GB2457347A - Fungicidal compositions - Google Patents

Abstract

A method of controlling phytopathogenic diseases on useful plants or on propagation material thereof, which comprises applying to the useful plants, the locus thereof or propagation material thereof a combination of components A) and B) in a synergistically effective amount, wherein component A) is a compound of formula I <EMI ID=1.1 HE=34 WI=73 LX=718 LY=965 TI=CF> wherein <DL TSIZE=3 COMPACT=COMPACT> <DT>R<DD>is CF2H or Cr3; <DT>Z1<DD>is halogen; <DT>Z2<DD>is halogen; and <DT>Y<DD>is hydrogen or halogen; and agronomically acceptable salts/isomers/enantiomers/tautomers/N-oxides of those compounds; and component B) is a compound selected from compounds known for their fungicidal and/or insecticidal activity, is particularly effective in controlling or preventing fungal diseases of useful plants. </DL>

Description

FUNGICIDAL COMPOSITIONS

The present invention relates to novel fungicidal compositions for the treatment of phyto-pathogenic diseases of useful plants, especially phytopathogenic fungi, and to a method of controlling phytopathogenic diseases on useful plants.

It is known from WO 2007/141009 and WO 2007/060164 that certain N-[2-(phenyl)ethyl]-carboxamide derivatives have biological activity against phytopathogenic fungi. On the other hand various fungicidal compounds of different chemical classes are widely known as plant fungicides for application in various crops of cultivated plants. However, crop tolerance and activity against phytopathogenic plant fungi do not always satisfy the needs of agricultural practice in many incidents and aspects.

There is therefore proposed in accordance with the present invention a method of controlling phytopathogenic diseases on useful plants or on propagation material thereof, which comprises applying to the useful plants, the locus thereof or propagation material thereof a combination of components A) and B) in a synergistically effective amount, wherein component A) is a compound of formula I CH3 wherein R is CF2H or CF3; 1, is halogen; Z2 is halogen; and Y is hydrogen or halogen; and agronomically acceptable salts/isomers/enantiomers/tautomers/N-oxjdes of those compounds; and component B) is.a compound selected from the group consisting of a strobilurin fungicide, such as azoxystrobin (47), dimoxystrobin (226), fluoxastrobin (382), kresoxim-methyl (485), metominostrobin (551), orysastrobin, picoxystrobin (647), pyraclostrobin (690); trifloxystrobin (832); the compound of formula B-6 H3CCH3CI (B-6); an azole fungicide, such as azaconazole (40), bromuconazole (96), cyproconazole (207), difenoconazole (247), diniconazole (267), diniconazole-M (267), epoxiconazole (298), fenbuconazole (329), fluquinconazole (385), flusilazole (393), flutriafol (397), hexaconazole (435), imazalil (449), imibenconazole (457), ipconazole (468), metconazole (525), myclobutanil (564), oxpoconazole (607), pefurazoate (618), penconazole (619), prochloraz (659), propiconazole (675), prothioconazole (685), simeconazote (731), tebuconazole (761), tetraconazole (778), triadimefon (814), triadimenol (815), triflumizole (834) triticonazole (842), diclobutrazol (1068), etaconazole (1129), furconazole (1198), furconazote-cis (1199) and Quinconazole (1378); and a phenyl pyrrole fungicide, such as fenpiclonil (341) and fludioxonil (368); and an anilino-pyrimidine fungicide, such as cyprodinil (208), mepanipyrim (508) and pyrimethanil (705); a morpholine fungicide, such as aldimorph, dodemorph (288), fenpropimorph (344), tridemorph (830), fenpropidin (343), spiroxamine (740); piperalin (648); and the compound of formula B-7 FJO CH3 (B-7), the compound of formula F-I

CH ill

H (F-i);

CH Cl

the compound of formula F-2 o2 CF2,,\LN r'f') H/

N CR3 (F2), CR3

CR3 CR3 the compound of formula F-3 CF)LN /

N

(F-3); CH3 ("CR3 the compound of formula F-4

CF N \

H

(F-4); CH3 \\\ CH3 CHj-0 CH3 the compound of formula F-5 on CF2)\-N N9 Ho I (F-5); CH3 CH3 the compound of formula F-6 o)) N CI (F-6); \\ )ç CH3 CH3CH3 the racemic compound of formula F-7 (trans) HH(' (F-7); CH3 the racemic compound of formula F-8 (cis) H NHSH (F-8); CH3 the compound of formula F-9 H (F-9), CH3 which represents a mixture of racemic compounds of formula F-7 (trans) and F-8 (cis), wherein the ratio of racemic compounds of formula F-7 (trans) to racemic compounds of formula F-8 (cis) is from 2: Ito 100:1; a racemic compound of formula F-b (syn) ()CH3 Ra7)L_N' \iH N) H (F-b), "N CH3 wherein Ra7 is trifluoromethyl or difluoromethyl; a racemic mixture of formula F-i I (anti) /\H (F-Il), CH3 wherein Ra7 is trifluoromethyl or difluoromethyl;a compound of formula F-12 /\ Ra7)\_ H (F-12),

N CH3

which is an epimeric mixture of racemic compounds of formulae F-i 0 (syn) and F-il (anti), wherein the ratio from racemic compn"nds of formu! F-b (syn) to racemic iripounds of formula F-il (anti) is from 1000: 1 to 1: 1000 and wherein Ra7 is trifluoromethyl or difluoromethyl; a compound of formula F-i 3 0)/> Ra8)LN' v:1/ N') H (F-13),

