GB2452566A - A radiation curable, nail coating composition - Google Patents
A radiation curable, nail coating composition Download PDFInfo
- Publication number
- GB2452566A GB2452566A GB0717563A GB0717563A GB2452566A GB 2452566 A GB2452566 A GB 2452566A GB 0717563 A GB0717563 A GB 0717563A GB 0717563 A GB0717563 A GB 0717563A GB 2452566 A GB2452566 A GB 2452566A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- composition
- radiation curable
- pigment
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000005855 radiation Effects 0.000 title claims abstract description 26
- 239000008199 coating composition Substances 0.000 title claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 238000000576 coating method Methods 0.000 claims abstract description 27
- 239000003921 oil Substances 0.000 claims abstract description 23
- 239000000049 pigment Substances 0.000 claims abstract description 20
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 11
- 238000003860 storage Methods 0.000 claims abstract description 5
- 241000273930 Brevoortia tyrannus Species 0.000 claims abstract description 3
- 235000004347 Perilla Nutrition 0.000 claims abstract description 3
- 244000124853 Perilla frutescens Species 0.000 claims abstract description 3
- 241001125046 Sardina pilchardus Species 0.000 claims abstract description 3
- 235000019512 sardine Nutrition 0.000 claims abstract description 3
- 239000003549 soybean oil Substances 0.000 claims abstract description 3
- 239000002383 tung oil Substances 0.000 claims abstract description 3
- 235000019198 oils Nutrition 0.000 claims description 21
- 238000001035 drying Methods 0.000 claims description 12
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- -1 thiol compound Chemical class 0.000 claims description 3
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 235000021323 fish oil Nutrition 0.000 claims description 2
- 239000000944 linseed oil Substances 0.000 claims description 2
- 235000021388 linseed oil Nutrition 0.000 claims description 2
- 239000003346 palm kernel oil Substances 0.000 claims description 2
- 235000019865 palm kernel oil Nutrition 0.000 claims description 2
- 235000005713 safflower oil Nutrition 0.000 claims description 2
- 239000003813 safflower oil Substances 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 241000251468 Actinopterygii Species 0.000 abstract 1
- 244000020518 Carthamus tinctorius Species 0.000 abstract 1
- 235000003255 Carthamus tinctorius Nutrition 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- 241000219146 Gossypium Species 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- 235000004443 Ricinus communis Nutrition 0.000 abstract 1
- 235000019688 fish Nutrition 0.000 abstract 1
- 235000004426 flaxseed Nutrition 0.000 abstract 1
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract 1
- 210000000282 nail Anatomy 0.000 description 20
- 239000002537 cosmetic Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 7
- 239000000975 dye Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000004922 lacquer Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000012505 colouration Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000019612 pigmentation Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- HGSFSBSPBVBPNY-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] 2-sulfanylpropanoate Chemical compound CC(S)C(=O)OCC(CO)(CO)CO HGSFSBSPBVBPNY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001668 ameliorated effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- UXWSUTBOOHDZIL-UHFFFAOYSA-N bis(1-hydroxycyclohexyl)methanone Chemical compound C1CCCCC1(O)C(=O)C1(O)CCCCC1 UXWSUTBOOHDZIL-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010954 commercial manufacturing process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- NLCKLZIHJQEMCU-UHFFFAOYSA-N cyano prop-2-enoate Chemical class C=CC(=O)OC#N NLCKLZIHJQEMCU-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 210000004905 finger nail Anatomy 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 210000004906 toe nail Anatomy 0.000 description 1
- 229940096522 trimethylolpropane triacrylate Drugs 0.000 description 1
- 125000005314 unsaturated fatty acid group Chemical group 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/81—Preparation or application process involves irradiation
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Zoology (AREA)
- Cosmetics (AREA)
Abstract
A radiation curable, nail coating composition comprising a radiation curable substance, at least one dye and/or pigment dissolved and/or dispersed in the composition to impart a colour and a means for causing the dye and/or pigment to remain homogeneously distributed throughout the composition during storage, application and curing of the coating. Said means for causing dye/pigment homogeneity may be an oil or derivatised oil, including castor, cotton, fish, linseed, menhaden, oiticaca, palm kernel, perilla, safflower, sardine, soybean or tung oils. The radiation curable substance may comprise at least one thiol group.
