GB611642A - An improved manufacture of composite materials containing hydrocarbon copolymers and bituminous materials - Google Patents
An improved manufacture of composite materials containing hydrocarbon copolymers and bituminous materialsInfo
- Publication number
- GB611642A GB611642A GB1340246A GB1340246A GB611642A GB 611642 A GB611642 A GB 611642A GB 1340246 A GB1340246 A GB 1340246A GB 1340246 A GB1340246 A GB 1340246A GB 611642 A GB611642 A GB 611642A
- Authority
- GB
- United Kingdom
- Prior art keywords
- olefine
- paper
- compositions
- bituminous
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 6
- 229920001577 copolymer Polymers 0.000 title abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- 239000002131 composite material Substances 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 125000003118 aryl group Chemical group 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 2
- 235000019738 Limestone Nutrition 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 238000007792 addition Methods 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 239000006028 limestone Substances 0.000 abstract 2
- 239000003208 petroleum Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 238000004078 waterproofing Methods 0.000 abstract 2
- KEIFWROAQVVDBN-UHFFFAOYSA-N 1,2-dihydronaphthalene Chemical compound C1=CC=C2C=CCCC2=C1 KEIFWROAQVVDBN-UHFFFAOYSA-N 0.000 abstract 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- 229920002367 Polyisobutene Polymers 0.000 abstract 1
- 239000005030 aluminium foil Substances 0.000 abstract 1
- 239000010425 asbestos Substances 0.000 abstract 1
- 239000010426 asphalt Substances 0.000 abstract 1
- 238000003490 calendering Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 239000011280 coal tar Substances 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 239000002385 cottonseed oil Substances 0.000 abstract 1
- 235000012343 cottonseed oil Nutrition 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000011888 foil Substances 0.000 abstract 1
- 239000011491 glass wool Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011810 insulating material Substances 0.000 abstract 1
- 239000003350 kerosene Substances 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- JYVLIDXNZAXMDK-UHFFFAOYSA-N methyl propyl carbinol Natural products CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000011490 mineral wool Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 abstract 1
- 239000011295 pitch Substances 0.000 abstract 1
- 229920000196 poly(lauryl methacrylate) Polymers 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- QROGIFZRVHSFLM-UHFFFAOYSA-N prop-1-enylbenzene Chemical class CC=CC1=CC=CC=C1 QROGIFZRVHSFLM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052895 riebeckite Inorganic materials 0.000 abstract 1
- 239000004576 sand Substances 0.000 abstract 1
- 239000011269 tar Substances 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 239000011276 wood tar Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/61—Bitumen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
- C10C3/02—Working-up pitch, asphalt, bitumen by chemical means reaction
- C10C3/026—Working-up pitch, asphalt, bitumen by chemical means reaction with organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/35—Polyalkenes, e.g. polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Thermoplastic compositions are made by homogeneously compounding a bituminous material and a copolymer of intrinsic viscosity above 0.5 of an aliphatic mono-olefine and an aromatic mono-olefine, the aromatic mono-olefine content of the copolymer being from 20-80 per cent, prepared at a temperature below - 50 DEG C. in the presence of a Friedel-Crafts catalyst. The preferred aliphatic mono-olefine is isobutylene, others specified are isopentene and a pentene obtained by dehydration of sec.-amyl alcohol. Styrene is the preferred aromatic mono-olefine, others are indene, methyl styrenes and dihydro-naphthalene. Listed bituminous materials include natural and petroleum asphalts, cracking coil tars, coal tar, wood tar and pitches. Asphalts which have been refined, e.g. by distillation, steam reduction, air blown and oxidized, may also be used. If desired, the bituminous material may be dissolved in kerosene, toluene, aromatic petroleum solvents, benzene, petroline or in aqueous emulsion. The composition may also include polymeric materials not normally compatible with asphalt, e.g. polyisobutylene, polymethyl and polylauryl methacrylates. Optional additions include clay, sand, limestone dust, limestone or coarser mineral aggregates, asbestos, hair, cotton and linseed oil. The addition of the copolymer to bituminous material improves its toughness, flexibility, oxidation resistance, low temperature flexibility and reduces the cold flow. The compositions may be calendered, extruded or cast or used for weather-resisting coating compositions, being applied in solution in a volatile solvent or in a heat-softened condition and, if desired, covered with roofing grit. They may be used for water-proofing concrete, e.g. building foundations, paving roads, caulking purposes, e.g. building joints and expansion joints in concrete surfaces, for water-proofing single sheets of paper, bonding sheets of paper together or for bonding paper to metal foils, e.g. aluminium foil (see Group VIII). Insulating material, e.g. rock and glass wool, may be bonded to craft paper with the compositions. They may also be used for lining storage battery containers and for the preparation of printing inks. Specification 513,521 is referred to.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1340246A GB611642A (en) | 1946-05-02 | 1946-05-02 | An improved manufacture of composite materials containing hydrocarbon copolymers and bituminous materials |
| FR927636D FR927636A (en) | 1946-05-02 | 1946-06-04 | Process for the preparation of thermoplastic products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1340246A GB611642A (en) | 1946-05-02 | 1946-05-02 | An improved manufacture of composite materials containing hydrocarbon copolymers and bituminous materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB611642A true GB611642A (en) | 1948-11-02 |
Family
ID=10022307
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1340246A Expired GB611642A (en) | 1946-05-02 | 1946-05-02 | An improved manufacture of composite materials containing hydrocarbon copolymers and bituminous materials |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR927636A (en) |
| GB (1) | GB611642A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2688005A (en) * | 1952-04-30 | 1954-08-31 | Standard Oil Dev Co | Cushion for railroad ties comprising a copolymer of styrene and isobutylene, a bituminous material, and a fibrous material |
| US2714568A (en) * | 1952-02-27 | 1955-08-02 | Exxon Research Engineering Co | Asphalt laminate |
| US3228896A (en) * | 1961-05-16 | 1966-01-11 | Phillips Petroleum Co | Method of making microporous polyolefin articles and product therefrom |
| US3505260A (en) * | 1967-09-11 | 1970-04-07 | Phillips Petroleum Co | Asphalt-polyolefin fiber blends |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2802798A (en) * | 1954-07-19 | 1957-08-13 | Exxon Research Engineering Co | High grade paving asphalt and method of making same |
| US2935486A (en) * | 1955-07-05 | 1960-05-03 | Exxon Research Engineering Co | Asphalt, isobutylene-styrene copolymer, hydrocarbon oil adhesive for laminates |
| US2889296A (en) * | 1955-07-15 | 1959-06-02 | Exxon Research Engineering Co | Process for preparing high quality asphalt-copolymer compositions |
-
1946
- 1946-05-02 GB GB1340246A patent/GB611642A/en not_active Expired
- 1946-06-04 FR FR927636D patent/FR927636A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2714568A (en) * | 1952-02-27 | 1955-08-02 | Exxon Research Engineering Co | Asphalt laminate |
| US2688005A (en) * | 1952-04-30 | 1954-08-31 | Standard Oil Dev Co | Cushion for railroad ties comprising a copolymer of styrene and isobutylene, a bituminous material, and a fibrous material |
| US3228896A (en) * | 1961-05-16 | 1966-01-11 | Phillips Petroleum Co | Method of making microporous polyolefin articles and product therefrom |
| US3505260A (en) * | 1967-09-11 | 1970-04-07 | Phillips Petroleum Co | Asphalt-polyolefin fiber blends |
Also Published As
| Publication number | Publication date |
|---|---|
| FR927636A (en) | 1947-11-04 |
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