N CH3

wherein Ra8 is trifluoromethyl or difluoromethyl; trinexapac-Ethyl (841); chlormequat chloride (137); ethephon (307); prohexadione calcium (664); mepiquat chloride (509); proquinazid (682); chlorothalonil (142); famoxadone (322); fenamidone (325); benomyl (62); carbendazim (116); fuberidazole (419); thiabendazole (790); thiophanate (1435); thiophanate-methyl (802), chlozolinate (149); iprodione (470); procymidone (660); vinclozolin (849); bitertanol (84); fenarimol (327); nuarimol (587); pyrifenox (703); triforine (838); benalaxyl (56); furalaxyl (410); metalaxyl (516); mefenoxam (metalaxyl-M) (517); ofurace (592); oxadixyl (601); edifenphos (290); iprobenfos (IBP) (469); isoprothiolane (474); pyrazophos (693); benodanil (896); carboxin (120); fenfuram (333); flutolanil (396); furametpyr (411); mepronil (510); oxycarboxin (608); thifluzamide (796); bupirimate (98); dimethirimol (1082); ethirimol (1133); diethofencarb (245); quinoxyfen (715); biphenyl (81); chloroneb (139); dicloran (240); etridiazole (321); quintozene (PCNB) (716); tecnazene (TCNB) (767); tolclofos-methyl (808); dimethomorph (263); carpropamid (122); diclocymet (237); fenoxanil (338); fthalide (643); pyroquilon (710); tricyclazole (828); fenhexamid (334); polyoxin (654); pencycuron (620); cyazofamid (185); zoxamide (857); blasticidin-S (85); kasuga mycin (483); streptomycin (744); validamycin (846); cymoxanil (200); iodocarb (3-lodo-2-propynyl butyl carbamate); propamocarb (668); prothiocarb (1361); dinocap (270); fluazinam (363); fentin acetate (347); fentin chloride; fentin hydroxide (347); oxolinic acid (606); hymexazole; octhilinone (590); fosetyl-aluminium (407); phosphoric acid; tecloftalam; triazoxide (821); flusulfamide (394); ferimzone (351); diclomezine (239); anilazine (878); arsenates; captafol (113); captan (114); chlorothalonil (142); copper (diverse salts); copper ammoniumcarbonate; copper octanoate (170); copper oleate; copper sulphate (87; 172; 173); copper hydroxide (169); dichlofluanid (230); dithianon (279); dodine (289); ferbam (350); folpet (400); guazatine (422); iminoctadine (459); mancozeb (496); maneb (497): mercury; metirm (546); prophieb (676); sulphur (754); thram (804), Luiyifiuanid (8iU); zineb (855); ziram (856); acibenzolar-S-methyl (6); probenazole (658); benthiavalicarb; benthiavalicarbisopropyl (68); iprovalicarb (471); diflumetorim (253); ethaboxam (304); flusulfamide (394); methasulfocarb (528); silthiofam (729); bacillus pumilus 0634; bacillus pumilus strain QST 2808; bacillus subtilis (50); bacilus subtilis + PCNB + metalaxyl (50; 716; 516); cadmium chloride; carbon disulfide (945); bordeaux mixture (87); cedar leaf oil; chlorine; cinnamaldehyde; cycloheximide (1022); fenaminosulf (1144); fenamiphos (326); dichloropropene (233); dichlone (1052); formaldehyde (404); gliocladium virens GL-21 (417); glyodin (1205); hexachlorobenzene (434); iprovalicarb (471); manganous dimethyldithiocarbamate; mercuric chloride (511); nabam (566); neem oil (hydrophobic extract); oxytetracycline (611); chinomethionat (126); paraformaldehyde; pentachloronitrobenzene (716); pentachlorophenol (623); paraffin oil (628); polyoxin D zinc salt (654); sodium bicarbonate; potassium bicarbonate; sodium diacetate; sodium propionate; TCMTB; benalaxyl -M; boscalid (88); hexaconazole (435); metrafenone; oxine copper (605); penthiopyrad; perfurazoate; tolyfluanid; trichoderma harzianum (825); triphenyltiri hydroxide (347); xanthomonas campestris (852); paclobutrazol (612); 1,1-bis(4-chlorophenyl)-2-ethoxyethano) (I UPAC-Name) (910); 2,4-dichlorophenyl benzenesu Ifonate (I UPAC-/ Chemical Abstracts-Name) (1059); 2-fluoro-N-methyl-N-1 -naphthylacetamide (IUPAC-Name) (1295); 4-chlorophenyl phenyl sulfone (IUPAC-Name) (981); abamectin (1); acequinocyl (3); acetoprole [CCNJ; acrinathrin (9); aldicarb (16); aldoxycarb (863); alpha-cypermethrin (202); amidithion (870); amidoflumet [CCN]; amidothioate (872); amiton (875); amiton hydrogen oxalate (875); amitraz (24); aramite (881); arsenous oxide (882); AVI 382 (compound code); AZ 60541 (compound code); azinphos-ethyl (44); azinphos-methyl (45); azobenzene (IUPAC-Name) (888); azocyclotin (46); azothoate (889); benomyl (62); benoxa-fos (alternative name) [CCN]; benzoximate (71); benzyl benzoate (IUPAC-Name) [CCN]; bifenazate (74); bifenthrin (76); binapacryl (907); brofenvalerate (alternative name); bromo-cyclen (918); bromophos (920); bromophos-ethyl (921); bromopropylate (94); buprofezin (99); butocarboxim (103); butoxycarboxim (104); butylpyridaben (alternative name); calcium polysulfide (IUPAC-Name) (111); camphechlor (941); carbanolate (943); carbaryl (115); carbofuran (118); carbophenothion (947); CGA 50'439 (development code) (125); chino-methionat (126); chlorbenside (959); chlordimeform (964); chlordimeform hydrochloride (964); chlorfenapyr (130); chlorfenethol (968); chlorfenson (970); chlorfensulphide (971); chlorfenvinphos (131); chlorobenzilate (975); chloromebuform (977); chloromethiuron (978); chloropropylate (983); chlorpyrifos (145); chlorpyrifos-methyl (146); chlorthiophos (994); cinerin 1(696); cinerin 11(696): cinerins (69A): c!ofentezine (158); dcrtc! (ctcmatve name) [CCN}; coumaphos (174); crotamiton (alternative name) [CCN]; crotoxyphos (1010); cufraneb (1013); cyanthoate (1020); cyhalothrin (196); cyhexatin (199); cypermethrin (201); DCPM (1032); DDT (219); demephion (1037); demephion-O (1037); demephion-S (1037); demeton (1038); demeton-methyl (224); demeton-O (1038); demeton-O-methyl (224); demeton-S (1038); demeton-S-methyl (224); demeton-S-methylsulphon (1039); diafen-thiuron (226); dialifos (1042); diazinon (227); dichlofluanid (230); dichlorvos (236); dicliphos (alternative name); dicofol (242); dicrotophos (243); dienochlor (1071); dimefox (1081); dimethoate (262); dinactin (alternative name) (653); dinex (1089); dinex-diclexine (1089); dinobuton (269); dinocap (270); dinocap-4 [CCN]; dinocap-6 [CCN]; dinocton (1090); dino-penton (1092); dinosulfon (1097); dinoterbon (1098); dioxathion (1102); diphenyl sulfone (IUPAC-Name) (1103); disulfiram (alternative name) [CCN]; disulfoton (278); DNOC (282); dofenapyn (1113); doramectin (alternative name) [CCN]; endosulfan (294); endothion (1121); EPN (297); eprinomectin (alternative name) [CCN]; ethion (309); ethoate-methyl (1134); etoxazole (320); etrimfos (1142); fenazaflor (1147); fenazaquin (328); fenbutatin oxide (330); fenothiocarb (337); fenpropathrin (342); fenpyrad (alternative name); fen- pyroximate (345); fenson (1157); fentrifanil (1161); fenvalerate (349); fipronil (354); fluacry-pyrim (360); fluazuron (1166); flubenzimine (1167); flucycloxuron (366); flucythrinate (367); fluenetil (1169); flufenoxuron (370); flumethrin (372); fluorbenside (1174); fluvalinate (1184); FMC 1137 (development code) (1185); formetanate (405); formetanate hydrochloride (405); formothion (1192); formparanate (1193); gamma-HCH (430); glyodin (1205); halfenprox (424); heptenophos (432); hexadecyl cyclopropanecarboxylate (IUPAC-/ Chemical Abstracts-Name) (1216); hexythiazox (441); iodomethane (IUPAC-Name) (542); isocarbo-phos (alternative name) (473); isopropyl O-(methoxyaminothiophosphoryl)salicylate (IIJPAC-Name) (473); ivermectin (alternative name) [CCN]; jasmolin I (696); jasmolin II (696); jodfenphos (1248); lindane (430); lufenuron (490); malathion (492); malonoben (1254); mecarbam (502); mephosfolan (1261); mesulfen (alternative name) [CCN]; meth-acrifos (1266); methamidophos (527); methidathion (529); methiocarb (530); methomyl (531); methyl bromide (537); metolcarb (550); mevinphos (556); mexacarbate (1290); milbemectin (557); milbemycin oxime (alternative name) [CCN]; mipafox (1293); monocro- tophos (561); morphothion (1300); moxidectin (alternative name) (CCN]; naled (567); NC- 184 (compound code); nifluridide (1309); nikkomycins (alternative name) [CCNI; nitrilacarb (1313); nitrilacarb 1:1 zinc chloride complex (1313); NNI-0101 (compound code); NNI-0250 (compound code); omethoate (594); oxamyl (602); oxydeprofos (1324); oxydisulfoton (1325); pp'-DDT (219); Darathion (615); nrmethnn (626); petroleum os (atematv naiii) (626); phenkapton (1330); phenthoate (631); phorate (636); phosalone (637); phosfolan (1338); phosmet (638); phosphamidon (639); phoxim (642); pirimiphos-methyl (652); polychloro-terpenes (traditional name) (1347); polynactins (alternative name) (653); proclonol (1350); profenofos (662); promacyl (1354); propargite (671); propetamphos (673); propoxur (678); prothidathion (1360); prothoate (1362); pyrethrin 1(696); pyrethrin 11(696); pyrethrins (696); pyridaben (699); pyridaphenthion (701); pyrimidifen (706); pyrimitate (1370); quinalphos (711); quintiofos (1381); R-1492 (development code) (1382); RA-17 (development code) (1383); rotenone (722); schradan (1389); sebufos (alternative name); selamectin (alternative name) [CCN]; Sl-0009 (compound code); sophamide (1402); spirodiclofen (738); spiromesifen (739); SSI-121 (development code) (1404); sulfiram (alternative name) [CCNI; sulfluramid (750); sulfotep (753); sulfur (754); SZI-121 (development code) (757); tau-fluvalinate (398); tebufenpyrad (763); TEPP (1417); terbam (alternative name); tetrachlorvinphos (777); tetradifon (786); tetranactin (alternative name) (653); tetrasul (1425); thiafenox (alternative name); thiocarboxime (1431); thiofanox (800); thiometon (801); thioquinox (1436); thuringiensin (alternative name) [CCN]; triamiphos (1441); triarathene (1443); triazophos (820); triazuron (alternative name); trichlorfon (824); trifenofos (1455); trinactiri (alternative name) (653); vamidothion (847); vaniliprole (CCN]; Yl-5302 (compound code); bethoxazin [CCN]; copper dioctanoate (IUPAC-Name) (170);copper sulfate (172); cybutryne [CCN]; dichlone (1052); dichlorophen (232); endothal (295); fentin (347); hydrated lime [CCN]; nabam (566); quinoclamine (714); quinonamid (1379); simazine (730); triphenyltin acetate (IUPAC-Name) (347); triphenyltin hydroxide (IUPAC-Name) (347); abamectin (1); crufomate (1011); doramectin (alternative name) [CCN}; emamectin (291); emamectin benzoate (291); eprinomectin (alternative name) [CCN]; ivermectin (alternative name) [CCNI; milbemycin oxime (alternative name) [CCN]; moxidectin (alternative name) [CCN]; piperazine [CCN]; selamectin (alternative name) [CCNJ; spinosad (737); thiophanate (1435); chloralose (127); endrin (1122); fenthion (346); pyridin-4-amine (IUPAC-Name) (23); strychnine (745); 1 -hydroxy-1 H-pyridine-2-thione (IUPAC-Nanie) (1222); 4-(quinoxalin-2-ylam,no)benzenesulfonamjde (IUPAC-Name) (748); 8-hydroxyquinoline sulfate (446); bronopol (97); copper dioctanoate (IUPAC-Name) (170); copper hydroxide (IUPAC-Name) (169); cresol [CCN]; dichlorophen (232); dipyrithione (1105); dodicin (1112); fenaminosulf (1144); formaldehyde (404); hydrargaphen (alternative name) [CCN]; kasugamycin (483); kasugamyciri hydrochloride hydrate (483); nickel bis(dimethyldithiocarbamate) (IUPAC-Name) (1308); nitrapyrin (580); octhilinone (590); oxolinic acid (606): oxtetrayIir (611); potsskim hydroxyquicne sfate (446); probenazole (658); streptomycin (744); streptomycin sesquisulfate (744); tecloftalam (766); thiomersal (alternative name) [CCN]; methyl bromide (537); apholate [CCN]; bisazir (alternative name) [CCN}; busulfan (alternative name) [CCN]; diflubenzuron (250); dimatif (alternative name) [CCNI; hemel [CCN]; hempa [CCN]; metepa [CCN]; methiotepa [CCN]; methyl apholate [CCNJ; morzid [CCN]; penfluron (alternative name) [CCN]; tepa [CCN]; thiohempa (alternative name) [CCN]; thiotepa (alternative name) [CCN]; tretamine (alternative name) [CCN]; uredepa (alternative name) [CCN]; (E)-dec-5-en-1-yl acetate with (E)-dec-5-en-1-oj (IUPAC-Name) (222); (E)-tridec-4-en-i-yl acetate (IUPAC-Name) (829); (E)-6-methylhept-2-en-4-oI (I UPAC-Name) (541); (E,Z)-tetradeca-4, I 0-dien-1-yl acetate (IUPAC-Name) (779); (Z)-dodec-7-en-1-yl acetate (IUPAC-Name) (285); (Z)-hexadec-11 -enal (IUPAC-Name) (436); (Z)-hexadec-1 1-en-i -yl acetate (I UPAC-Name) (437); (Z)-hexadec-13-en-il -yn-1 -yl acetate (IUPAC-Name) (438); (Z)-icos-i 3-en-i 0-one (IUPAC-Name) (448); (Z)-tetradec-7-en-l-al (IUPAC-Name) (782); (Z)-tetradec-9-en-l-ol (IUPAC-Name) (783); (Z)-tetradec-9-en-1-yl acetate (IUPAC-Name) (784); (7E,9Z)-dodeca- 7,9-dien-l-yl acetate (IUPAC-Name) (283); (9Z,1 IE)-tetradeca-9,i 1-dien-1-yl acetate (IUPAC-Name) (780); (9Z, 1 2E)-tetradeca-9, 1 2-dien-1 -yl acetate (IUPAC-Name) (781); 14-methyloctadec-1 -ene (I UPAC-Name) (545); 4-methylnonan-5-ol with 4-methylnonan-5-one (IUPAC-Name) (544); alpha-multistriatin (alternative name) [CCN]; brevicomin (alternative name) [CCNJ; codlelure (alternative name) [CCN]; codlemone (alternative name) (167); cuelure (alternative name) (179); disparlure (277); dodec-8-en-1-yl acetate (IUPAC-Name) (286); dodec-9-en-i -yl acetate (IUPAC-Name) (287); dodeca-8, 1 0-dien-i -yl acetate (I U PAC- Name) (284); dominicalure (alternative name) (CCN]; ethyl 4-methyloctanoate (IUPAC-Name) (317); eugenol (alternative name) [CCN]; frontalin (alternative name) [CCNJ; gossyplure (alternative name) (420); grandlure (421); grandlure I (alternative name) (421); grandlure II (alternative name) (421); grandlure Ill (alternative name)(42i); grandlure IV (alternative name) (421); hexalure [CCN]; ipsdienol (alternative name) [CCN]; ipsenol (alternative name) [CCN]; japonilure (alternative name) (481); lineatin (alternative name) [CCN]; litlure (alternative name) [CCN]; looplure (alternative name) [CCN]; medlure [CCN]; megatomoic acid (alternative name) [CCN]; methyl eugenol (alternative name) (540); muscalure (563); octadeca-2,13-dien-1-yl acetate (IUPAC-Name) (588); octadeca-3,13-dien- 1-yl acetate (IUPAC-Name) (589); orfralure (alternative name) [CCN]; oryctalure (alternative name) (317); ostramone (alternative name) [CCN]; siglure [CCN]; sordidin (alternative name) (736); sulcatol (alternative name) [CCN]; tetradec-1 1-en-1-yl acetate (IUPAC-Name) (785); trim!u,r (639); trimedure A (c!tcmtve name) (639); ijiiu,ediure B1 (alternative name) (839); triniedlure B2 (alternative name) (839); trimedlure C (alternative name) (839); trunc-call (alternative name) [CCN]; 2-(octylthio)ethanol (IUPAC-Name) (591); butopyronoxyl (933); butoxy(polypropylene glycol) (936); dibutyl adipate (IUPAC-Name) (1046); dibutyl phthalate (1047); dibutyl succinate (IUPAC-Name) (1048); diethyltoluamide [CCN]; dimethyl carbate [CCN]; dimethyl phthalate [CCN}; ethyl hexanediol (1137); hexamide [CCN]; methoquin-butyl (1276); methylneodecanamide [CCN]; oxamate [CCN]; picaridin [CCNJ; 1,1 -dichloro-1 -nitroethane (I UPAC-/ Chemical Abstracts-Name) (1058); 1,1 -dichloro- 2,2-bis(4-ethylphenyl)ethane (IUPAC-Name) (1056); 1,2-dichloropropane (IUPAC-/ Chemical Abstracts-Name) (1062); 1,2-dichloropropane with 1 3-dichloropropene (IUPAC- Name) (1063); 1 -bromo-2-chloroethane (IUPAC-/ Chemical Abstracts-Name) (916); 2,2,2- trichloro-1 -(3,4-dichlorophenyl)ethyl acetate (IUPAC-Name) (1451); 2,2-dichlorovinyl 2-ethyl- sulfinylethyl methyl phosphate (IUPAC-Narne) (1066); 2-(1,3-dithiolan-2-yl)phenyl dimethyl-carbamate (IUPAC-/ Chemical Abstracts-Name) (1109); 2-(2-butoxyethoxy)ethyl thiocyanate (IUPAC-/ Chemical Abstracts-Name) (935); 2-(4,5-dimethyl-1,3-dioxolan-2-yf)phenyl methylcarbamate (I U PAC-I Chemical Abstracts-Name) (1084); 2-(4-chloro-3, 5-xylyloxy)- ethanol (IUPAC-Name) (986); 2-chlorovinyl diethyl phosphate (IUPAC-Name) (984); 2- imidazolidone (IUPAC-Name) (1225); 2-isovalerylindan-1,3-dione (I UPAC-Name) (1246); 2-methyl(prop-2-ynyl)aminophenyl methylcarbamate (I UPAC-Name) (1284); 2-thiocyanatoethyl Jaurate (IUPAC-Narne) (1433); 3-bromo-1 -chloroprop-1 -ene (IUPAC-Name) (917); 3-methyl- 1 -phenylpyrazol-5-yl dimethylcarbamate (I UPAC-Name) (1283); 4-methyl(prop-2-ynyl)amino- 3,5-xylyl methylcarbamate (I UPAC-Name) (1285); 5,5-dimethyl-3-oxocyclohex-1 -enyl dimethylcarbarnate (IUPAC-Name) (1085); abamectin (1); acephate (2); acetamiprid (4); acethion (alternative name) [CCN]; acetoprole [CCN]; acrinathrin (9); acrylonitrile (IUPAC-Name) (861); alanycarb (15); aldicarb (16); aldoxycarb (863); aldrin (864); allethrin (17); ailosamidin (alternative name) [CCN]; allyxycarb (866); alpha-cypermethrin (202); alpha-ecdysone (alternative name) [CCN]; aluminium phosphide (640); amidithion (870); amidothioate (872); aminocarb (873); amiton (875); amiton hydrogen oxalate (875); amitraz (24); anabasine (877); athidathion (883); AVI 382 (compound code); AZ 60541 (compound code); azadirachtin (alternative name) (41); azamethiphos (42); azinphos-ethyl (44); azinphos-methyl (45); azothoate (889); Bacillus thuringiensis delta endotoxins (alternative name) (52); barium hexafluorosilicate (alternative name) [CCN]; barium polysulfide (IUPAC- / Chemical Abstracts-Name) (892); barthrin [CCNJ; BAS 320 I (compound code); Bayer 22/190 (development code) (893); Bayer 22408 (development code) (894); bendiocarb (58); benfuracarb (60); beniiltp (AR); heta-cyfk!thrin (194); beta-cypermethrn (203); bfcrthr (76); bioallethrin (78); bioallethrin S-cyclopentenyl isomer (alternative name) (79); bioethanomethrin [CCN]; biopermethrin (908); bioresmethrin (80); bis(2-chloroethyl) ether (IUPAC-Name) (909); bistrifluron (83); borax (86); brofenvalerate (alternative name); bromfenvinfos (914); bromocyclen (918); bromo-DDT (alternative name) [CCNJ; bromophos (920); bromophos-ethyl (921); bufencarb (924); buprofezin (99); butacarb (926); butathiofos (927); butocarboxim (103); butonate (932); butoxycarboxim (104); butylpyridaben (alternative name); cadusafos (109); calcium arsenate [CCNJ; calcium cyanide (444); calcium polysulfide (IUPAC-Name) (111); camphechlor (941); carbanolate (943); carbaryl (115); carbofuran (118); carbon disulfide (IUPAC-/ Chemical Abstracts-Name) (945); carbon tetrachioride (IUPAC-Name) (946); carbophenothion (947); carbosulfan (119); cartap (123); cartap hydrochloride (123); cevadine (alternative name) (725); chlorbicyclen (960); chlordane (128); chlordecone (963); chlordimeforrn (964); chlordimeform hydrochloride (964); chlorethoxyfos (129); chlorfenapyr (130); chlorfenvinphos (131); chlorfluazuron (132); chlormephos (136); chloroform [CCN]; chloropicrin (141); chlorphoxim (989); chlorprazophos (990); chlorpyrifos (145); chlorpyrifos-methyl (146); chlorthiophos (994); chromafenozide (150); cinerin 1(696); cinerin 11(696); cinerins (696); cis-resmethrin (alternative name); cismethrin (80); clocythrin (alternative name); cloethocarb (999); closantel (alternative name) [CCN]; clothianidin (165); copper acetoarsenite [CCNJ; copper arsenate [CCN]; copper oleate [CCNJ; coumaphos (174); coumithoate (1006); crotamiton (alternative name) [CCN]; crotoxyphos (1010); crufomate (1011); cryolite (alternative name) (177); CS 708 (development code) (1012); cyanofenphos (1019); cyanophos (184); cyanthoate (1020); cyclethrin [CCN]; cycloprothrin (188); cyfluthrin (193); cyhalothrin (196); cypermethrin (201); cyphenothrin (206); cyromazine (209); cythioate (alternative name) [CCN]; d-limonene (alternative name)[CCN]; d-tetramethrjn (alternative name) (788); DAEP (1031); dazomet (216); DDT (219); decarbofuran (1034); deltamethrin (223); demephion (1037); demephion-O (1037); demephion-S (1037); demeton (1038); demeton-methyl (224); demeton-O (1038); demeton-O-methyl (224); demeton-S (1038); demeton-S-methyl (224); demeton-S-methylsulphon (1039); diafenthiuron (226); dialifos (1042); diamidafos (1044); diazinon (227); dicapthon (1050); dichlofenthion (1051); dichlorvos (236); dicliphos (alternative name); dicresyl (alternative name) [CCN]; dicrotophos (243); dicyclanil (244); dieldrin (1070); diethyl 5-methylpyrazol-3-yl phosphate (IUPAC-Name) (1076); diflubenzuron (250); dilor (alternative name) [CCN]; dimefluthrin [CCN); dimefox (1081); dimetan (1085); dimethoate (262); dimethrin (1083); dimethylvinphos (265); dimetilan (1086); dinex (1089); dinex-diclexin (flq); rinnnrAn (it'103) r4,nrm (iflO4); d:ncccb (1005); dnotefuran (271); diofenolan (1099); dioxabenzofos (1100); dioxacarb (1101); dioxathion (1102); disulfoton (278); dithicrofos (1108); DNOC (282); doramectin (alternative name)[CCN]; DSP (1115); ecdysterone (alternative name) [CCN]; El 1642 (development code) (1118); emamectin (291); emamectin benzoate (291); EMPC (1120); empenthrin (292); endosulfan (294); endothion (1121); endrin (1122); EPBP (1123); EPN (297); epofenonane (1124); epri-nomectin (alternative name) [CCN]; esfenvalerate (302); etaphos (alternative name) [CCNJ; ethiofencarb (308); ethion (309); ethiprole (310); ethoate-methyl (1134); ethoprophos (312); ethyl formate (IUPAC-Name) [CCN]; ethyl-DDD (alternative name) (1056); ethylene dibromide (316); ethylene dichloride (chemical name) (1136); ethylene oxide [CCN]; etofen-prox (319); etrimfos (1142); EXD (1143); famphur (323); fenamiphos (326); fenazaflor (1147); lenchlorphos (1148); fenethacarb (1149); fenfluthrin (1150); fenitrothion (335); feno-bucarb (336); fenoxacrim (1153); fenoxycarb (340); fenpirithrin (1155); fenpropathrin (342); fenpyrad (alternative name); fensulfothion (1158); fenthion (346); fenthion-ethyl [CCNJ; fen- valerate (349); fipronil (354); flonicamid (358); flucofuron (1168); flucycloxuron (366); flu-cythrinate (367); fluenetil (1169); flufenerim [CCN]; flufenoxuron (370); flufenprox (1171); flumethrin (372); fluvalinate (1184); FMC 1137 (development code) (1185); fonofos (1191); formetanate (405); formetanate hydrochloride (405); formothion (1192); formparanate (1193); fosmethilan (1194); fospirate (1195); fosthiazate (408); fosthietan (1196); furathio-carb (412); furethrjn (1200); gamma-cyhalothrin (197); gamma-HCH (430); guazatine (422); guazatine acetates (422); GY-81 (development code) (423); halfenprox (424); halofenozide (425); HCH (430); HEOD (1070); heptachlor (1211); heptenophos (432); heterophos [CCN]; hexaflumuron (439); HHDN (864); hydramethylnon (443); hydrogen cyanide (444); hydro-prene (445); hyquincarb (1223); imidacloprid (458); imiprothrin (460); indoxacarb (465); IPSP (1229); isazofos (1231); isobenzan (1232); isocarbophos (alternative name) (473); isodrin (1235); isofenphos (1236); isolane (1237); isoprocarb (472); isopropyl O-(methoxyaminothio-phosphoryt)salicylate (IUPAC-Name) (473); isoprothiolane (474); isothioate (1244); isoxath jon (480); ivermectin (alternative name) [CCN]; jasmolin I (696); jasmolin 11(696); jodfenphos (1248); juvenile hormone I (alternative name) [CCN]; juvenile hormone II (alternative name) [CCN]; juvenile hormone Ill (alternative name) [CCN]; kelevan (1249); kinoprene (484); lambda-cyhalothrin (198); lead arsenate [CCN]; leptophos (1250); lindane (430); liiimfos (1251); lufenuron (490); lythidathion (1253); m-cumenyl methylcarbamate (IUPAC-Name) (1014); magnesium phosphide (IUPAC-Name) (640); malathion (492); malonoben (1254); mazidox (1255); mecarbam (502); mecarphon (1258); menazon (1260); mephosfojan (1261): mercurous hlnride (513); mesu!!enfo (1253); metam (51); rnetãrn-potassium (alternative name) (519); metam-sodium (519); methacrifos (1266); methamidophos (527); methanesulfonyl fluoride (IUPAC-/ Chemical Abstracts-Name) (1268); methidathion (529); methiocarb (530); methocrotophos (1273); methomyl (531); methoprene (532); methoquin-butyl (1276); methothrin (alternative name) (533); methoxychlor (534); methoxyfenozide (535); methyl bromide (537); methyl isothiocyanate (543); methylchloroform (alternative name) [CCN]; methylene chloride [CCNJ; metofluthrin [CCNJ; metolcarb (550); metoxadiazone (1288); mevinphos (556); mexacarbate (1290); milbemectin (557); milbemycin oxime (alternative name) [CCN]; mipafox (1293); mirex (1294); monocrotophos (561); morphothion (1300); moxidectin (alternative name) [CCN]; naftalofos (alternative name) [CCN]; naled (567); naphthalene (IUPAC-/ Chemical Abstracts-Name) (1303); NC-170 (development code) (1306); NC-I 84 (compound code); nicotine (578); nicotine sulfate (578); nifluridide (1309); nitenpyram (579); nithiazine (1311); nitrilacarb (1313); nitrilacarb 1:1 zinc chloride complex (1313); NNI-0101 (compound code); NNI-0250 (compound code); nornicotine (traditional name) (1319); novaluron (585); novi-flumuron (586); 0-2,5-dichloro-4-iodophenyl 0-ethyl ethylphosphonothioate (IUPAC-Name) (1057); 0, O-diethyl 0-4-methyl-2-oxo-2H-chromen-7-yl phosphorothioate (IUPAC-Name) (1074); O,0-diethyl 0-6-methyl-2-propylpyrirnicijn-4-yI phosphorothioate (IUPAC-Name) (1075); O,0,O',O'-tetrapropyl dithiopyrophosphate (IUPAC-Name) (1424); oleic acid (IUPAC-Name) (593); omethoate (594); oxamyl (602); oxydemeton-methyl (609); oxydeprofos (1324); oxydisulfoton (1325); pp'-DDT (219); para-dichlorobenzene [CCN]; parathion (615); parathion-methyl (616); penfluron (alternative name) [CCN]; pentachlorophenol (623); pen-tachlorophenyl laurate (IUPAC-Name) (623); permethrin (626); petroleum oils (alternative name) (628); PH 60-38 (development code) (1328); phenkapton (1330); phenothrin (630); phenthoate (631); phorate (636); phosalone (637); phosfolan (1338); phosmet (638); phosni- chlor (1339); phosphamidon (639); phosphine (IUPAC-Name) (640); phoxim (642); phoxim- methyl (1340); pirimetaphos (1344); pirimicarb (651); pirimiphos-ethyl (1345); pirimiphos- methyl (652); polychlorodicyclopentadiene isomers (IUPAC-Name) (1346); polychloroter-penes (traditional name) (1347); potassium arsenite (CCN]; potassium thiocyanate [CCN]; prallethrin (655); precocene I (alternative name) [CCN]; precocene II (alternative name) [CCN]; precocene Ill (alternative name) [CCN]; primidophos (1349); profenofos (662); pro-fluthrin [CCN]; promacyl (1354); promecarb (1355); propaphos (1356); propetamphos (673); propoxur (678); prothidathion (1360); prothiofos (686); prothoate (1362); protrifenbute [CCN]; pymetrozine (688); pyraclofos (689); pyrazophos (693); pyresmethrin (1367); pyre- thrin I (696): pvrethrin 11(696); pyrethrins (696); pyrdaben (699); pyrdcy (700); pyrapher-thion (701); pyrimidifen (706); pyrimitate (1370), pyriproxyfen (708); quassia (alternative name) [CCN]; quinalphos (711); quinalphos-methyl (1376); quinothion (1380); quintiofos (1381); R-1492 (development code) (1382); rafoxanide (alternative name) [CCN]; resme-thrin (719); rotenone (722); RU 15525 (development code) (723); RU 25475 (development code) (1386); ryania (alternative name) (1387); ryanodine (traditional name) (1387); saba-dilla (alternative name) (725); schradan (1389); sebufos (alternative name); selamectin (alternative name) [CCN]; Sl-0009 (compound code); silafluofen (728); SN 72129 (deve-lopment code) (1397); sodium arsenite [CCNJ; sodium cyanide (444); sodium fluoride (IUPAC-/ Chemical Abstracts-Name) (1399); sodium hexafluorosilicate (1400); sodium pen-tachlorophenoxide (623); sodium selenate (IUPAC-Name) (1401); sodium thiocyanate [CCN]; sophamide (1402); spinosad (737); spiromesifen (739); sulcofuron (746); sulcofuron-sodium (746); sulfiuramid (750); sulfotep (753); sulfuryl fluonde (756); sulprofos (1408); tar oils (alternative name) (758); tau-fluvalinate (398); tazimcarb (1412); TDE (1414); tebufeno-zide (762); tebufenpyrad (763); tebupirimfos (764); teflubenzuron (768); tefluthrin (769); temephos (770); TEPP (1417); terallethrin (1418); terbam (alternative name); terbufos (773); tetrachloroethane [CCN]; tetrachlorvinphos (777); tetramethrin (787); theta-cyperme-thrin (204); thiacloprid (791); thiafenox (alternative name); thiamethoxam (792); thicrofos (1428); thiocarboxime (1431); thiocyclam (798); thiocyclam hydrogen oxalate (798); thiodi- carb (799); thiofanox (800); thiometon (801); thionazin (1434); thiosultap (803); thiosultap-sodium (803); thuringiensin (alternative name) [CCN]; tolfenpyrad (809); tralomethrin (812); transfluthr,n (813); transpermethrin (1440); triamiphos (1441); triazamate (818); triazophos (820); triazuron (alternative name); trichlorfon (824); trichlormetaphos-3 (alternative name) [CCN]; trichloronat (1452); trifenofos (1455); triflumuron (835); trimethacarb (840); triprene (1459); vamidothion (847); vaniliprole [CCNJ; veratridine (alternative name) (725); veratrine (alternative name) (725); XMC (853); xylylcarb (854); Yl-5302 (compound code); zeta-cypermethrin (205); zetamethrin (alternative name); zinc phosphide (640); zolaprofos (1469) und ZXJ 8901 (development code) (858); a compound of formula II o CI Nj -(lD

