GB333559A - Process for the manufacture of reserving agents for wool - Google Patents
Process for the manufacture of reserving agents for woolInfo
- Publication number
- GB333559A GB333559A GB1455929A GB1455929A GB333559A GB 333559 A GB333559 A GB 333559A GB 1455929 A GB1455929 A GB 1455929A GB 1455929 A GB1455929 A GB 1455929A GB 333559 A GB333559 A GB 333559A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- sulphochloride
- sulphonic
- condensed
- dichlorobenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
333,559. Carpmael, A., (I. G. Farbenindustrie Akt.-Ges.). May 9, 1929, Sulphonic acid amides and carboxylic acid amides soluble in water and containing one or more free sulpho-groups but no nitro group or free amino or hydroxy group are made by condensing an aromatic sulphonic or carboxylic acid halide (2 mols.) with an aromatic diamine (1 mol.), at least one of the reacting components being substituted in m-position to the sulphonic or carboxylic acid halide or to the amino group. Bis-1 : 2- dichlorobenzene-4-sulpho-2<1> : 4'-tolylenediamide-6-sulphonic acid and bis-1 : 2-dichlorobenzene-4-sulphobenzidide-m-m<1>-disulphonic acid of Specification 324,962 are excluded. The products are suitable for reserving agents for wool or silk against substantive dyestuffs. In examples, (1) 1 : 3-phenylenediamine-4-sulpho acid is condensed with 2: 4-dichlorobenzoyl chloride, (2) benzidine-m-m<1>-disulpho acid with 1 : 2-dimethylbenzene-4-sulphochloride, 2-chlor-1-toluene-4-sulphochloride or 1 : 2 : 3-trichlorobenzene-4-sulphochloride, (3) benzidine-m-m<1>-disulpho acid is condensed with 4 - nitro - 1-chlorobenzene-2-sulphochloride (or m-nitrobenzenesulphochloride), the product reduced and condensed with 1 : 2-dichlorobenzene-4-sulphochloride (2 mols.), (4) bis- 3-aminobenzene-1-sulphonylbenzidine-m-m<1>- disulphonic acid is condensed with m-nitrobenzenesulphochloride, the product reduced and condensed with 1 : 2 - dichlorobenzene - 4 - sulphochloride; the original starting material i.e. benzidine-m-m<1>-disulpho acid may be replaced by tolidine-m-m<1>-disulpho acid or p-p<1>-diaminostilbene-o-o<1>-disulpho acid or by aminodiaryl derivatives having other bridge bonds e.g. 4: 4'-diaminodiphenylamine-2-sulphonic acid, (5) 2: 2'- dichlorobenzidine is condensed with the semichloride of m-sulphobenzoic acid. The Provisional Specification refers also to the condensation of aromatic sulphonic, or carboxylic acid halides with aromatic amines in general. Specification 333,554 is referred to. Sulphochlorides. - 1 : 2-Dimethylbenzene-4- sulphochloride, 2-chloro - 1 - toluene - 4 - sulphochloride, 1 : 2 : 3-trichlorobenzene - 4 - sulphochloride, 4-nitro-1-chlorobenzene-2-sulphochloride and 1 : 2- dichlorbenzene-4-sulphochloride are made by treating respectively with chlorosulphonic acid o-xylene, 2-chloro-1-toluene-4-sulphonic acid, 1 : 2 : 3-trichlorobenzene, 4-nitro-1- chlorobenzene-2-sulphonic acid and 1 : 2-dichlorobenzene or its 4-sulphonic acid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1455929A GB333559A (en) | 1929-05-09 | 1929-05-09 | Process for the manufacture of reserving agents for wool |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1455929A GB333559A (en) | 1929-05-09 | 1929-05-09 | Process for the manufacture of reserving agents for wool |
Publications (1)
Publication Number | Publication Date |
---|---|
GB333559A true GB333559A (en) | 1930-08-11 |
Family
ID=10043407
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1455929A Expired GB333559A (en) | 1929-05-09 | 1929-05-09 | Process for the manufacture of reserving agents for wool |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB333559A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2424477A (en) * | 1938-12-24 | 1947-07-22 | Geigy Ag J R | Preparation of halogen substituted aminoarylsulphonic acid derivatives |
EP0396077A1 (en) * | 1989-05-03 | 1990-11-07 | BASF Aktiengesellschaft | Phenylene diamines and a process for their preparation |
-
1929
- 1929-05-09 GB GB1455929A patent/GB333559A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2424477A (en) * | 1938-12-24 | 1947-07-22 | Geigy Ag J R | Preparation of halogen substituted aminoarylsulphonic acid derivatives |
EP0396077A1 (en) * | 1989-05-03 | 1990-11-07 | BASF Aktiengesellschaft | Phenylene diamines and a process for their preparation |
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