Description
Title: Nail Coatings The present invention relates to nail coatings and particularly to coloured radiation curable nail coatings. By the term "nail" we also include extensions to nails as well as artificial and false nails.
The decoration and colouration of fingernails, toenails and artificial nail extensions rely, almost exclusively, on a number of well established techniques: (1) applying polymer based, pigmented nail lacquers in a solvent or solvents by a coating process and then subsequently evaporating the solvent or solvents (2) mixing, applying and thermally curing two part (liquid and powder) acrylic components and (3) applying by a coating process ethylenically unsaturated, radiation (ultraviolet) curable gels or topcoats and subsequently curing the coating under a low intensity ultraviolet light source for 2 -5 minutes. S...
To achieve the desired combination of high covering power ie high *::::* pigmentation or colouration, strong durability and high gloss finish, the : application of conventional nail lacquers as in (1) above is often followed by the application and curing of a non pigmented, transparent clear or lightly : coloured ultraviolet curable top coat as in (3) above. Alternatively, to * achieve merely a transparent lightly coloured or glitter coating effect, ultraviolet curable coatings are often applied alone and then cured as in (3) above.
In the cases mentioned, because the ultraviolet curable compositions are inhibited from curing by air at the top surface of the coating, the final, desired very high gloss surface finish is achieved in an additional subsequent process by wiping away traces of incompletely cured material with a solvent soaked cloth or pad. The light colouration of the ultraviolet curable topcoats and gels is usually achieved by the dissolution of dyes at parts per million in the formulations. Higher levels of dyes or pigments reduce the transmission of radiation into the coating during curing and lead to slower or incomplete cure and a layer of un-reacted material at the coating surface. These effects are detrimental to the appearance and durability of the coated nail finish especially after the subsequent solvent wiping treatment.
It is an object of the present invention to provide coloured, radiation curable compositions which may be applied to natural or artificial nails and cured by exposure to low intensity ultraviolet light for of the order of 2-5 minutes to provide dry to touch, immediately glossy, durable decorative coatings of high covering power and over fully comparable ranges of colours and shades and effects to those currently provided by conventional polymer based, solvent drying nail lacquers. In decorative nail coatings such colours, shades and effects are generally achieved through pigmentation and/or the addition of other heterogeneous components such as reflective, refractive, pearlescent, metallic, holographic and/or nano particulates. Hereinafter such additional heterogeneous components are referenced by and are included in the terms "pigment", "pigmented", "pigmentation" etc. ***S * * S...
: It is a fundamental requirement of the commercial manufacturing process : * and for the customer-supplied cosmetic end product that the ultraviolet * : curable coating composition be adequately stable in all respects so that the * product is commercially viable and the product retains its specified characteristics and application properties for a defined and acceptable shelf-life.
In respect to pigmented coatings it is essential that the dispersed pigment particles do not settle, agglomerate or aggregate, ie that adequate pigment a dispersion is maintained. If this is not the case, the coating would become non-homogeneous and the colouring and covering power of the composition would be significantly reduced, rendering the product unusable. It is well known in the art that the addition of surface active and/or dispersing agents and polymers helps to maintain adequate pigment dispersion stability in various media (eg. aqueous, solvent, polymer solution and radiation curable compositions etc.).The effectiveness and compatibility of such pigment dispersion stabilisation agents is greatly influenced by the specific composition of the media to be pigmented. In addition, in cosmetic applications, all compositions must comply with worldwide cosmetic regulatory requirements and hence the range of suitable components and agents is significantly reduced compared to products for industrial use.
It is a further object of the present invention to provide coloured, radiation curable cosmetic compositions for natural or artificial nails, compliant with cosmetic regulatory requirements, which exhibit outstanding pigment dispersion properties and dispersion storage stability to provide fully comparable ranges of colours and shades and effects to those currently provided by conventional polymer based, solvent drying nail lacquers and excellent shelf life characteristics. *...
In respect of radiation curable coatings, which cross link and or polymerise * by free radical and/or anionic initiation and propagation of ethylenically 1:h unsaturated components (so called "monomers", "oligomers", "unsaturated polymers" etc.), it is essential that cross linking and/or polymerisation does : . not occur in stored coatings via radiation induced or thermal induced * generation of initiating species. In the case of the former possibility, ultraviolet or visible light curable coatings must be stored in containers which do not transmit the relevant activating wavelengths of light and the product must be applied under lighting similarly free from relevant activating wavelengths.