HN R1

wherein X is a bivalent group selected from R3 R (X1), (X), (X3), 4 R 4 R4 N R3 R3 R4-X( R5 (X4), R4 / (X5), (X6), R3 R3 (X8); U (X7) and

-NH

wherein a) R1 is cyclopropyl substituted by cyclopropyl at the 1-position, R2 is bromine, R3 is methyl, R4 is CN and X is X1; b) R1 is methyl substituted by cyclopropyl, R2 is CF3, R3 is methyl, R4 is Cl and X is X1; C) R1 is cyclopropyl substituted by cyclopropyl at the 1-position, R2 is CF3. R3 is methyl, R4 is Cl and X is X1; d) R1 is cyclopropyl substituted by cyclopropyl at the 1-position, R2 is CF3, R3 is methyl, R4 is CN and X is X1; -17-e) R1 is cyclopropyl substituted by cyclopropyl at the 1-position, R2 is OCH2CF3, R3 is methyl, R4 is CN and X is X1; f) R1 is isopropyl, R2 is methoxy; R3 is methyl, R4 is hydrogen and X is X8; g) R1 is isopropyl, R2 is trifluoromethyl, R3 is chlorine, R4 is hydrogen and X is X8; h) R1 is isopropyl, R2 is trifluoromethyl, R3 is methyl, R4 is hydrogen and X is X8; i) R1 is methyl, R2 is bromine, R3 is methyl, R4 is CN and X is X1; j) R1 is methyl, R2 is bromine, R3 is methyl, R4 is Cl and X is X1; and bis(tributyltin) oxide (IUPAC-Name) (913); bromoacetamide [CCN]; calcium arsenate [CCN]; cloethocarb (999); copper acetoarsenite [CCN]; copper sulfate (172); fentin (347); ferric phosphate (IUPAC-Name) (352); metaldehyde (518); methiocarb (530); niclosamide (576); niclosamide-olamine (576); pentachlorophenoi (623); sodium pentachlorophenoxide (623); tazimcarb (1412); thiodicarb (799); tributyltin oxide (913); trifenmorph (1454); trimethacarb (840); triphenyltin acetate (I UPAC-Name) (347); triphenyltin hydroxide (I U PAC-Name) (347); 1,2-dibromo-3-chloropropane (IUPAC-I Chemical Abstracts-Name) (1045); 1,2-dichloropropane (IUPAC-/ Chemical Abstracts-Name) (1062); 1,2-dichloropropane with 1,3-dichloropropene (IUPAC-Name) (1063); 1,3-dichloropropene (233); 3,4-dichlorotetra- hydrothiophene 1,1-dioxide (IUPAC-I Chemical Abstracts-Name) (1065); 3-(4-chlorophenyl)- 5-methylrhodanine (I UPAC-Name) (980); 5-methyl-6-thioxo-1,3, 5-thiadiazinan-3-ylacetic acid (IUPAC-Name) (1286); 6-isopentenylaminopurine (alternative name) (210); abamectin (1); acetoprole [CCN]; alanycarb (15); aldicarb (16); aldoxycarb (863); AZ 60541 (compound code); benclothiaz [CCN]; benomyl (62); butylpyridaben (alternative name); cadusafos (109); carbofuran (118); carbon disulfide (945); carbosulfan (119); chloropicrin (141); chlorpyrifos (145); cloethocarb (999); cytokinins (alternative name) (210); dazomet (216); DBCP (1045); DCIP (218); diamidafos (1044); dichlofenthion (1051); dicliphos (alternative name); dimethoate (262); doramectin (alternative name) [CCN]; emamectin (291); emamectin benzoate (291); eprinomectin (alternative name) [CCN]; ethoprophos (312); ethylene dibromide (316); fenamiphos (326); fenpyrad (alternative name); fensulfothion (1158); fosthiazate (408); fosthietan (1196); furfural (alternative name) [CCN]; GY-81 (development code) (423); heterophos [CCN]; isamidofos (1230); isazofos (1231); ivermectin (alternative name) [CCN}; kinetin (alternative name) (210); mecarphon (1258); metam (519); metam-potassium (alternative name) (519); metam-sodium (519); methyl bromide (537); methyl isothiocyanate (543); milbemycin oxime (alternative name) [CCN]; moxidectin (alternative name) [CCNJ; Myrothecium verrucaria composition (alternative name) (565); NC-i 84 (compound code); oxamyl (602); phorate (636); phosphamidon (639); phosphocarb [CCN]; sebufos (alternative name); selamectin (alternative name) [CCN]; spinosad (737); terirn (a!terative name); terbufos (773); tetr3ch!crcthphcnc (RJPAC-/ ChGmc Abstracts-Name) (1422); thiafenox (alternative name); thionazin (1434); triazophos (820); triazuron (alternative name); xylenols [CCN]; Yl-5302 (compound code); zeatin (alternative name) (210); potassium ethyixanthate [CCN]; nitrapyrin (580); acibenzolar (6); acibenzolar-S-methyl (6); probenazole (658); Reynoutria sachalinensis extract (alternative name) (720); 2-isovalerylindan-1,3-dione (IU PAC-Name) (1246); 4-(quinoxalin-2-ylamino)benzenesulfon-amide (IUPAC-Name) (748); alpha-chlorohydrin [CCNJ; aluminium phosphide (640); antu (880); arsenous oxide (882); barium carbonate (891); bisthiosemi (912); brodifacoum (89); bromadiolone (91); bromethalin (92); calcium cyanide (444); chloralose (127); chlorophacinone (140); cholecalciferol (alternative name) (850); coumachlor (1004); coumafuryl (1005); coumatetralyl (175); crimidine (1009); difenacoum (246); difethialone (249); diphacinone (273); ergocalciferol (301); flocoumafen (357); fluoroacetamide (379); flupropadine (1183); flupropadine hydrochloride (1183); gamma-HCH (430); HCH (430); hydrogen cyanide (444); lindane (430); magnesium phosphide (IUPAC-Name) (640); methyl bromide (537); norbormide (1318); phosacetim (1336); phosphine (IUPAC-Name) (640); phosphorus [CCN]; pindone (1341); potassium arsenite [CCN]; pyrinuron (1371); scilliroside (1390); sodium arsenite [CCN]; sodium cyanide (444); sodium fluoroacetate (735); strychnine (745); thallium sulfate [CCN]; warfann (851); zinc phosphide (640); 2-(2- butoxyethoxy)ethyl piperonylate (I UPAC-Name) (934); 5-( 1,3-benzodioxol-5-yl)-3-hexylcyclo-hex-2-enone (ItJPAC-Name) (903); farnesol with nerolidol (alternative name) (324); MB-599 (development code) (498); MGK 264 (development code) (296); piperonyl butoxide (649); piprotal (1343); propyl some (1358); S421 (development code) (724); sesamex (1393); Se-sasmolin (1394); sulfoxide (1406); anthraquinone (32); chloralose (127); copper naphthenate [CCNJ; copper oxychloride (171); diazinon (227); dicyclopentadiene (chemical name) (1069); guazatine (422); guazatine acetates (422); methiocarb (530); pyridin-4-amine (I U PAC-Name) (23); thiram (804); trimethacarb (840); zinc naphthenate [CCN]; ziram (856); imanin (alternative name) [CON]; ribavirin (alternative name) [CON]; mercuric oxide (512); octhilinone (590); thiophanate-methyl (802); and a compound of formula B-IA

FF

wherein R' is hydrogen, C1-C4alkyl or C1-C4haloalkyl; a compound of formula B-2 (8-2); a compound of formula B-3 CF3 �°O -(B-3); a compound of formula B-4 (B-4);

F

a compound of formula B-5 CkCF3 (B-5); a compound of formula B-8 oYo H3CN (B-8); a compound of formula B-9 CH3 o

-s CH 0

F N

(B-9); a compound of formula B-b

CI

(B-b 0); H3C a compound of formula B-li CH3 yF (B-li); H3C)) a compound of formula B-12

CI

(B-12); H3C(Jl)

NN CI

and a compound of formula B-i 3 Cl

N-ii IF

(B-13).

H3C(L)) It has now been found, surprisingly, that the active ingredient mixture according to the invention not only brings about the additive enhancement of the spectrum of action with respect to the phytopathogen to be controlled that was in principle to be expected but achieves a synergistic effect which extends the range of action of the component (A) and of the component (B) in two ways. Firstly, the rates of application of the component (A) and of the component (B) are lowered whilst the action remains equally good. Secondly, the active ingredient mixture still achieves a high degree of phytopathogen control even where the two individual components have become totally ineffective in such a low application rate range.

This allows, on the one hand, a substantial broadening of the spectrum of phytopathogens that can be controlled and, on the other hand, increased safety in use.

However, besides the actual synergistic action with respect to fungicidal activity, the pesticidal compositions according to the invention also have further surprising advantageous properties which can also be described, in a wider sense, as synergistic activity. Examples of such advantageous properties that may be mentioned are: a broadening of the spectrum of fungicidal activity to other phytopathogens, for example to resistant strains; a reduction in the rate of application of the ati'e ingredients; yrcrgistc actvty agaiilst anma pests, such as insects or representatives of the order Acarina; a broadening of the spectrum of pesticidal activity to other animal pests, for example to resistant animal pests; adequate pest control with the aid of the compositions according to the invention, even at a rate of application at which the individual compounds are totally ineffective; advantageous behaviour during formulation and/or upon application, for example upon grinding, sieving, emulsifying, dissolving or dispensing; increased storage stability; improved stability to light; more advantageuos degradability; improved toxicological and/or ecotoxicological behaviour; improved characteristics of the useful plants including: emergence, crop yields, more developed root system, tillering increase, increase in plant height, bigger leaf blade, less dead basal leaves, stronger tillers, greener leaf colour, less fertilizers needed, less seeds needed, more productive tillers, earlier flowering, early grain maturity, less plant verse (lodging), increased shoot growth, improved plant vigor, and early germination; or any other advantages familiar to a person skilled in the art.

The alkyl groups appearing in the substituent definitions may be straight-chain or branched and are, for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl or tert-butyl, preferred alkyl groups are methyl, isopropyl and tert-butyl. Halogen is generally fluorine, chlorine, bromine or iodine. This also applies, correspondingly, to halogen in combination with haloalkyl.

The components (B) are known. Where the components (B) are included in "The Pesticide Manual" [The Pesticide Manual -A World Compendium; Thirteenth Edition; Editor: C. D. S. Tomlin; The British Crop Protection Council], they are described therein under the entry number given in round brackets hereinabove for the particular component (B); for example, the compound "abamectin" is described under entry number (1). Where "[CCN]" is added hereinabove to the particular component (B), the component (B) in question is included in the "Compendium of Pesticide Common Names", which is accessible on the internet [A.

Wood; ComDendiurn of Pesticide Common Names, Copyright � 1995-2004]; for example, the compound "acetoprole" is described under the internet address html.

Most of the components (B) are referred to hereinabove by a so-called "common name", the rIvnf "JSO comrruy name" or another "common ncme" be;ng used ndvdua cases. ii the designation is not a "common name", the nature of the designation used instead is given in round brackets for the particular component (B); in that case, the IUPAC name, the IUPAC/Chemical Abstracts name, a "chemical name", a "traditional name", a "compound name" or a "develoment code" is used or, if neither one of those designations nor a "common name" is used, an "alternative name" is employed.

The following components B) are registered under a CAS-Reg. No.http://wwwl: aldimorph (CAS 91315-15-0); iodocarb (3-lodo-2-propynyl butyl carbamate) (CAS 55406-53-6); fentin chloride (CAS 668-34-8); hymexazole (CAS 10004-44-1); phosphoric acid (CAS 7664-38-2); tecloftalam (CAS 76280-91-6); arsenates (CAS 1327-53-3); copper ammoniumcarbonate (CAS 33113-08-5); copper oleate (CAS 1120-44-1); mercury (CAS 7487-94-7; 21908-53-2; 7546-30-7); benthiavalicarb (CAS 413615-35-7); cadmium chloride (CAS 10108-64-2); cedar leaf oil (CAS 8007-20-3); chlorine (CAS 7782-50-5); cinnamaldehyde (CAS: 104-55-2); manganous dimethyldithiocarbamate (CAS 15339-36-3); neem oil (hydrophobic extract) (CAS 8002-65-1); paraformaldehyde (CAS 30525-89-4); sodium bicarbonate (CAS 144-55- 8); potassium bicarbonate (CAS 298-14-6); sodium diacetate (CAS 127-09-3); sodium propionate (CAS 1 37-40-6);TCMTB (CAS 21564-17-0); benalaxyl -M (CAS 98243-83-5); metrafenone (CAS 220899-03-6); penthiopyrad (CAS 183675-82-3) and tolyfluanid (CAS 731-27-1).

