GB270840A - Manufacture of anthraquinone derivatives - Google Patents
Manufacture of anthraquinone derivativesInfo
- Publication number
- GB270840A GB270840A GB542126A GB542126A GB270840A GB 270840 A GB270840 A GB 270840A GB 542126 A GB542126 A GB 542126A GB 542126 A GB542126 A GB 542126A GB 270840 A GB270840 A GB 270840A
- Authority
- GB
- United Kingdom
- Prior art keywords
- anthraquinone
- bis
- heating
- aminoarylanthracenes
- toluidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C225/00—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones
- C07C225/22—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
270,840. Imray, O. Y., (I. G, Farbenindustrie Akt.-Ges.). Feb. 25, 1926. Bis-aminoarylanthrones and bis-aminoarylanthracenes are produced by heating anthraquinone or a homologue thereof with a salt of an aromatic amine having no substituent in the p-position to the amino group. When working for a short time at a temperature below 180‹ C., the firstmentioned products are principally obtained, the compound from anthraquinone and aniline being probably At temperatures above 185‹ C. the products are principally the bis-aminoarylanthracenes of the probable formula According to examples (1) anthraquinone is heated at 175‹ C. with hydrochloride of aniline, o-toluidine, or o-anisidine in presence of an excess of the free base; after rendering alkaline and steam distilling the residue is dissolved in acid and the bisaminoarylanthrone precipitated by alkali : (2) the heating is carried out at 180-185‹ C. and the product diluted with alcohol; the residue consists of the hydrochloride of the bis-aminoarylanthracene which can be decomposed by boiling with water. 2-Methylanthraquinone is also specified as parent material. Magenta is formed as a bye-product when heating anthraquinone with o-toluidine and its bydrochloride.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB542126A GB270840A (en) | 1926-02-25 | 1926-02-25 | Manufacture of anthraquinone derivatives |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB542126A GB270840A (en) | 1926-02-25 | 1926-02-25 | Manufacture of anthraquinone derivatives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB270840A true GB270840A (en) | 1927-05-19 |
Family
ID=9795862
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB542126A Expired GB270840A (en) | 1926-02-25 | 1926-02-25 | Manufacture of anthraquinone derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB270840A (en) |
-
1926
- 1926-02-25 GB GB542126A patent/GB270840A/en not_active Expired
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