Mfg | Aromatically unsaturated compounds and preparation thereof |
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