The compounds of formulae F-2, F-3, F-4, F-5 and F-6 are described in WO 04/058723. The compounds of formulae F-7, F-8 and F-9 are described in WO 03/074491. Compounds of formulae F-9 to F-13 are disclosed in W02004/035589.

The compounds of formula II are for example described in WO 04/067528, WO 2005/085234, WO 2006/111341, WO 03/015519, W007/020050, W006/0401 13, and WO 2007/093402. Bacillus pumilus GB34 and Bacillus pumilus strain QST are described at the U.S. Environmental Protection Agency, U.S. EPA PC Code 006493 and U.S. EPA PC Code 006485, respectively (see: http://www.epa.gov/).

The compound of formula F-I is described in WO 01/87822. Compounds of formula B-IA and the compound of formula B-i are described in wa 98/46607. The compound of formula B-2 is described in WO 99/042447. The compound of formula B-3 is described in WO 96/1 9442. The compound of formula B-4 is described in WO 99/14 187. The compound of formula B-5 is described in US-5,945,423 and WO 94/26722. The compound of formula B-6 is described in EP-O-936-213. The compound of formula B-7 is described in US-6,020,332, CN-1-167-568. CN-1-15-q77 EP-0-860-'138. Thc compound of formu 6-8 is registered under CAS-Reg. No.http://www/: 325156-49-8 and is also known as Pyribencarb.

The compound of formula 8-9 is registered under CAS-Reg. No.http:Ilwww/: 348635-87-0 and is also known as ambromdole oramisuibrom. The compounds of formulae B-10 to B12 are described in WO 05/121104, WO 06/001175 and WO 07/066601, the compound of formula B-i 3 is disclosed in PCT/EP/2007/006304.

According to the instant invention, a "racemic compound" means a mixture of two enantiomers in a ratio of substantially 50: 50 of the two enantiomers.

The combinations according to the invention may also comprise more than one of the active components B), if, for example, a broadening of the spectrum of phytopathogenic disease control is desired. For instance, it may be advantageous in the agricultural practice to combine two or three components B) with any of the compounds of formula I, or with any preferred member of the group of compounds of formula I. The compounds of formula I and their manufacturing processes are described for example in Preferred compounds A) are listed in the following Table 1: Table 1: ComDounds of formula I ZCH3CH (I): Compound No. Z1 Z2 V R 1.001 Cl Cl Cl CF2H 1.002 Cl Cl Cl CF3 1.003 Cl Cl H CF2H Compound No. Z1 Z2 4 V R 1Q04 C! C H CF3 1.005 CI F CI CF2H 1.006 CI F CI CF3 1.007 Ci F H CF2H 1.008 CI F H CF3 1.009 CI Br CI CF2H 1.010 CI Br Ci CF3 1.011 CI Br H CF2H 1.012 Ci Br H CF3 1.013 CI I CI CF2H 1.014 CI I CI CF3 1.015 CI I H CF2H 1.016 CI I H CF3 1.017 F CI CI CF2H 1.018 F CI CI CF3 1.019 F CI H CF2H 1.020 F Ci H CF3 1.021 Br CI CI CF2H 1.022 Br CI CI CF3 1.023 Br CI H CF2H 1.024 Br CI H CF3 1.025 I CI CI CF2H 1.026 I CI CI CF3 1.027 I CI H CF2H 1.028 I Ci H CF3 1.029 CI CI Br CF2H 1.030 CI Ci Br CF3 1.031 CI Ci F CF2H 1.032 CI CI F CF3 1.033 Ci F Br CF2H 1.034 Ci F Br CF3 1.035 CI F F CF2H Compound No. Z1 Z2 [Y R 1.036 C! F F CF3 1.037 CI Br Br CF2H 1.038 CI Br Br CF3 1.039 CI Br F CF2H 1.040 CI Br F CF3 1.041 CI I Br CF2H 1.042 CI I Br CF3 1.043 CI I F CF2I-t 1.044 CI I F CF3 1.045 F CI Br CF2H 1.046 F CI Br CF3 1.047 F CI F CF2H 1.048 F CI F CF3 1.049 Br CI Br CF2H 1.050 Br CI Br CF3 1.051 Br CI F CF2H 1.052 Br CI F CF3 1.053 I CI Br CF2H 1.054 I CI Br CF3 1.055 I CI F CF2H 1.056 I CI F CF3 1.057 CI CI I CF2H 1.058 CI CI I CF3 1.059 CI F I CF2H 1.060 CI F I CF3 1.061 CI Br I CF2H 1.062 CI Br I CF3 1.063 CI I I CF2H 1.064 CI I I CF3 1.065 F Ch I CF2H 1.066 F CI I CF3 1.067 Br CI I CF2H Compound No. Z1 f Z2 I_ R I 1.068 Br CF3 1.069 I Cl I CF2H 1.070 I Cl I CF3 1.071 Br Br Br CF2H 1.072 Br Br Br CF3 1.073 Br Br H CF2H 1.074 Br Br H CF3 1.075 F F F CF2H 1.076 F F F CF3 1.077 F F H CF2H 1.078 F F H CF3 The following mixtures of components A) with components B) are preferred (the abbreviation "TX" means: "one compound selected from the group consisting of the compounds specifically described in Table 1 of the present invention"): azoxystrobin + TX; dimoxystrobin + TX; fluoxastrobin + TX; kresoxim-methyl + TX; rnetominostrobjn + TX; orysastrobin + TX; picoxystrobin + TX; pyraclostrobin + TX; trifloxystrobin + TX; the compound of formula B-6 (B-6) + TX; azaconazole + TX; bromuconazole + TX; cyproconazole + TX; difenoconazole + TX; diniconazole + TX; diniconazole-M + TX; epoxiconazole + TX; fenbuconazole + TX; fluquinconazole + TX; flusilazole + TX; flutriafol + TX; hexaconazole + TX; imazalil + TX; imibenconazole + TX; ipconazole + TX; metconazole + TX; myclobutanil + TX; oxpoconazole + TX; pefurazoate + TX; penconazole + TX; prochloraz + TX; propiconazole + TX; prothioconazole + TX; simeconazoje + TX; tebuconazole + TX; tetraconazole + TX; triadimefon + TX; friadimenol + TX; triflumizole + TX; triticonazole + TX; diclobutrazol + TX; etaconazole + TX; furconazole + TX; furconazole-cis + TX; Quinconazole + TX; fenpiclonil + TX; fludioxo.iI TX; cyprodh! + TX; mcpanipyrm + TX; pTimih iii + TX; aidimorph + TX; dodemorph + TX; fenpropimorph + TX; tridemorph + TX; fenpropidin � TX; spiroxamine + TX; piperalin + TX; the compound of formula B-7 F(j0 CH3 yO N (-) 0 the compound of formula F-i

CH

(F-i) + TX; the compound of formula F-2 CF2)-w (F-2) + TX; cl-I3 CH3 CH3 the compound of formula F-3 CF2)-_N fl Ho I (F-3) + TX; CH3 CH3 the compound of formula F-4 o -::/ CF2H -N -\ N,) \ (F4)+TX, CH3 CH3 the compound of formula F-5 o CF2N / (F-5) + TX; N, CH3 CH3 the compound of formula F-6

N

N (F-6)-f TX; CH3 CIZ"CH3 the racemic compound of formula F-7 (trans) /\

FO

H (F-7)+TX; N) CH3 the racemic compound of formula F-8 (cis)