In the case of thermal stability, a wide range of free radical stabilizers are available such as sterically hindered phenolic compounds for instance 2,6-di-t-butyl-p-cresol. Acidic type thermal stabilisers are also available for instance aliphatic/aromatic sulphonic acids and these stabilise anionic initiated components such as cyanoacrylates. All these stabilisers may be added to the compositions. However, as indicated previously, the range of such additives available for use in cosmetic compositions is restricted by cosmetic regulations. Furthermore, in the case of free radically cured compositions, whilst providing improved thermal stability, the presence of free radical stabilizers reduces the rate of curing, which, coupled with the inhibiting effects of oxygen, increases the proportion of unreacted material at the surface of the coating after curing, which in turn results in a tacky, low gloss surface finish. This can be overcome to some extent by increasing the exposure intensity of the light source and/or extending the duration of exposure but neither of these is desirable or practical for providing an acceptable commercial cosmetic process. The effects of oxygen inhibition in ethylenically unsaturated, radiation curable compositions can be ameliorated by the addition of thiol compounds but these in turn reduce thermal stability and shelf-life and require additional chemical stabilization. S.
: It is a further object of the present invention to provide coloured, radiation curable, cosmetic compositions for application to natural or artificial nails, *::::* compliant with cosmetic regulatory requirements, which exhibit a : combination of excellent thermal stability, resistance to premature cross :. linking and polymerisation and excellent shelf life properties and directly * provide dry to touch, immediately glossy cured films after coating and **SI..
* exposure to low intensity ultraviolet light for of the order of 2-5 minutes.
According therefore to the present invention, we provide a radiation curable, nail coating composition comprising a radiation curable substance, at least one dye and/or pigment dissolved and/or dispersed in the composition to impart a colour and means for causing the dye and/or pigment to remain homogeneously distributed throughout the composition during storage, application and curing of the substance.
Preferably the means for causing the dye and/or pigment to remain homogeneously distributed throughout the substance is an oil or derivatised oil.
Suitably the oil is a drying and/or semi drying oil.
Conveniently the oil is selected from one or more of the following: castor oil, dehydrated castor oil, cotton seed oil, fish oil, linseed oil, menhaden oil, oiticaca oil, palm kernel oil, perilla oil, safflower oil, sardine oil, soybean oil and tung oil.
In one embodiment of the invention the radiation curable substance comprises at least one thiol compound of formula X-(SH)n where X represents an organic moiety and n is an integer from 1 to 10.
The invention is based on the fact that it has been unexpectedly found that the use of drying oil and/or semi-drying oil based dye and/or pigment :: dispersions in combination with radiation curable substances and particularly thiol (possibly poly thiol) compounds in ethylenically unsaturated radiation *,,*. sensitive compositions provide stable, highly pigmented, fast curing coatings : with outstanding surface cure characteristics ie dry to touch, immediately glossy, and durable.
* It is believed that the unsaturated fatty acid moiety of the drying or semi-drying oil, which is capable of free radical and oxidative cure, that is, cure at ambient temperature upon exposure to air, reacts during the exposure of the radiation sensitive composition to provide the unexpected and advantageous properties observed.
The compositions may also include additional components known to those skilled in the art of radiation sensitive compositions to confer specific desired properties for particular applications. This includes surface active materials to modify the rheological, and pigment dispersing properties of the coatings which can similarly and advantageously be drying oil/semi drying oil based agents.
A specific but in no way limiting example of the invention will now be given
Example
A nail coating composition was prepared as described below.
Solution A The following were blended together to form a clear, viscous solution:-Ebecryl 263 Aliphatic urethane acrylate resin 500g Trimethylolpropane trimethacrylate 500g :. Pentaerythritol mercaptopropionate 25g Hydroxycyclohexyl ketone 25g 2-Hydroxypropyl methacrylate log * * *** Solution B ** : **: A castor oil dispersion of 40% Red 6 (CI 15850) (20g) and rheological S.....
* additive Thixatrol ST (an organic derivative of castor oil) (2g) were added to trimethylolpropanetriacrylate (200g) and the mixture was stirred at 1000rpm for 120 minutes Solution B was added to Solution A and the mixture was stirred for 1 hour.
