GB541938A - Improvements in or relating to varnish compositions - Google Patents
Improvements in or relating to varnish compositionsInfo
- Publication number
- GB541938A GB541938A GB1044840A GB1044840A GB541938A GB 541938 A GB541938 A GB 541938A GB 1044840 A GB1044840 A GB 1044840A GB 1044840 A GB1044840 A GB 1044840A GB 541938 A GB541938 A GB 541938A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenol
- styrene
- oil
- drying
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- 239000002966 varnish Substances 0.000 title abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 4
- 238000001035 drying Methods 0.000 abstract 4
- 238000010438 heat treatment Methods 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 239000003921 oil Substances 0.000 abstract 3
- 235000019198 oils Nutrition 0.000 abstract 3
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 239000005049 silicon tetrachloride Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 abstract 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical class C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 abstract 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 abstract 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000292 calcium oxide Substances 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000057 synthetic resin Substances 0.000 abstract 1
- 239000002383 tung oil Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F5/00—Obtaining drying-oils
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
541,938. Condensation products. LILLEY, H. S., and IMPERIAL CHEMICAL INDUSTRIES, Ltd. June 17, 1940, No. 10448. [Class 2 (iii)] Synthetic resins are prepared by heating together a phenol, an aromatic hydrocarbon carrying a vinyl group attached directly to the aromatic nucleus, and a drying or semi-drying oil. Specified phenols are phenol, p-cresol, p-tertiarybutyl phenol, and m-5-xylenol, and specified hydrocarbons are styrene and its homologues and vinyl naphthalenes. The reaction may be conducted either in the presence or absence of a volatile solvent, and in the presence of a catalyst known to accelerate the polymerization of styrene and having an acid re-action or being capable of splitting off acid, e.g. tin or silicon tetrachloride or borofluoro acetic acid. The resins may be admixed with solvents, thinners, driers; plasticizers or pigments and the resulting compositions used as varnishes. The initial re-action products may be subjected to a further heat treatment in the presence of an additional quantity of drying or semi-drying oil. In examples, styrene, phenol and either (a) tung oil and tin tetrachloride or (b) bodied linseed oil and silicon tetrachloride, are heated together with stirring, and the resulting mass is de-coloured by heating with calcium oxide and allowed to settle. The clear liquid is decanted, heated to drive off excess phenol and styrene, and more oil is added. The temperature is then increased and the heating continued until a product of the desired viscosity is obtained, which may be thinned with white spirit. Specification 456,359 is referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1044840A GB541938A (en) | 1940-06-17 | 1940-06-17 | Improvements in or relating to varnish compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1044840A GB541938A (en) | 1940-06-17 | 1940-06-17 | Improvements in or relating to varnish compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB541938A true GB541938A (en) | 1941-12-18 |
Family
ID=9968045
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1044840A Expired GB541938A (en) | 1940-06-17 | 1940-06-17 | Improvements in or relating to varnish compositions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB541938A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2586652A (en) * | 1946-02-15 | 1952-02-19 | Sherwin Williams Co | Manufacture of interpolymers of styrene with polyhydric alcoholic mixed esters and of coating compositions obtained therefrom |
| DE951770C (en) * | 1942-07-28 | 1956-10-31 | Lewis Berger & Sons Ltd | Process for the production of coating resins from styrene and mixed esters of polyhydric alcohols |
-
1940
- 1940-06-17 GB GB1044840A patent/GB541938A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE951770C (en) * | 1942-07-28 | 1956-10-31 | Lewis Berger & Sons Ltd | Process for the production of coating resins from styrene and mixed esters of polyhydric alcohols |
| US2586652A (en) * | 1946-02-15 | 1952-02-19 | Sherwin Williams Co | Manufacture of interpolymers of styrene with polyhydric alcoholic mixed esters and of coating compositions obtained therefrom |
| DE975683C (en) * | 1946-02-15 | 1962-05-03 | Lewis Berger & Sons Ltd | Process for the preparation of polymerization products |
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