FO

H N\SH (F-8)+TX; N2 CH3 the compound of formula F-9 /\

EQ

H N (F-9), N) CH3 which represents a mixture of racemic compounds of formula F-7 (trans) and F-8 (cis), wherein the ratio of racemic compounds of formula F-7 (trans) to racemic compounds of formula F-B (cis) is from 2: Ito 100: 1 + TX; a racemic compound of formula F-I 0 (syn) H CH3 H3 Ra7 (F-i 0), N2 CH3 wherein Ra7 is trifluoromethyl or difluoromethyl + TX; a racemic mixture of formula F-I I (anti) /ThH Ra7>)LN &/ "CH3 N (F-Il), CH3 wherein Ra7 is trifluoromethyl or difluoromethyl + TX;a compound of formula F-i 2 /\ Ra7 [) H "N CH3 which is an epimeric mixture of racemic compounds of formulae F-lU (syn) and F-li (anti), wherein the ratio from racemic compounds of formula F-b (syn) to racemic cmpounds of formula F-li (anti) is from 1000: 1 to 1: 1000 and wherein Ra7 is trifluoromethyl or difluoromethyl + TX; a compound of formula F-i 3 Ra8)\-N\ \() N') H (F-13), CH3 wherein Ra3 is trifluoromethyl or difluoromethyl + TX; trinexapac-ethyl + TX; chlormequat chloride + TX; ethephon + TX; prohexadione calcium + TX; mepiquat chloride + TX; proquinazid + TX; chlorothalonil + TX; famoxadone + TX; fenamidone + TX; benomyl + TX; carbendazim + TX; fuberidazole + TX; thiabendazole + TX; thiophanate + TX; thiophanate-methyl + TX; chlozolinate + TX; iprodione + TX; procymidone + TX; vinclozolin + TX; bitertanol + TX; fenarimol + TX; riuarimol + TX; i5 pyrifenox + TX; triforine + TX; benalaxyl + TX; furalaxyl + TX; metalaxyl + TX; mefenoxam (metaiaxyl-M) + TX; ofurace + TX; oxadixyl + TX; edifenphos + TX; iprobenfos (IBP) + TX; isoprothiolane + TX; pyrazophos + TX; benodanil + TX; carboxin + TX; fenfuram + TX; flutolanil + TX; furametpyr + TX; mepronil + TX; oxycarboxin + TX; thifiuzamide + TX; bupirimate + TX; dimethirimol + TX; ethirimol + TX; diethofencarb + TX; quinoxyfen + TX; biphenyl + TX; chioroneb + TX; dicloran + TX; etridiazole + TX; quintozene (PCNB) + TX; tecnazene (TCNB) + TX; tolciofos-methyl + TX; dimethomorph + TX; carpropamid + TX; diclocyniet + TX; fenoxanil + TX; fthalide + TX; pyroquilon + TX; tricyclazole + TX; fenhexamid + TX; polyoxin + TX; pencycuron + TX; cyazofamid + TX; zoxamide + TX; blasticidin-S + TX; kasugamycin + TX; streptomycin + TX; validamycin + TX; cymoxanil + TV. /) .J... .. .1 L I......-L._.._.._. . ----. s, *.Jj.,ciuu uJ-.-piLipJyIuyi iJuiyI QIL)IlIt) IA, IUpdIIIU(.dIU 1 IA, pIUtIIlO(dIU 1 TX; dinocap + TX; fluazinam + TX; fentin acetate + TX; fentin chloride + TX; fentin hydroxide + TX; oxolinic acid + TX; hymexazole + TX; octhilinone + TX; fosetyl-Aluminium + TX; phosphoric acid + TX; tecloftalam + TX; triazoxide + TX; flusulfamide + TX; ferimzone + TX; diclomezine + TX; anilazine + TX; arsenates + TX; captafol + TX; captan + TX; chiorothalonil + TX; copper ammoniumcarbonate + TX; copper octanoate + TX; copper oleate + TX; copper sulphate + TX; copper hydroxide + TX; dichiofluanid + TX; dithianon + TX; dodine + TX; ferbam + TX; folpet + TX; guazatine + TX; iminoctadine + TX; mancozeb + TX; maneb + TX; mercury + TX; metiram + TX; propineb + TX; sulphur + TX; thiram + TX; tolyifluanid + TX; zineb + TX; ziram + TX; acibenzolar-S-methyl + TX; probenazole + TX; benthiavalicarb + TX; benthiavalicarb-isopropyl + TX; iprovalicarb + TX; diflumetonm + TX; ethaboxam + TX; flusulfamide + TX; methasulfocarb + TX; silthiofam + TX; bacillus pumilus GB34 + TX; bacillus pumilus strain QST 2808 + TX; bacillus subtilis + TX; bacilus subtilis + PCNB + metalaxyl + TX; cadmium chloride + TX; carbon disulfide + TX; bordeaux mixture + TX; cedar leaf oil + TX; chlorine + TX; cinnamaldehyde + TX; cycloheximide + TX; fenaminosuif + TX; fenamiphos + TX; dichloropropene + TX; dichione + TX; formaldehyde + TX; gliocladium virens GL-21 + TX; glyodin + TX; hexachlorobenzene + TX; iprovalicarb � TX; manganous dimethyldithiocarbamate + TX; mercuric chloride + TX; nabam + TX; neem oil (hydrophobic extract) + TX; oxytetracycline + TX; chinomethionat + TX; paraformaldehyde + TX; pentachloronjtrobenzene i TX; pentachioropheriol + TX; paraffin oil + TX; polyoxin D zinc salt + TX; sodium bicarbonate + TX; potassium bicarbonate + TX; sodium diacetate + TX; sodium propionate + TX; TCMTB + TX; benalaxyl -M + TX; boscalid + TX; hexaconazole + TX; metrafenone + TX; oxine copper + TX; penthiopyrad + TX; perfurazoate + TX; tolyfluanid + TX; trichoderma harzianum + TX; triphenyltin hydroxide + TX; xanthomonas campestris + TX; paclobutrazol + TX; 1,1-bis(4-chlorophenyl)-2-ethoxyethanol (IUPAC- Name) + TX; 2,4-dichiorophenyl benzenesulfonate + TX; 2-fluoro-N-methyl-N-1-naphthylacetamide + TX; 4-chiorophenyl phenyl sulfone + TX; abamectin + TX; acequinocyl + TX; acetoprole + TX; acnnathrin + TX; aldicarb + TX; aldoxycarb + TX; alpha-cypermethrin + TX; amidithion + TX; amidoflumet + TX; amidothioate + TX; amiton + TX; amiton hydrogen oxalate + TX; amitraz + TX; aramite + TX; arsenous oxide + TX; AVI 382 + TX; AZ 60541 + TX; azinphos-ethyl + TX; azinphos-methyl + TX; azobenzene � TX; azocyclotin + TX; azothoate + TX; benomyl + TX; benoxafos + TX; benzoximate + TX; benzyl benzoate + TX; bifenazate + TX; bifenthrin + TX; binapacryl + TX; brofenvalerate + TX; bromocyclen + TX; bromophos + TX; bromophos-ethyl + TX; bromopropylate + TX; buprofezin + TX; butocrbcx:m + TX; butoxycarbox,m + TX; buypyriddbert + TX; caicium poiysuifide + ix; camphechior + TX; carbanolate + TX; carbaryl + TX; carbofuran + TX; carbophenothion + TX; CGA 50'439 + TX; chinomethionat + TX; chiorbenside + TX; chiordimeform + TX; chlordimeform hydrochloride + TX; chlorfenapyr + TX; chiorfenethol + TX; chlorfenson + TX; chiorfensulphide + TX; chlorfenvinphos + TX; chlorobenzilate + TX; chioromebuform + TX; chloromethiuron + TX; chioropropylate + TX; chlorpyrifos + TX; chiorpyrifos-methyl + TX; chlorthiophos + TX; cinerin I + TX; cinerin II + TX; cinerins + TX; clofentezine � TX; closantel + TX; coumaphos + TX; crotamiton + TX; crotoxyphos + TX; cufraneb + TX; cyanthoate + TX; cyhalothrin + TX; cyhexatin + TX; cypermethrin + TX; DCPM + TX; DDT + TX; demephion + TX; demephion-O + TX; demephion-S + TX; demeton + TX; demeton-methyl + TX; demeton-O + TX; demeton-O-methyl + TX; demeton-S + TX; demeton-S-methyl + TX; demeton-S-methylsulphon + TX; diafenthiuron + TX; dialifos � TX; diazinon + TX; dichlofluanid + TX; dichiorvos � TX; dicliphos + TX; dicofol + TX; dicrotophos + TX; dienochlor + TX; dimefox + TX; dimethoate + TX; dinactin + TX; dinex + TX; dinex-diclexine + TX; dinobuton + TX; dinocap + TX; dinocap-4 + TX; dinocap-6 + TX; dinocton + TX; dino-penton + TX; dinosulfon + TX; dinoterbon + TX; dioxathion + TX; diphenyl sulfone + TX; disulfiram + TX; disulfoton + TX; DNOC + TX; dofenapyn + TX; doramectin + TX; endosulfan + TX; endothion + TX; EPN + TX; eprinomectin + TX; ethion + TX; ethoate-methyl + TX; etoxazole + TX; etrimfos + TX; fenazaflor + TX; fenazaquin + TX; fenbutatin oxide + TX; fenothiocarb + TX; fenpropathrin + TX; fenpyrad + TX; fenpyroximate + TX; fenson + TX; fentrifanil + TX; fenvalerate + TX; fipronil + TX; fluacrypyrim + TX; fluazuron + TX; flubenzimine + TX; flucycloxuron + TX; flucythrinate + TX; fluenetil + TX; flufenoxuron + TX; flumethrin + TX; fluorbenside + TX; fluvalinate + TX; FMC 1137 + TX; formetanate + TX; formetanate hydrochloride + TX; formothion + TX; formparanate + TX; gamma-HCH + TX; glyodin + TX; halfenprox + TX; heptenophos + TX; hexadecyl cyclopropanecarboxylate + TX; hexythiazox + TX; iodomethane + TX; isocarbophos + TX; isopropyl O-(methoxyamino-thiophosphoryl)salicylate + TX; ivermectin + TX; jasmolin I + TX; jasmolin II + TX; jodfenphos + TX; lindane + TX; lufenuron � TX; malathion + TX; malonoben + TX; mecarbam + TX; mephosfolan + TX; mesulfen + TX; methacrifos + TX; methamidophos + TX; methidathion + TX; methiocarb + TX; methomyl + TX; methyl bromide + TX; metolcarb + TX; mevinphos + TX; mexacarbate + TX; milbemectin + TX; milbemycin oxime + TX; mipafox + TX; monocrotophos + TX; morphothion + TX; moxidectin + TX; naled + TX; NC- 184 + TX; nifluridide + TX; nikkomycins + TX; nitrilacarb + TX; nitrilacarb 1:1 zinc chloride complex + TX; NNI-0101 + TX; NNI-0250 + TX; omethoate + TX; oxamyl + TX; oxydeprofos + TX; nyiij!foton + TX; pp-DDT � TX; prthcn + TX; permethrn TX; petioeum os � TX; phenkapton + TX; phenthoate + TX; phorate + TX; phosalone + TX; phosfolan + TX; phosmet + TX; phosphamidon + TX; phoxim + TX; pirimiphos-methyl + TX; polychloro-terpenes + TX; polynactins + TX; proclonol + TX; profenofos + TX; promacyl + TX; propargite + TX; propetamphos + TX; propoxur + TX; prothidathion + TX; prothoate + TX; pyrethrin I + TX; pyrethrin H + TX; pyrethrins + TX; pyridaben + TX; pyridaphenthion + TX; pyrimidifen + TX; pyrimitate + TX; quirtalphos + TX; quintiofos + TX; R-1492 + TX; RA-17 + TX; rotenone + TX; schradan + TX; sebufos + TX; selamectin + TX; Sl-0009 + TX; sophamide + TX; spirodiclofen + TX; spiromesifen + TX; SSI-121 + TX; sulfiram + TX; sulfiuramid + TX; sulfotep + TX; sulfur + TX; SZI-121 + TX; tau-fluvalinate + TX; tebufenpyrad + TX; TEPP + TX; terbam + TX; tetrachlorvinphos + TX; tetradifon + TX; tetranactin + TX; tetrasul + TX; thiafenox + TX; thiocarboxime + TX; thiofanox + TX; thiometon + TX; thioquinox + TX; thuringiensin + TX; triamiphos + TX; triarathene + TX; triazophos + TX; triazuron + TX; trichiorfon + TX; trifenofos + TX; trinactin + TX; vamidothion + TX; vaniliprole + TX; Yl-5302 + TX; bethoxazin + TX; copper dioctanoate + TX; copper sulfate + TX; cybutryne + TX; dichlone + TX; dichiorophen + TX; endothal + TX; fentin + TX; hydrated lime + TX; nabam + TX; quinoclamine + TX; quinonamid + TX; simazirie + TX; triphenyltin acetate + TX; triphenyltin hydroxide + TX; abamectin + TX; crufomate + TX; doramectin + TX; emamectin + TX; emamectin berizoate + TX; eprinomectin + TX; ivermectin + TX; milbemycin oxime + TX; moxidectin + TX; piperazine + TX; selamectin + TX; spinosad + TX; thiophanate + TX; chioralose + TX; endrin + TX; fenthion + TX; pyridin- 4-amine + TX; strychnine + TX;1-hydroxy-1H-pyridine-2-thione + TX; 4-(quinoxalin-2- ylamino)benzenesulfonarnjde + TX; 8-hydroxyquinoline sulfate + TX; bronopol copper diocta-noate + TX; copper hydroxide + TX; cresol + TX; dichiorophen + TX; dipyrithione + TX; dodicin + TX; fenaminosuif + TX; formaldehyde + TX; hydrargaphen + TX; kasugamycin + TX; kasugamycin hydrochloride hydrate + TX; nickel bis(dimethyldithiocarbamate) + TX; nitrapyrin + TX; octhilinone + TX; oxolinic acid + TX; oxytetracycline + TX; potassium hydroxyquinoline sulfate + TX; probenazole + TX; streptomycin + TX; streptomycin sesquisulfate + TX; tecloftalam + TX; thiomersal + TX; methyl bromide + TX; apholate + TX; bisazir + TX; busutfan + TX; diflubenzuron + TX; dimatif + TX; hemel + TX; hempa + TX; metepa + TX; methiotepa + TX; methyl apholate + TX; morzid + TX; penfluron + TX; tepa + TX; thiohempa + TX; thiotepa + TX; tretamine + TX; uredepa + TX; (E)-dec-5-en-1-yl acetate with (E)-dec-5-en-1-ol + TX; (E)-tridec-4-en-1-yl acetate + TX; (E)-6-methylhept-2-en-4-ol + TX; (E,Z)-tetradeca-4,10-dien-1-yl acetate + TX; (Z)-dodec-7-en-1-yl acetate + TX; (Z)-hc-1 1-ena! TX; (Z)-hexdcc I l-cr-1-y acetãt + TX; (Z)-ilexddee-13-en-i i-yn-1-yi acetate + TX; (Z)-icos-1 3-en-I 0-one + TX; (Z)-tetradec-7-en-I -al + TX; (Z)-tetradec-9-en-1 -ol + TX; (Z)-tetradec-9-en-1-yl acetate + TX; (7E,9Z)-dodeca-7,9-dien-1-yl acetate + TX; (9Z, 11 E)-tetradeca-9, 1 1-dien-I -yl acetate + TX; (9Z,12E)-tetradeca-9,12-d len-i -yl acetate + TX; 14-methyloctadec-i-ene + TX; 4-methylnonan-5-ol with 4-methylnonan-5-one + TX; aipha-multistriatin + TX; brevicomin + TX; codlelure + TX; codlemone + TX; cuelure + TX; disparlure + TX; dodec-8-en-1-yl acetate + TX; dodec-9-en-1-yl acetate + TX; dodeca-8,10-dien-1-yl acetate + TX; dominicalure + TX; ethyl 4-methyloctanoate + TX; eugenol + TX; frontalin + TX; gossyplure + TX; grandlure + TX; grandlure I + TX; grandlure II + TX; grandlure Ill + TX; grandlure IV + TX; hexalure + TX; ipsdienol + TX; ipsenol + TX; japonilure + TX; lineatin + TX; litlure + TX; looplure + TX; medlure + TX; megatomoic acid + TX; methyl eugenol + TX; muscalure + TX; octadeca-2,13-dien-i-yI acetate + TX; octadeca-3,13-dien-1-yl acetate + TX; orfralure + TX; oryctalure + TX; ostramone + TX; siglure + TX; sordidin + TX; sulcatol + TX; tetradec-11-en-1-yI acetate + TX; trimedlure + TX; trimedlure A + TX; trimedlure B1 + TX; trimedlure B2 + TX; trimedlure C + TX; trunc-call + TX; 2- (octylthio)ethanol + TX; butopyronoxyl + TX; butoxy(polypropylene glycol) + TX; dibutyl adipate + TX; dibutyl phthalate + TX; dibutyl succinate � TX; diethyltoluamide + TX; dimethyl carbate + TX; dimethyl phthalate + TX; ethyl hexanediol + TX; hexamide + TX; methoquin- butyl + TX; methylneodecanamide + TX; oxamate + TX; picaridin + TX; 1,1-dichloro-I-nitroethane + TX; I,1-dichloro-2,2-bis(4-ethylphenyl)ethane + TX; 1,2-dichloropropane + TX; I,2-dichloropropane with 1,3-dichloropropene + TX; 1-bromo-2-chloroethane + TX; 2,2,2-trichloro-1 -(3,4-dichlorophenyl)ethyl acetate + TX; 2,2-dichiorovinyl 2-ethylsulfinylethyl methyl phosphate + TX; 2-(1,3-dithiolan-2-yl)phenyl dimethylcarbamate + TX; 2-(2-butoxyethoxy)ethyl thiocyanate + TX; 2-(4,5-dimethyl-1,3-dioxolan-2-yl)phenyl methylcarbamate + TX; 2-(4-chloro-3,5-xylyloxy)ethanol + TX; 2-chiorovinyl diethyl phosphate + TX; 2-imidazolidone + TX; 2-isovalerylindan-1,3-dione + TX; 2-methyl(prop-2- ynyl)aminophenyl methylcarbamate + TX; 2-thiocyanatoethyl laurate + TX; 3-bromo-I- chloroprop-1-ene + TX; 3-methyl-1-phenylpyrazol-5-yI dimethylcarbamate + TX; 4- methyl(prop-2-ynyl)amno3,5-xylyl methylcarbamate + TX; 5,5-dimethyl-3-oxocyclohex-1 -enyl dimethylcarbamate + TX; abamectin + TX; acephate + TX; acetamiprid + TX; acethion + TX; acetoprole + TX; acrinathrin + TX; acrylonitrile + TX; alanycarb + TX; aldicarb + TX; aldoxycarb + TX; aldrin + TX; allethrin + TX; allosamidin + TX; allyxycarb + TX; alpha-cypermethrin + TX; alpha-ecdysone + TX; aluminium phosphide + TX; amidithion + TX; amidothioate + TX; aminocarb + TX; amiton + TX; amiton hydrogen oxalate + TX; amitraz + TX; anabasine + TX; athidatnion + i x; AVI + I X; AL b0541 + TX; azadirachtin + TX; azamethiphos + TX; azinphos-ethyl + TX; azinphos-methyl + TX; azothoate + TX; Bacillus thuringiensis delta endotoxins + TX; barium hexafluorosilicate + TX; barium polysulfide + TX; barthrin + TX; BAS 320 I + TX; Bayer 22/190 + TX; Bayer 22408 + TX; bendiocarb + TX; benfuracarb + TX; bensultap + TX; beta-cyfluthrin + TX; beta-cypermethrin + TX; bifenthrin + TX; bioallethrin + TX; bioallethrin S-cyclopentenyl isomer + TX; bioethanomethrin + TX; biopermethrin + TX; bioresmethrin + TX; bis(2-chloroethyl) ether + TX; bistrifluron + TX; borax + TX; brofenvalerate + TX; bromfenvinfos 4-TX; bromocyclen + TX; bromo-DDT + TX; bromophos + TX; bromophos-ethyl + TX; bufencarb + TX; buprofezin + TX; butacarb + TX; butathiofos + TX; butocarboxim + TX; butonate + TX; butoxycarboxim + TX; butylpyridaben + TX; cadusafos + TX; calcium arsenate + TX; calcium cyanide + TX; calcium polysulfide + TX; camphechior + TX; carbanolate + TX; carbaryl + TX; carbofuran + TX; carbon disulfide + TX; carbon tetrachioride + TX; carbophenothion + TX; carbosulfan + TX; cartap � TX; cartap hydrochloride + TX; cevadine + TX; chlorbicyclen + TX; chlordane + TX; chiordecone + TX; chiordimeform + TX; chlordimeform hydrochloride + TX; chlorethoxyfos + TX; chlorfenapyr + TX; chlorlenvinphos + TX; chlorfluazuron + TX; chlormephos + TX; chloroform + TX; chioropicrin + TX; chiorphoxim + TX; chlorprazophos + TX; chlorpyrifos + TX; chiorpyrifos-methyl + TX; chiorthiophos + TX; chromafenozide + TX; cinerin I + TX; cinerin II + TX; cinerins + TX; cis-resmethrin + TX; cismethrin + TX; clocythrin + TX; cloethocarb + TX; closantel + TX; clothianidin + TX; copper acetoarsenite + TX; copper arsenate + TX; copper oleate + TX; coumaphos + TX; coumithoate + TX; crotamiton + TX; crotoxyphos + TX; crufomate + TX; cryolite + TX; Cs 708 + TX; cyanofenphos + TX; cyanophos + TX; cyanthoate + TX; cyclethrin + TX; cycloprothrin + TX; cyfluthrin + TX; cyhalothrin + TX; cypermethrin + TX; cyphenothrin + TX; cyromazine + TX; cythioate + TX; d-limonene + TX; d-tetramethrin + TX; DAEP + TX; dazomet + TX; DDT + TX; decarbofuran + TX; deltamethrin + TX; demephion + TX; demephion-O + TX; demephion-S + TX; demeton + TX; demeton-methyl + TX; demeton-O + TX; demeton-O-methyl + TX; demeton-S + TX; demeton-S-methyl + TX; demeton-S-methylsulphon + TX; diafenthiuron + TX; dialifos + TX; diamidafos + TX; diazinon + TX; dicapthon + TX; dichlofenthion + TX; dichlorvos + TX; dicliphos + TX; dicresyl + TX; dicrotophos + TX; dicyclanil + TX; dieldrin + TX; diethyl 5-methylpyrazol-3-yl phosphate + TX; diflubenzuron + TX; dilor + TX; dimefluthrin + TX; dimefox + TX; dimetan + TX; dimethoate + TX; dimethrin + TX; dimethylvinphos + TX; dimetilan + TX; dinex + TX; dinex-diclexine + TX; dinoprop + TX; dinosam + TX; dinoseb + TX; dinotefuran + TX; diofenolan + TX; dioxabenzofos + TX; dioxacai-b + TX; dioxathion + TX; disijifoton + TX; dthcrcfc � TX; DNOC TX; doamciii + TX, DSP TX; ecdysterone + TX; El 1642 + TX; emamectin + TX; emamectin benzoate + TX; EMPC + TX; empenthrin + TX; endosulfan + TX; endothion + TX; endrin + TX; EPBP + TX; EPN + TX; epofenonane + TX; eprinomectin + TX; esfenvalerate + TX; etaphos + TX; ethiofencarb + TX; ethion + TX; ethiprole + TX; ethoate-methyl + TX; ethoprophos + TX; ethyl formate + TX; ethyl-DDD + TX; ethylene dibromide + TX; ethylene dichioride + TX; ethylene oxide + TX; etofenprox + TX; etrimfos + TX; EXD + TX; famphur + TX; fenamiphos + TX; fenazaflor + TX; fenchiorphos + TX; fenethacarb + TX; fenfluthrin � TX; fenitrothion + TX; fenobucarb + TX; fenoxacrim + TX; fenoxycarb + TX; fenpirithrin + TX; fenpropathrin + TX; fenpyrad + TX; fensulfothion + TX; fenthion + TX; fenthion-ethyl + TX; fenvalerate + TX; fipronil + TX; flonicamid + TX; flucofuron + TX; flucycloxuron + TX; flucythrinate + TX; fluenetil + TX; flufenerim + TX; flufenoxuron + TX; flufenprox + TX; flumethrin + TX; fluvalinate + TX; FMC 1137 + TX; fonofos + TX; formetanate + TX; formetanate hydrochloride + TX; formothion + TX; formparanate + TX; fosmethilan + TX; fospirate + TX; fosthiazate + TX; fosthietan + TX; furathiocarb + TX; furethrin + TX; gamma-cyhalothrin + TX; gamma-HCH + TX; guazatine + TX; guazatine acetates + TX; GY-81 + TX; halfenprox + TX; halofenozide + TX; HCH + TX; HEOD + TX; heptachior + TX; heptenophos + TX; heterophos + TX; hexaflumuron + TX; HHDN + TX; hydramethylnon + TX; hydrogen cyanide + TX; hydroprene + TX; hyquincarb + TX; imidacloprid + TX; imiprothrin + TX; indoxacarb + TX; IPSP + TX; isazofos + TX; isobenzan + TX; isocarbophos + TX; isodrin + TX; isofenphos + TX; isolane + TX; isopro-carb + TX; isopropyl O-(methoxyaminothiophosphoryl)saljcylate + TX; isoprothiolane + TX; isothicate + TX; isoxathion + TX; ivermectin + TX; jasmolin I + TX; jasmolin II + TX; jodfenphos + TX; juvenile hormone I + TX; juvenile hormone II + TX; juvenile hormone Ill kelevan + TX; kinoprene + TX; Iambda-cyhalothrin + TX; lead arsenate + TX; leptophos + TX; lindane + TX; lirimfos + TX; lufenuron + TX; lythidathion + TX; m-cumenyl methylcarbamate + TX; magnesium phosphide + TX; malathion + TX; malonoben + TX; mazidox + TX; mecarbam + TX; mecarphon + TX; menazon + TX; mephosfolan + TX; mercurous chloride + TX; mesulfenfos + TX; metam + TX; metam-potassium + TX; metam-sodium + TX; methacrifos + TX; methamidophos + TX; methanesulfonyl fluoride + TX; methidathion + TX; methiocarb + TX; methocrotophos + TX; methomyl + TX; methoprene + TX; methoquin-butyl + TX; methothrin + TX; methoxychlor + TX; methoxyfenozide + TX; methyl bromide + TX; methyl isothiocyanate + TX; methylchloroform + TX; methylene chloride + TX; metotluthrin + TX; metolcarb + TX; metoxadiazone + TX; mevinphos + TX; mexacarbate � TX; milbemectin + TX; mUbemycin oxime + TX; mipafox + TX; mirex + TX; monocrotophos + TX; mnrphnthion + TX: moxdectr TX; ncftcfcs -TX; naed � TX; naphthalene + TX; NC-170 + TX; NC-184 + TX; nicotine + TX; nicotine sulfate + TX; nifluridide + TX; nitenpyram + TX; nithiazine + TX; nitrilacarb + TX; nitrilacarb 1:1 zinc chloride complex + TX; NNI-01O1 + TX; NNI-0250 + TX; nornicotine + TX; novaluron + TX; noviflumuron + TX; 0-2,5-dichloro-4-iociophenyl 0-ethyl ethylphosphonothioate + TX; 0,0- d iethyl 0-4-methyl-2-oxo-2H-chromen-7-yl phosphorothioate + TX; 0, 0-d iethyl 0-6-methyl- 2-propylpyrimidin-4-yI phosphorothioate + TX; 0,0,0', 0'-tetrapropyl dithiopyrophosphate + TX; oleic acid + TX; omethoate + TX; oxamyl + TX; oxydemeton-methyl + TX; oxydeprofos + TX; oxydisulfoton + TX; pp'-DDT + TX; para-dichlorobenzene + TX; parathion + TX; parathion-methyl + TX; penfluron + TX; pentachiorophenol + TX; pentachlorophenyl laurate + TX; permethrin + TX; petroleum oil + TX; PH 60-38 + TX; phenkapton + TX; phenothrin + TX; phenthoate + TX; phorate + TX; phosalone + TX; phosfolan + TX; phosmet + TX; phosnichior + TX; phosphamidon + TX; phosphine + TX; phoxim + TX; phoxim-methyl + TX; pirimetaphos + TX; pirimicarb + TX; pirimiphos-ethyl + TX; pirimiphos-methyl + TX; polychiorodicyclopentadiene isomers + TX; polychloroterpenes + TX; potassium arsenite + TX; potassium thiocyanate + TX; prallethrin + TX; precocene I + TX; precocene II + TX; precocene Ill + TX; primidophos + TX; profenofos + TX; profluthrin + TX; promacyl � TX; promecarb + TX; propaphos + TX; propetamphos + TX; propoxur + TX; prothidathion + TX; prothiofos + TX; prothoate + TX; protrifenbute + TX; pymetrozine + TX; pyraclofos + TX; pyrazophos + TX; pyresmethrin + TX; pyrethrin I + TX; pyrethrin II + TX; pyrethrins + TX; pyridaben + TX; pyridalyl + TX; pyridaphenthion + TX; pyrimidifen + TX; pynmitate + TX; pyriproxyfen + TX; quassia + TX; quinaiphos + TX; quinalphos-methyl + TX; quinothion + TX; quintiofos + TX; R-1492 + TX; rafoxanide + TX; resmethrin + TX; rotenone + TX; RU 15525 + TX; RU 25475 + TX; ryania + TX; ryanodine + TX; sabadilla + TX; schradan + TX; sebufos + TX; selamectin + TX; Sl-0009 + TX; silafluofen + TX; SN 72129 + TX; sodium arsenite + TX; sodium cyanide + TX; sodium fluoride + TX; sodium hexafluorosilicate + TX; sodium pentachiorophenoxide + TX; sodium selenate + TX; sodium thiocyanate + TX; sophamide + TX; spinosad + TX; spiromesifen + TX; sulcofuron + TX; sulcofuron-sodium + TX; suifluramid + TX; sulfotep + TX; sulfuryl fluoride + TX; suiprofos + TX; tar oils + TX; tau-fluvalinate + TX; tazimcarb + TX; TDE + TX; tebufenozide + TX; tebufenpyrad + TX; tebupirimfos + TX; teflubenzuron + TX; tefluthrin + TX; temephos + TX; TEPP + TX; teratlethrin + TX; terbam + TX; terbufos + TX; tetrachioroethane + TX; tetrachlorvinphos + TX; tetramethrin + TX; theta-cypermethrin + TX; thiacloprid + TX; thiafenox + TX; thiamethoxam + TX; thicrofos + TX; thiocarboxime + TX; thiocyclam + TX; thiocyclam +k; -, -ru. l_*__--hydrogen oxalate + TX: thiodicrh + TX: thiofanox TX, * s,, uuiuiiiii TX; thiosultap + TX; thiosultap-sodiurn � TX; thuringiensin + TX; tolfenpyrad + TX; tralomethrin + TX; transfluthrin + TX; transpermethrin + TX; triamiphos + TX; triazamate + TX; triazophos + TX; triazuron + TX; trichiorfon + TX; trichlormetaphos-3 + TX; trichioronat + TX; trifenofos + TX; tnflumuron + TX; trimethacarb + TX; triprene + TX; vamidothion + TX; vanhliprole + TX; veratridine + TX; veratrine + TX; XMC + TX; xylylcarb + TX; Yl-5302 + TX; zeta-cypermethrin + TX; zetamethrin + TX; zinc phosphide + TX; zolaprofos + TX; ZXI 8901 + TX; a compound of formula II R2

