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GB440004A - An improved method of refining selenium - Google Patents

An improved method of refining selenium

Info

Publication number
GB440004A
GB440004A GB3745/35A GB374535A GB440004A GB 440004 A GB440004 A GB 440004A GB 3745/35 A GB3745/35 A GB 3745/35A GB 374535 A GB374535 A GB 374535A GB 440004 A GB440004 A GB 440004A
Authority
GB
United Kingdom
Prior art keywords
selenium
alkali
impurities
selenate
selenite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3745/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bolidens Gruvaktiebolag
Original Assignee
Bolidens Gruvaktiebolag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bolidens Gruvaktiebolag filed Critical Bolidens Gruvaktiebolag
Publication of GB440004A publication Critical patent/GB440004A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B19/00Selenium; Tellurium; Compounds thereof
    • C01B19/02Elemental selenium or tellurium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/60Optical properties, e.g. expressed in CIELAB-values
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicon Compounds (AREA)

Abstract

Selenium containing impurities such as oxides of lead, iron, aluminium, copper and silica is purified by treatment with molten alkali at a temperature of 360 DEG C. or above. The selenium is dissolved with the formation of alkali selenide and selenite together with some polyselenides and selenate. Undissolved impurities, such as iron and copper oxides are separated by filtering, and if desired the selenite and selenate are reduced by means of charcoal. The molten mass is then dissolved in water and treated with an oxidizing agent, preferably air or oxygen, with the formation of selenium and alkali hydrate. The remaining impurities may be removed by acid washing. Reference has been directed by the Comptroller to British Specifications 134,536, [Class 90], and 423,084, and U.S.A. Specification 1,945,074.
GB3745/35A 1934-06-06 1935-02-05 An improved method of refining selenium Expired GB440004A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE440004X 1934-06-06

Publications (1)

Publication Number Publication Date
GB440004A true GB440004A (en) 1935-12-18

Family

ID=20309957

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3745/35A Expired GB440004A (en) 1934-06-06 1935-02-05 An improved method of refining selenium

Country Status (1)

Country Link
GB (1) GB440004A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2816008A (en) * 1955-12-06 1957-12-10 American Smelting Refining Recovery of selenium from scrap selenium rectifiers
US2863731A (en) * 1952-12-20 1958-12-09 American Smelting Refining Control of the state of the selenium in alkali slags
US4863508A (en) * 1987-10-01 1989-09-05 Xerox Corporation Process for the preparation of chalcogenide alloys by the solution oxidation of alkaline selenium and alkaline tellurium compounds
CN112357893A (en) * 2020-11-16 2021-02-12 昆明理工大学 Method for purifying crude selenium by melting and filtering
CN116161629A (en) * 2023-04-03 2023-05-26 昆明理工大学 A method for purifying selenium

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2863731A (en) * 1952-12-20 1958-12-09 American Smelting Refining Control of the state of the selenium in alkali slags
US2816008A (en) * 1955-12-06 1957-12-10 American Smelting Refining Recovery of selenium from scrap selenium rectifiers
US4863508A (en) * 1987-10-01 1989-09-05 Xerox Corporation Process for the preparation of chalcogenide alloys by the solution oxidation of alkaline selenium and alkaline tellurium compounds
CN112357893A (en) * 2020-11-16 2021-02-12 昆明理工大学 Method for purifying crude selenium by melting and filtering
CN116161629A (en) * 2023-04-03 2023-05-26 昆明理工大学 A method for purifying selenium

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