The resultant viscous red coating was applied to artificial nail tips in a thin layer and the tips were immediately exposed to light from a UV Exposure Unit for 120 secs. The result was a dry, non-tacky, tough, red coating of high gloss and indistinguishable in appearance from that of a tip coated with conventional solvent based nail lacquer and dried for 10 minutes. Se * * *** * S IS'S 555S * I S...
S
*IS.SS * I * S * S..
S
S SSS5 S
S S
Claims (6)
- Claims 1. A radiation curableq nail coating composition comprising a radiation curable substance, at least one dye and/or pigment dissolved and/or dispersed in the composition to impart a colour and a means for causing the dye and/or pigment to remain homogeneously distributed throughout the composition during storage, application and curing of the coating.
- 2. A coating composition as claimed in claim 1 in which the means for causing the dye and/or pigment to remain homogeneously distributed throughout the composition is an oil or derivatised oil.
- 3. A coating composition as claimed in claim 1 or claim 2 in which the oil is a drying and/or semi drying oil.
- 4. A coating composition as claimed in claim 3 in which the oil is selected from one or more of the following: castor oil, dehydrated castor oil, cotton seed oil, fish oil, linseed oil, menhaden oil, oiticaca oil, palm kernel oil, perilla oil, safflower oil, sardine oil, soybean oil and tung oil. j
- 5. A coating composition as claimed in any of the preceding claims in which the radiation curable substance comprises at least one thiol compound of * formula X-(SH)n where X represents an organic moiety, and n is an integer : from 1 to 10.
- 6. A coating composition substantially as hereinbefore described with ***S.S * reference to the example.Abstract A radiation curable, nail coating composition comprising a radiation curable substance, at least one dye and/or pigment dissolved and/or dispersed in the composition to impart a colour and a means for causing the dye and/or pigment to remain homogeneously distributed throughout the composition during storage, application and curing of the coating. I. bI * * * *. **** * t I... * I... * * ** * * *** * * S
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0717563A GB2452566A (en) | 2007-09-08 | 2007-09-08 | A radiation curable, nail coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0717563A GB2452566A (en) | 2007-09-08 | 2007-09-08 | A radiation curable, nail coating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB0717563D0 GB0717563D0 (en) | 2007-10-17 |
| GB2452566A true GB2452566A (en) | 2009-03-11 |
Family
ID=38640509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB0717563A Withdrawn GB2452566A (en) | 2007-09-08 | 2007-09-08 | A radiation curable, nail coating composition |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2452566A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2496990A (en) * | 2011-11-24 | 2013-05-29 | Chemence Ltd | Nail coating compositions |
| JP2014005260A (en) * | 2012-05-28 | 2014-01-16 | Satoda Kako Kk | Artificial nail raw material composition, method of curing artificial nail raw material composition, method of producing artificial nail, and artificial nail |
| US20140261512A1 (en) * | 2013-03-14 | 2014-09-18 | Esschem | Curable nail composition and methods for strengthening and repairing nails |
| WO2015000470A1 (en) * | 2013-07-04 | 2015-01-08 | Polystone-Chemical Gmbh | Gel for producing a coating for a finger nail |
| EP2547730A4 (en) * | 2010-03-16 | 2015-12-02 | Mycone Dental Supply Company Inc | Method of preparation of radiation-curable colored artificial nail gels |
| WO2016072353A1 (en) * | 2014-11-05 | 2016-05-12 | 株式会社スリーボンド | Photocurable composition for topcoat of nails or artificial nails |
| CN106389157A (en) * | 2016-04-27 | 2017-02-15 | 金华市名仕科技股份有限公司 | Fingernail glaze |