CI (II), HN.

wherein X is a bivalent group selected from R3 iI( (X1), (X2), R4 R4 R4' N'-' R3 R4 X5), (Y (X6) / (X4), R4-4, R5 N R3 R

N R

(X7)and N-NH wherein a) R1 is cvclopropyl sIIhtit1!!ed by cyc!oprcpy! et the 1-pcston, "2 s brornir,e, I3 iS iiihy, R4 is CN and X is X1 + TX; b) R1 is methyl substituted by cyclopropyl, R2 is CF3, R3 is methyl, R4 is Cl and X is X1 + TX; C) R1 is cyclopropyl substituted by cyclopropyl at the 1-position, R2 is CE3, R3 is methyl, R4 is Cl and X is X1 + TX; d) R1 is cyclopropyl substituted by cyclopropyl at the 1-position, R2 is CF3, R3 is methyl, R4 is CN and X is X1 + TX; e) R1 is cyclopropyl substituted by cyclopropyl at the 1-position, R2 is OCH2CF3, R3 is methyl, R4 is CN and X is X1 + TX; f) R1 is isopropyl, R2 is methoxy + TX; R3 is methyl, R4 is hydrogen and X is X8 + TX; g) R1 is isopropyl, R2 is trifluoromethyl, R3 is chlorine, R4 is hydrogen and X is X8 + TX; h) R1 is isopropyl, R2 is trifluoromethyl, R3 is methyl, R.4 is hydrogen and X is X8 + TX; i) R1 is methyl, R2 is bromine, R3 is methyl, R4 is CN and X is X1 + TX; j) R1 is methyl, R2 is bromine, R3 is methyl, R4 is Cl and X is X1 + TX; bis(tributyltin) oxide + TX; bromoacetamide + TX; calcium arsenate + TX; cloethocarb + TX; copper acetoarsenite + TX; copper sulfate � TX; fentin + TX; ferric phosphate + TX; metaldehyde + TX; methiocarb + TX; niclosamide + TX; niclosamide-olamine + TX; pentachlorophenol + TX; sodium pentachiorophenoxide + TX; tazimcarb + TX; thiodicarb + TX; tributyltin oxide + TX; trifenmorph + TX; trimethacarb + TX; triphenyltin acetate + TX; triphenyltin hydroxide + TX; 1,2-dibromo-3-chloropropane + TX; I,2-dichloropropane + TX; 1,2-dichloropropane with 1,3-dichloropropene + TX; I.3-dichioropropene + TX; 3,4-dichioro- tetrahydrothiophene 1,1-dioxide + TX; 3-(4-chlorophenyl)-5-methylrhodanine + TX; 5-methyl- 6-thioxo-1,3,5-thiadiazinan-3-ylacetic acid + TX; 6-isopentenylaminopurine + TX; abamectin + TX; acetoprole + TX; alanycarb + TX; aldicarb + TX; aldoxycarb + TX; AZ 60541 + TX; benclothiaz + TX; benomyl + TX; butylpyridaben + TX; cadusafos + TX; carbofuran + TX; carbon disulfide + TX; carbosulfan + TX; chioropicrin + TX; chlorpyrifos + TX; cloethocarb + TX; cytokinins + TX; dazomet + TX; DBCP + TX; DCIP + TX; diamidafos + TX; dichiofenthion + TX; dicliphos + TX; dimethoate + TX; doramectin + TX; emamectin + TX; emamectin benzoate + TX; eprinomectin + TX; ethoprophos + TX; ethylene dibromide + TX; fenamiphos + TX; fenpyrad + TX; fensulfothion + TX; fosthiazate + TX; fosthietan + TX; furfural + TX; GY-81 + TX; heterophos + TX; isamidofos + TX; isazofos + TX; ivermectin + TX; kinetin + TX; mecarphon + TX; metam + TX; metam-potassium + TX; metam-sodium + TX; methyl bromide + TX; methyl isothiocyanate + TX; milbemycin oxime + TX; moxidectin + TX; Myrothecium verrucaria composition + TX; NC-i 84 + TX; oxamyl + TX; phorate + TX; phosphamidon + TX: phnphncrb + TX; sebufo + TX; samectn � TX; piiod + TX; terbam + TX; terbufos + TX; tetrachiorothiophene + TX; thiafenox + TX; thionazin + TX; triazophos + TX; triazuron + TX; xylenols + TX; Yl-5302 + TX; zeatiri + TX; potassium ethylxanthate + TX; nitrapyrin + TX; acibenzolar + TX; acibenzolar-S-methyl + TX; probenazole + TX; Reynoutria sachalinensis extract + TX; 2-isovalerylindan-1,3-dione � TX; 4-(quinoxalin-2-yiamino)benzenesu(fonam,de + TX; aipha-chiorohydrin + TX; aluminium phosphide + TX; antu + TX; arsenous oxide + TX; banum carbonate + TX; bisthiosemi + TX; brodifacoum + TX; bromadiolone + TX; bromethalin + TX; calcium cyanide + TX; chloralose + TX; chiorophacinone + TX; cholecalciferol + TX; coumachior + TX; coumafuryl + TX; coumatetralyl + TX; crimidine + TX; difenacoum + TX; difethialone � TX; diphacinone + TX; ergocalciferol + TX; flocoumafen + TX: fluoroacetamide + TX; flupropadine + TX; flupropadine hydrochloride + TX; gamma-HCH + TX; HCH + TX; hydrogen cyanide + TX; lindane + TX; magnesium phosphide + TX; methyl bromide + TX; norbormide + TX; phosacetim + TX; phosphine + TX; phosphorus + TX; pindone + TX; potassium arsenite + TX; pyrinuron + TX; scilliroside + TX; sodium arsenite + TX; sodium cyanide + TX; sodium fluoroacetate + TX; strychnine + TX; thallium sulfate + TX; warfarin + TX; zinc phosphide + TX; 2-(2-butoxyethoxy)ethyl piperonylate + TX; 5-(1,3-benzodioxol-5-yI)-3-hexylcyclohex-2-enone farnesol with nerolidol + TX; MB-599 + TX; MGK 264 + TX; piperonyl butoxide + TX; piprotal + TX; propyl isome + TX; S421 + TX; sesamex + TX; sesasmolin + TX; sulfoxide + TX; anthraquinone + TX; chloralose + TX; copper naphthenate + TX; copper oxychioride + TX; diazinon + TX; dicyclopentadiene + TX; guazatine + TX; guazatine acetates + TX; methiocarb + TX; pyridin-4-amine + TX; thiram + TX; trimethacarb + TX; zinc naphthenate + TX; ziram + TX; imanin + TX; nbavirin + TX; mercuric oxide + TX; octhilinone + TX; thiophanate-methyl + TX; a compound of formula B-lA R'

FF

N (B-IA)

F

N Cl wherein R' is methyl + TX; a compound of formula B-2 (B-2) + TX; a compound of formula B-3 F (B-3)+TX; a compound of formula B-4 OCHF2 NLO F (B-4)+TX;

F

a compound of formula B-5 (B-5)+TX; a compound of formula B-8 ?H3 o-o (B-8) + TX; a compound of formula B-9 CH3

-

S 0

F

(B-9) + TX; a compound of formula B-b

CI

(B-iO) + TX; H3C(L1) N CI a compound of formula B-il

CH

I F F (B11)+TX* H3C N CI a compound of formula B-I 2 N°3 (B-i2) + TX; H3C..(1t1) and a compound of formula B-i 3 Cl 1i IF -.--F (B-i 3) + TX.

H3C(L.).) N Cl Especially preferred compositions according to the present invention comprise a mixture of component A) and a component B) which is selected from the group consisting of bitertanol, carbendazim, carpropamid, cyproconazole, dichlofluanid, edifenphos, fenamidone, propamocarb, fenhexamid, a compound of formula B-2 1":Ii. ft CF3 fluoxastrobin, fluquinconazole, fosetyl-aluminium, iprodione, iprovalicarb, prochloraz, pencycuron, propamocarb, propineb, prothioconazole, pyrimethanil, tebuconazole, spiroxamine, tolylfluanid, triadimefon, triadimenol, triazoxide and trifloxystrobin.

Further especially preferred compositions according to the present invention comprise a mixture of component A) and a component B) which is selected from the group consisting of azoxystrobin; picoxystrobin; cyproconazole; difenoconazole; propiconazole; fludioxonil; cyprodinil; fenpropimorph; fenpropidin; epoxiconazole, ipconazole, a compound of formula F-1

CH

CIX1XZ (F-i) CH and chlorothalonil.

The active ingredient combinations are effective against harmful microorganisms, such as microorganisms, that cause phytopathogenic diseases, in particular against phytopathogenic fungi and bacteria.

The active ingredient combinations are effective especially against phytopathogenic fungi belonging to th fnhlnwipg c'asses: Ascomycetec (e.g. Vcntr:a, Podosphaera, Dsphe, Monilinia, Mycosphaerella, Uncinula); Basidiomycetes (e.g. the genus Hemileia, Rhizoctonia, Phakopsora, Puccinia, Ustilago, Tilletia); Fungi irnperfecti (also known as Deuteromycetes; e.g. Botrytis, Helminthosporium, Rhynchosporium, Fusarium, Septoria, Cercospora, Alternaria, Pyricularia and Pseudocercosporella); Oomycetes (e.g. Phytophthora, Peronospora, Pseudoperonospora, Albugo, Bremia, Pythium, Pseudosclerospora, Plasmopara).

According to the invention useful plants" typically comprise the following species of plants: grape vines; cereals, such as wheat, barley, rye or oats; beet, such as sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, for example apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries or blackberries; leguminous plants, such as beans, lentils, peas or soybeans; oil plants, such as rape, mustard, poppy, olives, sunflowers, coconut, castor oil plants, cocoa beans or groundnuts; cucumber plants, such as marrows, cucumbers or me'ons; fibre plants, such as cotton, flax, hemp or jute; citrus fruit, such as oranges, lemons, grapefruit or mandarins; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, cucurbits or paprika; lauraceae, such as avocados, cinnamon or camphor; maize; tobacco; nuts; coffee; sugar cane; tea; vines; hops; durian; bananas; natural rubber plants; turf or ornamentals, such as flowers, shrubs, broad-leaved trees or evergreens, for example conifers. This list does not represent any limitation.

The term "useful plants" is to be understood as including also useful plants that have been rendered tolerant to herbicides like bromoxynhl or classes of herbicides (such as, for example, HPPD inhibitors, ALS inhibitors, for example primisulfuron, prosulfuron and trifloxysulfuron, EPSPS (5-enol-pyrovyl-shikimate-3-phosphate-synthase) inhibitors, GS (glutamine synthetase) inhibitors) as a result of conventional methods of breeding or genetic engineering. An example of a crop that has been rendered tolerant to imidazolinones, e.g. imazamox, by conventional methods of breeding (mutagenesis) is Clearfield� summer rape (Canola). Examples of crops that have been rendered tolerant to herbicides or classes of herbicides by genetic engineering methods include glyphosate-and glufosinate-resistant maize varieties commercially available under the trade names RoundupReady�, Herculex I � and LibertyLink�.

The term "useful plants" is to be understnrwl ls inchjdin a!c uscfi plants whch have beeu so transformed by the use of recombinant DNA techniques that they are capable of synthesising one or more selectively acting toxins, such as are known, for example, from toxin-producing bacteria, especially those of the genus Bacillus.

Toxins that can be expressed by such transgenic plants include, for example, insecticidal proteins, for example insecticidal proteins from Bacillus cereus or Bacillus popliae; or insecticidal proteins from Bacillus thuringiensis, such as ö-endotoxins, e.g. CrylA(b), CrylA(c), CryIF, CryIF(a2), CryllA(b), CrylilA, CrylllB(bl) or Cry9c, or vegetative insecticidal proteins (VIP), e.g. VIP1, VIP2, VIP3 or VIP3A; or insecticidal proteins of bacteria colonising nematodes, for example Photorhabdus spp. or Xenorhabdus spp., such as Photorhabdus lurninescens, Xenorhabdus nematophilus; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins and other insect-specific neurotoxins; toxins produced by fungi, such as Streptomycetes toxins, plant lectins, such as pea lectins, barley lectins or snowdrop lectins; agglutinins; proteinase inhibitors, such as trypsine inhibitors, serine protease inhibitors, patatin, cystatin, papain inhibitors; ribosome-inactivating proteins (RIP), such as ricin, maize-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroidoxidase, ecdysteroid-UDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors, HMG-COA-reductase, ion channel blockers, such as blockers of sodium or calcium channels, juvenile hormone esterase, diuretic hormone receptors, stilbene synthase, bibenzyl synthase, chitinases and glucanases.

