[go: up one dir, main page]

GB631457A - An improved process for the catalytic synthesis of hydrocarbons - Google Patents

An improved process for the catalytic synthesis of hydrocarbons

Info

Publication number
GB631457A
GB631457A GB23324/46A GB2332446A GB631457A GB 631457 A GB631457 A GB 631457A GB 23324/46 A GB23324/46 A GB 23324/46A GB 2332446 A GB2332446 A GB 2332446A GB 631457 A GB631457 A GB 631457A
Authority
GB
United Kingdom
Prior art keywords
oxides
metals
mgo
bivalent
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23324/46A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Priority to GB23324/46A priority Critical patent/GB631457A/en
Publication of GB631457A publication Critical patent/GB631457A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/10—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20—Carbon compounds
    • C07C2527/232—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/24—Nitrogen compounds
    • C07C2527/25—Nitrates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Hydrocarbons are produced by contacting a mixture of carbon monoxide and hydrogen in synthesis proportions and under hydrocarbon synthesis conditions of temperature and pressure with a catalyst comprising a trivalent iron oxide and at least an equimolecular proportion of one or more oxides of one or more bivalent metals other than iron which will form a spinel type compound with said iron oxide or products obtained by reducing such mixtures. Suitable bivalent metals are Mg, Zn, Mn, Cd, alkaline earth metals, Be and Cu. With an excess of a bivalent component of low bulk density such as MgO, catalysts suitable for fluidized operation are obtained. Promoters, such as compounds of K, Na, Li, Ba and Ca, and oxides of Al, Si, Cu, Mn or Cr, and stabilizers such as oxides of metals of the right-hand side of Groups 1, 2 and 3, especially CuO, may be present. The oxides may be coprecipitated, dried, filled and roasted, and, if desired, reduced in hydrogen, and sintered. Conventional synthesis conditions of 450-800 DEG F., 3-25 atmos., H2 : CO ratios of 0.6-3 : 1, and space velocities of 100-2500 v./v./hr. are used. Examples compare the results of using Fe2O3 + MgO, ZnO or CaO with those of magnetite, and of a preferred catalyst: MgO 54, Fe2O3 40, CuO 5, and K2O 1 per cent with iron oxides alone or in various carriers with fixed bed or fluidized operation.
GB23324/46A 1946-08-06 1946-08-06 An improved process for the catalytic synthesis of hydrocarbons Expired GB631457A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB23324/46A GB631457A (en) 1946-08-06 1946-08-06 An improved process for the catalytic synthesis of hydrocarbons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB23324/46A GB631457A (en) 1946-08-06 1946-08-06 An improved process for the catalytic synthesis of hydrocarbons

Publications (1)

Publication Number Publication Date
GB631457A true GB631457A (en) 1949-11-03

Family

ID=10193765

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23324/46A Expired GB631457A (en) 1946-08-06 1946-08-06 An improved process for the catalytic synthesis of hydrocarbons

Country Status (1)

Country Link
GB (1) GB631457A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0071770A2 (en) * 1981-08-05 1983-02-16 Schering Aktiengesellschaft Catalyst and process for the production of olefins, especially linear alpha-olefins, from synthesis gas
EP0191205A1 (en) * 1983-12-14 1986-08-20 Exxon Research And Engineering Company Cobalt-promoted fischer-tropsch catalysts
WO2005049765A1 (en) * 2003-11-20 2005-06-02 Sasol Technology (Pty) Limited The use of a source of chromium with a precipitated catalyst in a fischer-tropsch reaction
EP1889660A1 (en) * 2005-05-09 2008-02-20 Toyo Boseki Kabushiki Kasisha Ozone-decomposing agent

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0071770A2 (en) * 1981-08-05 1983-02-16 Schering Aktiengesellschaft Catalyst and process for the production of olefins, especially linear alpha-olefins, from synthesis gas
EP0071770A3 (en) * 1981-08-05 1983-08-17 Schering Aktiengesellschaft Catalyst and process for the production of olefins, especially linear alpha-olefins, from synthesis gas
EP0191205A1 (en) * 1983-12-14 1986-08-20 Exxon Research And Engineering Company Cobalt-promoted fischer-tropsch catalysts
WO2005049765A1 (en) * 2003-11-20 2005-06-02 Sasol Technology (Pty) Limited The use of a source of chromium with a precipitated catalyst in a fischer-tropsch reaction
US7598295B2 (en) 2003-11-20 2009-10-06 Sasol Technology (Pty) Limited Use of a source of chromium with a precipitated catalyst in a Fischer-Tropsch reaction
EP1889660A1 (en) * 2005-05-09 2008-02-20 Toyo Boseki Kabushiki Kasisha Ozone-decomposing agent
EP1889660A4 (en) * 2005-05-09 2011-09-21 Toyo Boseki Ozone-decomposing agent

Similar Documents

Publication Publication Date Title
US3925498A (en) Oxidative dehydrogenation process
US3450788A (en) Dehydrogenation process
US2438584A (en) Preparation of nonsintered iron catalyst
US3270080A (en) Production of unsaturated compounds
US3686347A (en) Oxidative dehydrogenation of organic compounds
GB1284464A (en) Process for the manufacture of isoprene from isoamylenes and catalyst therefore
US3951869A (en) Modified zinc ferrite oxidative dehydrogenation catalysts
JPH05228368A (en) Method for producing and using dehydration catalyst
US2456072A (en) Conversion of hydrocarbons in the presence of a catalyst and calcium oxide together with steam and/or carbon dioxide
US3527834A (en) Conversion of butene-2 to butene-1
GB1283369A (en) Catalysts containing antimony oxide and process for their production
GB631457A (en) An improved process for the catalytic synthesis of hydrocarbons
CN103721735A (en) Catalyst precursor and catalyst used for selective oxidative dehydrogenation
US2457719A (en) Preparation of extruded iron oxide catalysts
US4010114A (en) Oxidative dehydrogenation catalyst
GB1375226A (en)
GB683722A (en) Ferromagnetic materials
GB1357335A (en) Hydrogen
GB994170A (en) Catalytic dehydrogenation
US3291756A (en) Catalytic dehydrogenation
US2567296A (en) Preparation of a fischer-tropsch catalyst
US2431427A (en) Alumina base dehydrogenation catalyst
GB1266586A (en)
US2819283A (en) Process of producing hydrocarbons
US2991321A (en) Dehydrogenation in the presence of oxygen and bismuth phosphate