GB605442A - Improvements in or relating to the preparation of diaryl mercury compounds - Google Patents
Improvements in or relating to the preparation of diaryl mercury compoundsInfo
- Publication number
- GB605442A GB605442A GB12736/44A GB1273644A GB605442A GB 605442 A GB605442 A GB 605442A GB 12736/44 A GB12736/44 A GB 12736/44A GB 1273644 A GB1273644 A GB 1273644A GB 605442 A GB605442 A GB 605442A
- Authority
- GB
- United Kingdom
- Prior art keywords
- product
- textiles
- organic
- inhibitor
- mercuric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 diaryl mercury compounds Chemical class 0.000 title 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical class C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 4
- 239000003112 inhibitor Substances 0.000 abstract 4
- 239000004753 textile Substances 0.000 abstract 4
- JCIIKRHCWVHVFF-UHFFFAOYSA-N 1,2,4-thiadiazol-5-amine;hydrochloride Chemical compound Cl.NC1=NC=NS1 JCIIKRHCWVHVFF-UHFFFAOYSA-N 0.000 abstract 2
- 235000015165 citric acid Nutrition 0.000 abstract 2
- 230000008021 deposition Effects 0.000 abstract 2
- 230000002070 germicidal effect Effects 0.000 abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 2
- 235000014655 lactic acid Nutrition 0.000 abstract 2
- 229940100892 mercury compound Drugs 0.000 abstract 2
- 150000002731 mercury compounds Chemical class 0.000 abstract 2
- 229940096826 phenylmercuric acetate Drugs 0.000 abstract 2
- 125000003944 tolyl group Chemical group 0.000 abstract 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 abstract 1
- RRFGSWMKSSCUSU-UHFFFAOYSA-M 2-hydroxypropanoate;phenylmercury(1+) Chemical compound CC(O)C(=O)O[Hg]C1=CC=CC=C1 RRFGSWMKSSCUSU-UHFFFAOYSA-M 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000003385 bacteriostatic effect Effects 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- HWMTUNCVVYPZHZ-UHFFFAOYSA-N diphenylmercury Chemical compound C=1C=CC=CC=1[Hg]C1=CC=CC=C1 HWMTUNCVVYPZHZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 230000000855 fungicidal effect Effects 0.000 abstract 1
- 230000001408 fungistatic effect Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000004310 lactic acid Substances 0.000 abstract 1
- 239000010985 leather Substances 0.000 abstract 1
- 229940049920 malate Drugs 0.000 abstract 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 230000002028 premature Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
- C07F3/12—Aromatic substances containing mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Organic mercury compounds having germicidal and fungicidal properties are prepared by treating an organic mercury compound of the formula RHgX, where R is an aryl group and X is an anion of an organic or inorganic acid, with an alkylolamine in the presence of a decomposition inhibitor. Preferred inhibitors which are used are organic carboxylic acids such as lactic and citric acids or salts thereof. The function of the inhibitor is to prevent the premature deposition of the products of the invention which are insoluble. The effect of the inhibitor may be overcome by heat and this property may be used to cause the deposition of the product of the invention in situ in fibrous materials such as textiles, fibres, yarns, paper, leather, films and sheets and to render such materials permanently germicidal, bacteristatic and fungistatic. Starting materials of the formula RHgX which may be used include phenyl mercuric acetate, phenyl mercuric lactate, tolyl mercuric malate, and tolyl mercuric butyrate. Alkylolamines mentioned include mono-, di- and tri-ethanolamines and mono-isopropanolamine. The reaction is carried out by merely mixing the ingredients in aqueous solution. In examples: (1) phenyl mercuric acetate, triethanolamine and lactic acid are mixed, and the product diluted with water containing citric acid to form a product suitable for treating textiles which yields diphenyl mercury on heating; (2)-(4) the product of example (1) is applied to textiles in admixture with other textile treating agents.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US605442XA | 1943-06-04 | 1943-06-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB605442A true GB605442A (en) | 1948-07-23 |
Family
ID=22030161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12736/44A Expired GB605442A (en) | 1943-06-04 | 1944-07-04 | Improvements in or relating to the preparation of diaryl mercury compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB605442A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3033704A (en) * | 1959-05-19 | 1962-05-08 | Armour & Co | Rendering fabric anti-static, soft, and microorganisms resistant |
-
1944
- 1944-07-04 GB GB12736/44A patent/GB605442A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3033704A (en) * | 1959-05-19 | 1962-05-08 | Armour & Co | Rendering fabric anti-static, soft, and microorganisms resistant |
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