In the context of the present invention there are to be understood by 8-endotoxins, for example CrylA(b), CryIA(c), CrylF, CrylF(a2), CryllA(b), CryillA, CrylllB(bl) or Crygc, or vegetative insecticidal proteins (VIP), for example VIPI, VIP2, VIP3 or VIP3A, expressly also hybrid toxins, truncated toxins and modified toxins. Hybrid toxins are produced recombinantly by a new combination of different domains of those proteins (see, for example, WO 02/15701). An example for a truncated toxin is a truncated CrylA(b), which is expressed in the Btl 1 maize from Syngenta Seed SAS, as described below. In the case of modified toxins, one or more amino acids of the naturally occurring toxin are replaced. In such amino acid replacements, preferably non-naturally present protease recognition sequences are inserted into the toxin, such as, for example, in the case of CrylllAO55, a cathepsin-D-recognition sequence is inserted into a CrylliA toxin (see WO 03/01 8810) Examples of such toxins or transaenic plnt capab!e cf cyrthes;s1ng 5uii toxins are disclosed, for example, in EP-A-0 374 753, WO 93/07278, WO 95/34656, EP-A-0 427 529, EP-A-451 878 and WO 03/052073.

The processes for the preparation of such transgenic plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. Cryl-type deoxyribonucleic acids and their preparation are known, for example, from WO 95/34656, EP-A-0 367 474, EP-A-0 401 979 and WO 90/1 3651.

The toxin contained in the transgenic plants imparts to the plants tolerance to harmful insects. Such insects can occur in any taxonomic group of insects, but are especially commonly found in the beetles (Coleoptera), two-winged insects (Diptera) and butterflies (Lepidoptera).

Transgenic plants containing one or more genes that code for an insecticidal resistance and express one or more toxins are known and some of them are commercially available.

Examples of such plants are: YieldGard� (maize variety that expresses a CrylA(b) toxin); YieldGard Rootworm� (maize variety that expresses a CrylllB(bl)toxin); YieldGard Plus� (maize variety that expresses a CrylA(b) and a CrylllB(bl) toxin); Starlink� (maize variety that expresses a Cry9(c) toxin); Herculex I� (maize variety that expresses a CrylF(a2) toxin and the enzyme phosphinothricine N-acetyltransferase (PAT) to achieve tolerance to the herbicide glufosinate ammonium); NuCOTN 33B� (cotton variety that expresses a CrylA(c) toxin); Boilgard I� (cotton variety that expresses a CryIA(c) toxin); Boilgard Il� (cotton variety that expresses a CrylA(c) and a CryJIA(b) toxin); VIPCOT� (cotton variety that expresses a VIP toxin); NewLeaf� (potato variety that expresses a CrylilA toxin); Nature-Gard� and Protecta�.

Further examples of such transgenic crops are: 1. Btll Maize from Syngenta Seeds SAS, Chemin de I'Hobit 27, F-31 790 St. Sauveur, France, registration number C/FR/96/05/10. Genetically modified Zea mays which has been rendered resistant to attack by the European corn borer (Ostrinia nubilalls and Sesamia nonagrioides) by transgenic expression of a truncated CryIA(b) toxin. Btl 1 maize also transgenically expresses the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium.

2. Bt176 Maize from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31 790 St. Sauveur, France, registration number C/FR/96/05/10. Genetically modified Zea mays which has been rendered resistant to attack by the European corn borer (Ostrinia nubilalis and Sesamia nonagrioides) by transgenic expression of a CrylA(b) toxin. Btl 76 maize also transgenically expresses the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium.

3. MIR6O4 Maize from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31 790 St. Sauveur, France, registration number C/FR/96/05/1 0. Maize which has been rendered insect-resistant by transgenic expression of a modified CrylliA toxin. This toxin is Cry3AO55 modified by insertion of a cathepsin-D-protease recognition sequence. The preparation of such transgenic maize plants is described in WO 03/01 8810.

4. MON 863 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C/DE/02/9. MON 863 expresses a CrylllB(bl) toxin and has resistance to certain Coleoptera insects.

5. IPC 531 Cotton from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C/ES/96/02.

6. 1507 Maize from Pioneer Overseas Corporation, Avenue Tedesco, 7 B-I 160 Brussels, Belgium, registration number C/NL/00/1 0. Genetically modified maize for the expression of the protein Cryl F for achieving resistance to certain Lepidoptera insects and of the PAT protein for achieving tolerance to the herbicide glufosinate ammonium.

7. NK603 x MON 810 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervureri, B-I 150 Brussels, Belgium, registration number C/GB/02/M3/03. Consists of conventionally bred hybrid maize varieties by crossing the genetically modified varieties NK603 and MON 810. NK603 x MON 810 Maize transgenically expresses the protein CP4 EPSPS, obtained from Agrobacterium sp. strain CP4, which imparts tolerance to the herbicide Roundup� (contains glyphosate), and also a CrylA(b) toxin obtained from Bacillus thuringiensis subsp.

kurstaki which brings about tolerance to certain Lepidoptera, include the European corn borer.

Transgenic crops of insect-resistant plants are also described in BATS (Zentrum für Biosicherheit und Nachhaltigkeit, Zentrum BATS, Clarastrasse 13, 4058 Basel, Switzerland) Report 2003, (http://bats.ch).

The term "useful plants" is to be understood as including also useful plants which have been so transformed by the use of reenmhinpt [NA techr.que thct thcy are capab of synthesising antipathogenic substances having a selective action, such as, for example, the so-called "pathogenesis-related proteins" (PRPs, see e.g. EP-A-0 392 225). Examples of such antipathogenic substances and transgenic plants capable of synthesising such antipathogenic substances are known, for example, from EP-A-0 392 225, WO 95/33818, and EP-A-0 353 191. The methods of producing such transgenic plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above.

Antipathogenic substances which can be expressed by such transgenic plants include, for example, ion channel blockers, such as blockers for sodium and calcium channels, for example the viral KP1, KP4 or KP6 toxins; stilbene synthases; bibenzyl synthases; chitinases; glucanases; the so-called "pathogenesis-related proteins" (PRPs; see e.g. EP-A- 0 392 225); antipathogenic substances produced by microorganisms, for example peptide antibiotics or heterocyclic antibiotics (see e.g. WO 95/33818) or protein or polypeptide factors involved in plant pathogen defence (so-called "plant disease resistance genes", as described in WO 03/000906).

Usefui plants of elevated interest in connection with present invention are cereals; soybean; rice; oil seed rape; pome fruits; stone fruits; peanuts; coffee; tea; strawberries; turf; vines and vegetables, such as tomatoes, potatoes, cucurbits and lettuce.

The term "locus" of a useful plant as used herein is intended to embrace the place on which the useful plants are growing, where the plant propagation materials of the useful plants are sown or where the plant propagation materials of the useful plants will be placed into the soil.

An example for such a locus is a field, on which crop plants are growing.

The term "plant propagation material" is understood to denote generative parts of a plant, such as seeds, which can be used for the multiplication of the latter, and vegetative material, such as cuttings or tubers, for example potatoes. There may be mentioned for example seeds (in the strict sense), roots, fruits, tubers, bulbs, rhizomes and parts of plants.

Germinated plants and young plants which are to be transplanted after germination or after emergence from the soil, may also be mentioned. These young plants may be protected before transplantation by a total or partial treatment by immersion. Preferably "plant propagation motcr" is understood to deiiot seeds.

A futher aspect of the instant invention is a method of protecting natural substances of plant and/or animal origin, which have been taken from the natural life cycle, and/or their processed forms against attack of fungi, which comprises applying to said natural substances of plant and/or animal origin or their processed forms a combination of components A) and B) in a synergistically effective amount.

According to the instant invention, the term "natural substances of plant origin, which have been taken from the natural life cycle" denotes plants or parts thereof which have been harvested from the natural life cycle and which are in the freshly harvested form. Examples of such natural substances of plant origin are stalks, leafs, tubers, seeds, fruits or grains.

According to the instant invention, the term "processed form of a natural substance of plant origin" is understood to denote a form of a natural substance of plant origin that is the result of a modification process. Such modification processes can be used to transform the natural substance of plant origin in a more storable form of such a substance (a storage good).

Examples of such modification processes are pre-drying, moistening, crushing, comminuting, grounding, compressing or roasting. Also falling under the definition of a processed form of a natural substance of plant origin is timber, whether in the form of crude timber, such as construction timber, electricity pylons and barriers, or in the form of finished articles, such as furniture or objects made from wood.

According to the instant invention, the term "natural substances of animal origin, which have been taken from the natural life cycle and/or their processed forms" is understood to denote material of animal origin such as skin, hides, leather, furs, hairs and the like.

The combinations according the present invention can prevent disadvantageous effects such as decay, discoloration or mold.

A preferred embodiment is a method of protecting natural substances of plant origin, which have been taken from the natural life cycle, and/or their processed forms against attack of fungi, which comprises applying to said natural substances of plant and/or animal origin or their processed forms a combination of components A) and B) in a synergistically effective amount A further preferred embodiment is a method of protecting fruits, preferably pomes, stone fruits, soft fruits and citrus fruits, which have been taken from the natural life cycle, and/or their processed forms, which comprises applying to said fruits and/or their processed forms a combination of components A) and B) in a synergistically effective amount.

The combinations of the present invention may also be used in the field of protecting industrial material against attack of fungi. According to the instant invention, the term uindustrial material" denotes non-live material which have been prepared for use in industry.

For example, industrial materials which are intended to be protected against attack of fungi can be glues, sizes, paper, board, textiles, carpets, leather, wood, constructions, paints, plastic articles, cooling lubricants, aquaeous hydraulic fluids and other materials which can be infested with, or decomposed by, microorganisms. Cooling and heating systems, ventilation and air conditioning systems and parts of production plants, for example cooling-water circuits, which may be impaired by multiplication of microorganisms may also be mentioned from amongst the materials to be protected. The combinations according the present invention can prevent disadvantageous effects such as decay, discoloration or mold.

The combinations of the present invention may also be used in the field of protecting technical material against attack of fungi. According to the instant invention, the term "technical material" includes paper; carpets; constructions; cooling and heating systems; ventilation and air conditioning systems and the like. The combinations according the present invention can prevent disadvantageous effects such as decay, discoloration or mold.

The combinations according to the present invention are particularly effective against powdery mildews; rusts; leafspot species; early blights and molds; especially against Septoria, Puccinia, Erysiphe, Pyrenophora and Tapesia in cereals; Phakopsora in soybeans; Hemileia in coffee; Phragmidium in roses; Alternaria in potatoes, tomatoes and cucurbits; Sclerotinia in turf, vegetables, sunflower and oH seed rape; black rot, red fire, powdery mildew, grey mold and dead arm disease in vine; Botrytis cinerea in fruits; Monilinia spp. in fruits and Penicillium spp. in fruits.

--52-The combinations according to the present invention are furthermore particularly effective against seedborne and soilborne diseases, such as Alternaria spp., Ascochyta spp., Botrytis cinerea, Cercospora spp., Claviceps purpurea, Cochliobolus sativus, Colletotrichum spp., Epicoccum spp., Fusarium graminearum, Fusarium moniliforme, Fusarium oxysporum, Fusarium proliferatum, Fusarium solani, Fusarium subglutinans, Gaumannomyces graminis, Helminthosporium spp., Microdochium nivale, Phoma spp., Pyrenophora graminea, Pyricularia oryzae, Rhizoctonia solani, Rhizoctonia cerealis, Scierotinia spp., Septoria spp., Sphacelotheca reilliana, Tilletia spp., Typhula incarnata, Urocystis occulta, Ustilago spp. or Verticillium spp.; in particular against pathogens of cereals, such as wheat, barley, rye or oats, maize; rice; cotton; soybean; turf; sugarbeet; oil seed rape; potatoes; pulse crops, such as peas, lentils or chickpea; and sunflower.

The combinations according to the present invention are furthermore particularly effective against post harvest diseasese such as Botrytis cinerea, Colletotrichum musae, Curvularia lunata, Fusarium semitecum, Geotrichum candidum, Monilinia fructicola, Monilinia fructigena, Monilinia laxa, Mucor piriformis, Penicilium italicum, Penicilium solitum, Penicillium digitatum or Penicillium expansum in particular against pathogens of fruits, such as pomefruits, for example apples and pears, stone fruits, for example peaches and plums, citrus, melons, papaya, kiwi, mango, berries, for example strawberries, avocados, pomegranates and bananas, and nuts.

The amount of a combination of the invention to be applied, will depend on various factors, such as the compounds employed; the subject of the treatment, such as, for example plants, soil or seeds; the type of treatment, such as, for example spraying, dusting or seed dressing; the purpose of the treatment, such as, for example prophylactic or therapeutic; the type of fungi to be controlled or the application time.

It has been found that the use of components B) in combination with the compound of formula I surprisingly and substantially enhance the effectiveness of the latter against fungi, and vice versa. Additionally, the method of the invention is effective against a wider spectrum of such fungi that can be combated with the active ingredients of this method, when used solely.

The active ingredient mixture of the compounds of formula I selected from table 1 with active ingredients B) described above comprises a compound selected from table I and an active ingredient as described above preferably in a mixing ratio of from 1000:1 to 1:1000, CspeCay from 50:1 to i:G0, moi speiaiiy iii a ratio of from 20:1 to i:2u, even more especially from 10:1 to 1:10, very especially from 5:1 and 1:5, special preference being given to a ratio of from 2:1 to 1:2, and a ratio of from 4:1 to 2:1 being likewise preferred, above all in a ratio of 1:1, or 5:1, or 5:2, or 5:3, or 5:4, or4:1, or4:2, or4:3, or 3:1, or 3:2, or 2:1, or 1:5, or 2:5, or 3:5, or 4:5, or 1:4, or 2:4, or 3:4, or 1:3, or 2:3, or 1:2, or 1:600, or 1:300, or 1:150, or 1:35, or 2:35, or 4:35, or 1:75, or 2:75, or 4:75, or 1:6000, or 1:3000, or 1:1500, or 1:350, or 2:350, or 4:350, or 1:750, or 2:750, or 4:750. Those mixing ratios are understood to include, on the one hand, ratios by weight and also, on other hand, molar ratios.

The mixtures comprising a compound of formula I selected from table 1 and one or more active ingredients as described above can be applied, for example, in a single "ready-mix" form, in a combined spray mixture composed from separate formulations of the single active ingredient components, such as a "tank-mix", and in a combined use of the single active ingredients when applied in a sequential manner, i.e. one after the other with a reasonably short period, such as a few hours or days. The order of applying the compounds of formula I selected from table I and the active ingredients as described above is not essential for The synergistic activity of the combination is apparent from the fact that the fungicidal activity of the composition of A) + B) is greater than the sum of the fungicidal activities of A) and B).

The method of the invention comprises applying to the useful plants, the locus thereof or propagation material thereof in admixture or separately, a synergistically effective aggregate amount of a component A) and a component B).

Some of said combinations according to the invention have a systemic action and can be used as foliar, soil and seed treatment fungicides.

With the combinations according to the invention it is possible to inhibit or destroy the phytopathogenic microorganisms which occur in plants or in parts of plants (fruit, blossoms, leaves, stems, tubers, roots) in different useful plants, while at the same time the parts of plants which grow later are also protected from attack by phytopathogenic microorganisms.

The combinations of the present invention are of particular interest for controlling a large number of fungi in vrous usefui p!nts or thr seeds, pec.iaiiy in fieid crops such as potatoes, tobacco and sugarbeets, and wheat, rye, barley, oats, rice, maize, lawns, cotton, soybeans, oil seed rape, pulse crops, sunflower, coffee, sugarcane, fruit and ornamentals in horticulture and viticulture, in vegetables such as cucumbers, beans and cucurbits.

The combinations according to the invention are applied by treating the fungi, the useful plants, the locus thereof, the propagation material thereof, the natural substances of plant and/or animal origin, which have been taken from the natural life cycle, and/or their processed forms, or the industrial materials threatened by fungus attack with a combination of components A) and B) in a synergistically effective amount.

The combinations according to the invention may be applied before or after infection of the useful plants, the propagation material thereof, the natural substances of plant and/or animal origin, which have been taken from the natural life cycle, and/or their processed forms, or the industrial materials by the fungi.

The combinations according to the invention are particularly useful for controlling the following plant diseases: Alternaria species in fruit and vegetables, Ascochyta species in pulse crops, Botrytis cinerea in strawberries, tomatoes, sunflower, pulse crops, vegetables and grapes, Cercospora arachidicola in peanuts, Cochijobolus sativus in cereals, Colletotrichum species in pulse crops, Erysiphe species in cereals, Erysiphe cichoracearum and Sphaerotheca fuliginea in cucurbits, Fusarium species in cereals and maize, Gäumannomyces graminis in cereals and lawns, Helminthosporium species in maize, rice and potatoes, Hemileia vastatrix on coffee, Microdochium species in wheat and rye, Phakopsora species in soybean, Puccinia species in cereals, broadleaf crops and perrenial plants, Pseudocercosporella species in cereals, Phragmidium mucronatum in roses, Podosphaera species in fruits, Pyrenophora species in barley, Pyricularia oryzae in rice, Ramularia collo-cygni in barley, Rhizoctonia species in cotton, soybean, cereals, maize, potatoes, rice and lawns, Rhynchosporium secalis in barley and rye, Scierotinia species in lawns, lettuce, vegetables and oil seed rape, Septoria species in cereals, soybean and vegetables, Sphacelotheca reilliana in maize, Tilletia species in cereals, Uncinula necator, Guignardia bidwellii and Phomopsis viticola in vines, Urocystis occulta in rye, Ustilago species in cereals and maize, Venturia species in fruits, Monilinia species on fruits, Penicillium species on citrus and apples.

