GB455540A - Improvements in or relating to agents for stabilizing aqueous suspensions or emulsions and for increasing the hydrophilic capacity thereof and a process of producing same - Google Patents
Improvements in or relating to agents for stabilizing aqueous suspensions or emulsions and for increasing the hydrophilic capacity thereof and a process of producing sameInfo
- Publication number
- GB455540A GB455540A GB1522/36A GB152236A GB455540A GB 455540 A GB455540 A GB 455540A GB 1522/36 A GB1522/36 A GB 1522/36A GB 152236 A GB152236 A GB 152236A GB 455540 A GB455540 A GB 455540A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fatty acids
- esters
- esterified
- agents
- increasing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title abstract 2
- 230000000087 stabilizing effect Effects 0.000 title abstract 2
- 239000007900 aqueous suspension Substances 0.000 title 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 4
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 4
- 150000002148 esters Chemical class 0.000 abstract 4
- 229930195729 fatty acid Natural products 0.000 abstract 4
- 239000000194 fatty acid Substances 0.000 abstract 4
- 150000004665 fatty acids Chemical class 0.000 abstract 4
- 235000019198 oils Nutrition 0.000 abstract 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 235000011187 glycerol Nutrition 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 239000011591 potassium Substances 0.000 abstract 2
- 238000000746 purification Methods 0.000 abstract 2
- 239000000344 soap Substances 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- 235000020238 sunflower seed Nutrition 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/34—Higher-molecular-weight carboxylic acid esters
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/01—Other fatty acid esters, e.g. phosphatides
- A23D7/013—Spread compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Esters of higher fatty acids and polyhydric alcohols containing at least one unsubstituted hydroxy group are treated, e.g. by oxidation or polymerization, to introduce further hydrophile groups. This may be done either before or after the synthesis of the esters and in the former case there may be an intermediate purification process. For example, sunflower seed oil is blown with air at 175 DEG C. until its viscosity is doubled. The oxidized oil is saponofied and the fatty acids isolated. These are then esterified with a large excess of anhydrous glycerine at 180 DEG C. using potassium soap as catalyst.ALSO:Agents for stabilizing aqueous emulsions or suspensions and increasing their hydrophilic capacity comprise esters of higher fatty acids and polyhydric alcohols having at least one unsubstituted hydroxy group, into which additional hydrophile groups have been introduced, e.g. by oxidation or polymerization. The said additional groups may be introduced either before or after the synthesis of the esters and in the former case the substances may undergo an intermediate purification before being esterified. According to an example sunflower seed oil is heated to 175 DEG C, and air is blown through until its viscosity is doubled. The oxidized oil is saponified and the fatty acids isolated. These are then esterified with a large excess of anhydrous glycerine at 180 DEG C., using potassium soap as catalyst.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1522/36A GB455540A (en) | 1936-01-17 | 1936-01-17 | Improvements in or relating to agents for stabilizing aqueous suspensions or emulsions and for increasing the hydrophilic capacity thereof and a process of producing same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1522/36A GB455540A (en) | 1936-01-17 | 1936-01-17 | Improvements in or relating to agents for stabilizing aqueous suspensions or emulsions and for increasing the hydrophilic capacity thereof and a process of producing same |
Publications (1)
Publication Number | Publication Date |
---|---|
GB455540A true GB455540A (en) | 1936-10-22 |
Family
ID=9723440
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1522/36A Expired GB455540A (en) | 1936-01-17 | 1936-01-17 | Improvements in or relating to agents for stabilizing aqueous suspensions or emulsions and for increasing the hydrophilic capacity thereof and a process of producing same |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB455540A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE752917C (en) * | 1937-01-19 | 1952-11-24 | Herbert Schou | Process for the production of dispersants for the production of plastic oil and fat dispersions |
-
1936
- 1936-01-17 GB GB1522/36A patent/GB455540A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE752917C (en) * | 1937-01-19 | 1952-11-24 | Herbert Schou | Process for the production of dispersants for the production of plastic oil and fat dispersions |
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