GB640836A - Improvements in or relating to the manufacture of interpolymers of styrene with unsaturated fatty acids and derivatives thereof - Google Patents
Improvements in or relating to the manufacture of interpolymers of styrene with unsaturated fatty acids and derivatives thereofInfo
- Publication number
- GB640836A GB640836A GB14502/48A GB1450248A GB640836A GB 640836 A GB640836 A GB 640836A GB 14502/48 A GB14502/48 A GB 14502/48A GB 1450248 A GB1450248 A GB 1450248A GB 640836 A GB640836 A GB 640836A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- interpolymers
- fatty acids
- acids
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F242/00—Copolymers of drying oils with other monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Interpolymers of styrene or alkyl or halogen nuclear-substituted styrene, with one or more unsaturated fatty acids or the partial ester or esters thereof are made by heating, e.g. below 250 DEG C. a mixture of the components, optionally dissolved in a volatile solvent, with or without superatmospheric pressure, in the presence of 1/2 to 5 per cent by weight of sulphur based on the fatty acid radicles. In a modification the fatty acid is fully esterified and the interpolymer saponified to the fatty acid or acids, or alcoholysed, e.g. in the presence of ethylene glycol, glycerol, sorbitol or pentaerythritol to yield partial esters. Styrenated oil-modified alkyd resins may be prepared by heating the interpolymers with polybasic acids, e.g. phthalic acid and polyhydric alcohols, e.g. glycerine. Specified fatty acids are those derived from linseed and castor oil; specified partial esters are mono- or di-glycerides of linseed oil; specified fully esterified fatty acids are linseed oil, china wood oil and dehydrated castor oil. The interpolymers may be converted into soaps and the alkali metal and ammonium soaps used as emulsifying agents. The styrenated oil-modified alkyd resins may be compounded with pigments, solvents, e.g. xylol, driers such as cobalt and lead naphthenates, water and stabilizing agents such as glue and casein, and used as coating or impregnating compositions or printing inks. Specifications 573,809, 573,835 and 616,044 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB285780X | 1948-05-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB640836A true GB640836A (en) | 1950-07-26 |
Family
ID=10277827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14502/48A Expired GB640836A (en) | 1948-05-28 | 1948-05-28 | Improvements in or relating to the manufacture of interpolymers of styrene with unsaturated fatty acids and derivatives thereof |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE489299A (en) |
| CH (1) | CH285780A (en) |
| FR (1) | FR987346A (en) |
| GB (1) | GB640836A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2736716A (en) * | 1951-02-07 | 1956-02-28 | Oxirane Ltd | Production of polymeric products from styrene and unsaturated fatty compounds |
| EP0373883A2 (en) * | 1988-12-12 | 1990-06-20 | Dainippon Ink And Chemicals, Inc. | Continuous mass polymerization process for making styrene copolymers |
| US5194525A (en) * | 1988-12-12 | 1993-03-16 | Dainippon Ink And Chemicals, Inc. | Continuous mass polymerization process for making styrene copolymers |
-
0
- BE BE489299D patent/BE489299A/xx unknown
-
1948
- 1948-05-28 GB GB14502/48A patent/GB640836A/en not_active Expired
-
1949
- 1949-05-27 FR FR987346D patent/FR987346A/en not_active Expired
- 1949-05-27 CH CH285780D patent/CH285780A/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2736716A (en) * | 1951-02-07 | 1956-02-28 | Oxirane Ltd | Production of polymeric products from styrene and unsaturated fatty compounds |
| EP0373883A2 (en) * | 1988-12-12 | 1990-06-20 | Dainippon Ink And Chemicals, Inc. | Continuous mass polymerization process for making styrene copolymers |
| EP0373883A3 (en) * | 1988-12-12 | 1990-12-27 | Dainippon Ink And Chemicals, Inc. | Continuous mass polymerization process for making styrene copolymers |
| US5194525A (en) * | 1988-12-12 | 1993-03-16 | Dainippon Ink And Chemicals, Inc. | Continuous mass polymerization process for making styrene copolymers |
Also Published As
| Publication number | Publication date |
|---|---|
| BE489299A (en) | |
| CH285780A (en) | 1952-09-30 |
| FR987346A (en) | 1951-08-13 |
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