| EP2525773B1 (en) * | 2010-04-14 | 2020-02-12 | Mycone Dental Supply Co. Inc. | Easily appliable, storage stable, radiation-curable, pigmented, artificial nail gel coatings |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5823614A (en) * | 1981-08-03 | 1983-02-12 | Kanebo Ltd | Nail make-up agent |
| US5407666A (en) * | 1993-04-05 | 1995-04-18 | International Beauty Design, Inc. | Removable, hard, durable, nail coating |
| WO2001043579A1 (en) * | 1999-12-17 | 2001-06-21 | Gel Products, Inc. | Radiation curable nail coatings and methods of using same |
| US20040191192A1 (en) * | 2003-03-28 | 2004-09-30 | Blankenbeckler Nicole L. | Nail polish composition and method of making same |
-
2007
- 2007-09-08 GB GB0717563A patent/GB2452566A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5823614A (en) * | 1981-08-03 | 1983-02-12 | Kanebo Ltd | Nail make-up agent |
| US5407666A (en) * | 1993-04-05 | 1995-04-18 | International Beauty Design, Inc. | Removable, hard, durable, nail coating |
| WO2001043579A1 (en) * | 1999-12-17 | 2001-06-21 | Gel Products, Inc. | Radiation curable nail coatings and methods of using same |
| US20040191192A1 (en) * | 2003-03-28 | 2004-09-30 | Blankenbeckler Nicole L. | Nail polish composition and method of making same |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2547730A4 (en) * | 2010-03-16 | 2015-12-02 | Mycone Dental Supply Company Inc | Method of preparation of radiation-curable colored artificial nail gels |
| KR102140135B1 (en) * | 2010-03-16 | 2020-08-03 | 마이콘 덴탈 서플라이 코., 인크. | Method of preparation of radiation-curable colored artificial nail gels |
| KR102048523B1 (en) * | 2010-03-16 | 2019-11-25 | 마이콘 덴탈 서플라이 코., 인크. | Method of preparation of radiation-curable colored artificial nail gels |
| KR20190126446A (en) * | 2010-03-16 | 2019-11-11 | 마이콘 덴탈 서플라이 코., 인크. | Method of preparation of radiation-curable colored artificial nail gels |
| KR20190003834A (en) * | 2010-03-16 | 2019-01-09 | 마이콘 덴탈 서플라이 코., 인크. | Method of preparation of radiation-curable colored artificial nail gels |
| EP2525773B1 (en) * | 2010-04-14 | 2020-02-12 | Mycone Dental Supply Co. Inc. | Easily appliable, storage stable, radiation-curable, pigmented, artificial nail gel coatings |
| CN104066420A (en) * | 2011-11-24 | 2014-09-24 | 彻美斯有限公司 | Nail polish |
| GB2496990B (en) * | 2011-11-24 | 2014-10-01 | Chemence Ltd | Nail polish |
| WO2013076511A2 (en) | 2011-11-24 | 2013-05-30 | Chemence Limited | Nail polish |
| US9623268B2 (en) | 2011-11-24 | 2017-04-18 | Chemence Limited | Nail polish |
| WO2013076511A3 (en) * | 2011-11-24 | 2014-01-09 | Chemence Limited | Nail polish |
| GB2496990A (en) * | 2011-11-24 | 2013-05-29 | Chemence Ltd | Nail coating compositions |
| JP2014005260A (en) * | 2012-05-28 | 2014-01-16 | Satoda Kako Kk | Artificial nail raw material composition, method of curing artificial nail raw material composition, method of producing artificial nail, and artificial nail |
| US11691034B2 (en) | 2013-03-14 | 2023-07-04 | Famous Names, Llc | Methods for strengthening and repairing nails using curable compositions |
| US20140261512A1 (en) * | 2013-03-14 | 2014-09-18 | Esschem | Curable nail composition and methods for strengthening and repairing nails |
| WO2015000470A1 (en) * | 2013-07-04 | 2015-01-08 | Polystone-Chemical Gmbh | Gel for producing a coating for a finger nail |
| CN107072924A (en) * | 2014-11-05 | 2017-08-18 | 三键有限公司 | Nail or the finish paint Photocurable composition of artificial nails |
| JPWO2016072353A1 (en) * | 2014-11-05 | 2017-08-17 | 株式会社スリーボンド | Photocurable composition for nail or artificial nail topcoat |
| CN107072924B (en) * | 2014-11-05 | 2020-08-14 | 三键有限公司 | Photocurable composition for top coat of nail or artificial nail |
| WO2016072353A1 (en) * | 2014-11-05 | 2016-05-12 | 株式会社スリーボンド | Photocurable composition for topcoat of nails or artificial nails |
| CN106389157A (en) * | 2016-04-27 | 2017-02-15 | 金华市名仕科技股份有限公司 | Fingernail glaze |
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|---|---|
| GB0717563D0 (en) | 2007-10-17 |
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