The combinations according to the invention are preventively and/or curatively valuable ac-tive ingredients in the field of pest control, even at low rates of application, which have a very favorable biocidal spectrum and are well tolerated by warm-blooded species, fish and plants.

The active ingredients according to the invention which are partially known for their insecticidal action act against all or individual developmental stages of normally sensitive, but also resistant, animal pests, such as insects or representatives of the order Acarina. The insecticidal or acaricidal activity of the combinations according to the invention can manifest itself directly, i.e. in destruction of the pests, which takes place either immediately or only after some time has elapsed, for example during ecdysis, or indirectly, for example in a reduced oviposition and/or hatching rate, a good activity corresponding to a destruction rate (mortality) of at least 50 to 60%.

Examples of the abovementioned animal pests are: from the order Acarina, for example, Acarus siro, Aceria sheldoni, Aculus schlechtendali, Amblyomma spp., Argas spp., Boophi- lus spp.. Brevipalous spp, B.ryob pr3eccc, Ccptrftnerus pp., Chorioptes spp., Derma- nyssus galiinae, Eotetranychus carpini, Eriophyes spp., Hyalomma spp., Ixodes Spp., Oly- gonychus pratensis, Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polypha-gotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Tarsonemus spp. and Tetranychus spp.; from the order Anoplura, for example, Haematopinus spp., Linognathus spp., Pediculus spp., Pemphigus spp. and Phylloxera spp.; from the order Coleoptera, for example, Agriotes spp., Anthonomus spp., Atomaria linearis, Chaetocnema tibialis, Cosmopolites spp, Curculio spp., Dermestes spp., Diabrotica spp., Epilachna spp., Eremnus spp., Leptinotarsa decemlineata, Lissorhoptrus spp., Melolontha spp., Orycaephilus spp., Otiorhynchus spp., Phlyctinus spp., Popillia spp., Psylliodes spp., Rhizopertha spp., Scarabeidae, Sitophilus spp., Sitotroga spp., Tenebrio spp., Tribolium spp. and Trogoderma spp.; from the order Diptera, for example, Aedes spp., Antherigona soccata, Biblo hortulanus, Calliphora erythrocephala, Ceratitis spp., Chrysomyia spp., Culex spp., Cuterebra spp., Dacus spp., Drosophila melanogaster, Fannia spp., Gastrophilus spp., Glossina spp., Hypoderma spp., Hyppobosca spp., Liriomyza spp., Lucilia spp., Melanagromyza spp., Musca spp., Oestrus spp., Orseolia spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp., Rhagoletis pomonella, Sciara spp., Stomoxys spp., Tabanus spp., Tannia spp. and Tipula spp.; from the order Heteroptera, for example, Cimex spp., Distantiella theobroma, Dysdercus spp., Euchistus spp., Eurygaster spp., Lep- tocorjsa spp., Nezara spp., Piesma spp., Rhodnius spp., Sahibergella singularis, Scotino-phara spp. and Triatoma spp.; from the order Homoptera, for example, Aleurothrixus floccosus, Aleyrodes brassicae, Aonidiella spp., Aphididae, Aphis spp., Aspi-diotus spp., Bemisia tabaci, Ceroplaster spp., Chrysomphalus aonidium, Chrysomphalus dictyospermi, Coccus hesperidum, Empoasca spp., Eriosoma larigerum, Erythroneura spp., Gascardia spp., Laodelphax spp., Lecanium corni, Lepidosaphes spp., Macrosiphus spp., Myzus spp., Nephotettix spp., Nilaparvata spp., Parlatoria spp., Pemphigus spp., Planococ-cus spp., Pseudaulacaspis spp., Pseudococcus spp., Psylla spp., Pulvinaria aethiopica, Quadraspidiotus spp., Rhopalosiphum spp., Saissetia spp., Scaphoideus spp., Schizaphis spp., Sitobion spp., Trialeurodes vaporariorum, Trioza erytreae and Unaspis citri; from the order Hymenoptera, for example, Acromyrmex. Atta spp Cephus spp., Dprcn app., aprhJIldde, Giipinia polytoma, Hoplo-campa spp., Lasius spp., Monomorium pharaonis, Neodiprion spp., Solenopsis spp. and Vespa spp.; from the order Isoptera, for example, Reticulitermes spp.; from the order Lepidoptera, for example, Acleris spp., Adoxophyes spp., Aegeria spp., Agrotis spp., Alabama argillaceae, Amylois spp., Anticarsja gernmataiis, Archips spp., Argyrotaenia spp., Autographa spp., Busseota fusca, Cadra cautella, Carposina nipponensis, Chilo spp., Choristoneura spp., Clysia ambi-guella, Cnaphalocrocis spp., Cnephasia spp., Cochylis spp., Coleophora spp., Crocidolomia binotalis, Cryptophlebia leucotreta, Cydia spp., Diatraea spp., Diparopsis castanea, Earias spp., Ephestia spp., Eucosma spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Gra-pholita spp., Hedya nubiferana, Heliothis spp., Hellula undalis, Hyphantria cunea, Keiferia lycopersicella, Leucoptera scitella, Lithocollethis spp., Lobesia botrana, Lymantria spp., Ly-onetia spp., Malacosoma spp., Mamestra brassicae, Manduca sexta, Operophtera spp., Ostrinia nubflalis, Pammene spp., Pandemjs spp., Panolis flammea, Pectinophora gossypi- ela, Phthorimaea operculella, Pieris rapae, Pieris spp., Plutella xylostella, Prays spp., Scir-pophaga spp., Sesamia spp., Sparganothis spp., Spodoptera spp., Synanthedon spp., Thaumetopoea spp., Tortrjx spp., Trichoplusia ni and Yponomeuta spp.; from the order Maiophaga, for example, Damalinea spp. and Trichodectes spp.; from the order Orthoptera, for example, Biatta spp., Blattella spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Periplaneta spp. and Schistocerca spp.; from the order Psocoptera, for example, Liposcelis spp.; from the order Siphonaptera, for example, Ceratophyllus spp., Ctenocephalides spp. and Xenopsylla cheopis; from the order Thysanoptera, for example, Frankliniella spp., Hercinothrips spp., Scirtothrips aurantii, Taeniothrips spp., Thrips palmi and Thrips tabaci; from the order Thysanura, for example, Lepisma saccharina; nematodes, for example root knot nematodes, stem eelworms and foliar nematodes; cpecaUy!-!etercder spp., for xamp HLeiodera schacht,i, ileterodora avenae and Heterodora trifolii; Globodera spp., for example Globodera rostochiensis; Meloidogyne spp., for example Meloidogyne incoginita and Meloidogyne javanica; Radopholus spp., for example Radopholus similis; Pratylenchus, for example Pratylenchus neglectans and Pratylenchus penetrans; Tylenchulus, for example Tylenchulus semipenetrans; Longidorus, Trichodorus, Xiphinema, Ditylenchus, Aphelenchoides and Anguina; crucifer flea beetles (Phyllotreta spp.); root maggots (Delia spp,) and cabbage seedpod weevil (Ceutorhynchus spp.).

The combinations according to the invention can be used for controlling, i. e. containing or destroying, animal pests of the abovementioned type which occur on useful plants in agriculture, in horticulture and in forests, or on organs of useful plants, such as fruits, flowers, foliage, stalks, tubers or roots, and in some cases even on organs of useful plants which are formed at a later point in time remain protected against these animal pests.

When applied to the useful plants the compound of formula I is applied at a rate of 5 to 2000 g a.i./ha, particularly 10 to 1000 g a.i./ha, e.g. 50, 75, 100 or 200 g a.i./ha, in association with 1 to 5000 g a.i.Iha, particularly 2 to 2000 g a.i./ha, e.g. 100, 250, 500, 800, 1000, 1500 g a.i./ha of a compound of component B), depending on the class of chemical employed as component B).

In agricultural practice the application rates of the combination according to the invention depend on the type of effect desired, and typically range from 20 to 4000 g of total combination per hectare.

When the combinations of the present invention are used for treating seed, rates of 0.001 to g of a compound of formula I per kg of seed, preferably from 0.01 to I Og per kg of seed, and 0.001 to 50 g of a compound of component B), per kg of seed, preferably from 0.01 to lOg per kg of seed, are generally sufficient.

The invention also provides fungicidal compositions comprising a combination of components A) and B) according to claim 1 in a synergistically effective amount, together with an agriculturally acceptable carrier, and optionally a surfactant. In said compositions, the WeiQii IdIlU of A) to B) is between 1000:1 and 1:1000.

The composition of the invention may be employed in any conventional form, for example in the form of a twin pack, a powder for dry seed treatment (DS), an emulsion for seed treatment (ES), a flowabje concentrate for seed treatment (FS), a solution for seed treatment (LS), a water dispersible powder for seed treatment (WS), a capsule suspension for seed treatment (CE), a gel for seed treatment (GF), an emulsion concentrate (EC), a suspension concentrate (SC), a suspo-emulsion (SE), a capsule suspension (CS), a water dispersible granule (WG), an emulsifiable granule (EG), an emulsion, water in oil (EO), an emulsion, oil in water (EW), a micro-emulsion (ME), an oil dispersion (00), an oil miscible flowable (OF), an oil miscible liquid (OL), a soluble concentrate (SL), an ultra-low volume suspension (SU), an ultra-low volume liquid (UL), a technical concentrate (TK), a dispersible concentrate (DC), a wettable powder (WP) or any technically feasible formulation in combination with agriculturally acceptable adjuvants.

Such compositions may be produced in conventional manner, e.g. by mixing the active ingredients with appropriate formulation inerts (diluents, solvents, fillers and optionally other formulating ingredients such as surfactants, biocides, anti-freeze, stickers, thickeners and compounds that provide adjuvancy effects). Also conventional slow release formulations may be employed where long lasting efficacy is intended. Particularly formulations to be applied in spraying forms, such as water dispersible concentrates (e.g. EC, SC, DC, OD, SE, EW, EO and the like), wettable powders and granules, may contain surfactants such as wetting and dispersing agents and other compounds that provide adjuvancy effects, e.g. the condensation product of formaldehyde with naphthalene sulphonate, an alkylarylsulphonate, a lignin sulphonate, a fatty alkyl sulphate, and ethoxylated alkylphenol and an ethoxylated fatty alcohol.

A seed dressing formulation is applied in a manner known per se to the seeds employing the combination of the invention and a diluent in suitable seed dressing formulation form, e.g. as an aqueous suspension or in a dry powder form having good adherence to the seeds. Such seed dressing formulations are known in the art. Seed dressing formulations may contain the single active ingredients or the combination of active ingredients in encapsulated form, e.g. as slow release capsules or microcapsules.

gerer, th fur iriuiaiiuns include from 0.01 to 9U'Yo by weight ot active agent, from 0 to 20% agriculturally acceptable surfactant and 10 to 99.99% solid or liquid formulation inerts and adjuvant(s), the active agent consisting of at least the compound of formula I together 5 with a compound of component B), and optionally other active agents, particularly microbiocides or conservatives or the like. Concentrated forms of compositions generally contain in between about 2 and 80%, preferably between about 5 and 70% by weight of active agent. Application forms of formulation may for example contain from 0.01 to 20% by weight, preferably from 0.01 to 5% by weight of active agent. Whereas commercial products will preferably be formulated as concentrates, the end user will normally employ diluted formulations.

The Examples which follow serve to illustrate the invention, "active ingredient" denoting a mixture of compound I and a compound of component B) in a specific mixing ratio.

Formulation Examples

Wettable powders a) b) c) active ingredient [I: comp B) = 1:3(a), 1:2(b), 1:1(c)] 25% 50 % 75 % sodium lignosulfonate 5 % 5 % -sodium lauryl sulfate 3 % -5 % sodium diisobutylnaphthalenesulfonate -6 % 10 % phenol polyethylene glycol ether -2 % - (7-8 mol of ethylene oxide) highly dispersed silicic acid 5% 10% 10% Kaolin 62 % 27 % -The active ingredient is thoroughly mixed with the adjuvants and the mixture is thoroughly ground in a suitable mill, affording wettable powders that can be diluted with water to give suspensions of the desired concentration.

Powders for dry seed treatment a) b) c) active ingredient [I: comp B) = 1:3(a), 1:2(b), 1:1(c)] 25% 50% 75% light mineral oil 5 % 5 % 5 % highly dispersed silicic acid 5 % 5 % - Kaolin 65 % 40 % -Tajurjj -20 The active ingredient is thoroughly mixed with the adjuvants and the mixture is thoroughly ground in a suitable mill, affording powders that can be used directly for seed treatment.

Emulsifiable concentrate active ingredient (I: comp B) = 1:6) 10% octyiphenol polyethylene glycol ether 3 % (4-5 mol of ethylene oxide) calcium dodecylbenzenesulfonate 3 % castor oil polyglycol ether (35 mol of ethylene oxide) 4 % Cyclohexanone 30 % xylene mixture 50 % Emulsions of any required dilution, which can be used in plant protection, can be obtained from this concentrate by dilution with water.

Dusts a) b) c) Active ingredient [I: comp B) = 1:6(a), 1:2(b), 1:10(c)] 5 % 6% 4% talcum 95 % -- Kaolin -94% -mineral filler --96 % Ready-for-use dusts are obtained by mixing the active ingredient with the carrier and grinding the mixture in a suitable mill. Such powders can also be used for dry dressings for seed.

Extruder granules Active ingredient (I: comp B) = 2:1) 15 % sodium lignosulfonate 2 % carboxymethylcellulose 1 % Kaolin 82 % The active ingredient is mixed and ground with the adjuvants, and the mixture is moistened with water. The mixture is extruded and then dried in a stream of air.

pted granules Active ingredient (I:comp B) = 1:10) 8% pyethyene 9yc0 (muL wL 200) 3 % Kaolin 89 % The finely ground active ingredient is uniformly applied, in a mixer, to the kaolin moistened with polyethylene glycol. Non-dusty coated granules are obtained in this manner.

SusDension concentrate active ingredient (I: comp B) = 1:8) 40 % propylene glycol 10 % nonylphenol polyethylene glycol ether (15 mol of ethylene oxide) 6 % Sodium lignosulfonate 10 % carboxymethylcellulose I % silicone oil (in the form of a 75 % emulsion in water) 1 % Water 32 % The finely ground active ingredient is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water. Using such dilutions, living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion.

Flowable concentrate for seed treatment active ingredient (I: comp B) = 1:8) 40 % propylene glycol 5 % copolymer butanol POIEO 2 % tristyrenephenole with 10-20 moles EQ 2 % 1,2-benzisothiazolin-3-one (in the form of a 20% solution in 0.5 % water) monoazo-pigment calcium salt 5 % Silicone oil (in the form of a 75 % emulsion in water) 0.2 % Water 45.3 % The finely ground active ingredient is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water. Using such dilutions, living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or i in mo r Slow Release Capsule Suspension 28 parts of a combination of the compound of formula I and a compound of component B), or of each of these compounds separately, are mixed with 2 parts of an aromatic solvent and 7 parts of toluene diisocyanate/polymethylenepolyphenyljsocyanatemixture (8:1). This mixture is emulsified in a mixture of 1.2 parts of polyvinylalcohol, 0.05 parts of a defoamer and 51.6 parts of water until the desired particle size is achieved. To this emulsion a mixture of 2.8 parts 1,6-diaminohexane in 5.3 parts of water is added. The mixture is agitated until the polymerization reaction is completed.

The obtained capsule suspension is stabilized by adding 0.25 parts of a thickener and 3 parts of a dispersing agent. The capsule suspension formulation contains 28% of the active ingredients. The medium capsule diameter is 8-15 microns.

The resulting formulation is applied to seeds as an aqueous suspension in an apparatus suitable for that purpose.

Biological Examples

A synergistic effect exists whenever the action of an active ingredient combination is greater than the sum of the actions of the individual components.

The action to be expected E for a given active ingredient combination obeys the so-called COLBY formula and can be calculated as follows (COLBY, S.R. "Calculating synergistic and antagonistic responses of herbicide combination". Weeds, Vol. 15, pages 20-22; 1967): ppm = milligrams of active ingredient (= a.i.) per liter of spray mixture X = % action by active ingredient A) using p ppm of active ingredient Y % action by active ingredient B) using q ppm of active ingredient.

According to COLBY, the expected (additive) action of active ingredients A)+B) using p+q ppm of active ingredient is E = X + Y -X.Y If the action actually observed (0) is greater than the expected action (E), then the action of the combination is super-additive, i.e. there is a synergistic effect. In mathematical terms the synergism factor SF corresponds to OlE. In the agricultural practice an SF of �=1.2 indicates significant improvement over the purely complementary addition of activities (expected r.tivitv wh!e n SF of O.O - t1cai a)pIIeaLIon rouiine signals a loss of activity compared to the expected activity.