GB2401581A - A ceramic label and a method of applying it to a substrate - Google Patents
A ceramic label and a method of applying it to a substrate Download PDFInfo
- Publication number
- GB2401581A GB2401581A GB0407500A GB0407500A GB2401581A GB 2401581 A GB2401581 A GB 2401581A GB 0407500 A GB0407500 A GB 0407500A GB 0407500 A GB0407500 A GB 0407500A GB 2401581 A GB2401581 A GB 2401581A
- Authority
- GB
- United Kingdom
- Prior art keywords
- substrate
- ceramic
- ceramic material
- decal
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/22—Removing surface-material, e.g. by engraving, by etching
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/003—General methods for coating; Devices therefor for hollow ware, e.g. containers
- C03C17/005—Coating the outside
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/24—Ablative recording, e.g. by burning marks; Spark recording
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/32—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/32—After-treatment
- C03C2218/328—Partly or completely removing a coating
- C03C2218/33—Partly or completely removing a coating by etching
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/335—Reverse coating
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
In the method of applying the label (2, 3) to the fireable substrate (5), etched or etchable ceramic material is applied to the substrate (5) and subsequently fired to the substrate (5), the ceramic material being laser etched prior to or after its being fired to the substrate (5). The label is provided from a decal comprising a layer of etchable ceramic material releasably attached to a backing sheet.
Description
CERAMIC LABELLING
DESCRIPTION
This invention relates to ceramic labelling, often in the form of barcodes, more particularly the application of ceramic labels to fireable substrates such as glass phials.
Traditionally, barcodes have been printed on to a form of sticky-backed, paper label and then stuck on to a substrate. These labels are relatively expensive to make. In addition, the labels are easily removed and are prone to damage from abrasion with other articles. The lip, as defined by the edge of the label when attached to the substrate, tends to stick up prominently from the substrate and is especially prone to damage. Damage and undesired removal can also readily occur if these known bar code labels become wet.
The use of ceramic-type barcodes is also known in the art. Again, the barcode is printed on to a type of label which can then be placed on to a substrate and fired. Although the anti-abrasion qualities are improved, as is the adhesion of the label to the substrate, the labels are still prominent because of the thickness of the label itself.
As one of the primary uses of these known barcodes would be for labelling medical apparatus, such as phials, this is a great disadvantage because a prominent edge would provide an area where bacteria can shelter and grow.
There is, therefore, a need for a cheap and effective method for applying labels, such as a barcode or any other indicia, to a fireable substrate.
Such labels can be made of etched or etchable "ceramic
material" which, throughout this specification,
embraces materials such as ceramic ink, ceramic paint lo and ceramic print which can be fired. The label should neither be easily abraded or removed nor should its edge be prominent with respect to the substrate itself. This invention provides such a method and decal for performing that method.
According to a first aspect of the invention, there is provided a method of applying a ceramic label to a fireable substrate, the method comprising applying to the substrate an etched or etchable ceramic material, as herein defined, and firing the material to the substrate, wherein the ceramic material is laser etched prior to or after its being fired to the substrate.
The ceramic material may be applied directly to the substrate in any suitable manner, for example, as a continuous layer for subsequent etching before or after its being fired to the substrate.
Another ceramic material may be provided as a layer intermediate the now outer ceramic material and and the substrate. That intermediate ceramic material layer may not be etched at all or it may be etched prior to or after firing the outer ceramic layer along with the substrate and the intermediate layer itself.
The ceramic material can also be provided as a decal which might comprise one or more layers of ceramic material on a support sheet, such as paper backing sheet, to which the layer(s) is preferably detachably secured, for example, as in the case of a lo water releasable transfer. The layer or the outer layer may be provided with a film, for example, a thin, lowtemperature film, which facilitates handling of the decal.
The decal can be soaked in water to release the ceramic layer(s) from the support sheet, which is then positioned on the substrate where it is allowed to dry, usually for about twelve hours.
When applying ceramic material directly to the substrate, subsequent layers of laser etchable ceramic material may be applied one on top of the other and allowed to dry. Multiple layers of ceramic material, whether they are applied directly to the substrate or by means of a decal, may be of different colours.
The thickness of each coloured layer is preferably in the region of 50p, so as to prevent or at least substantially reduce undesirable burning through of the laser at the etching stage.
The fireable substrate can be made of any suitable glassware, ceramic or even metal material.
Preferably, however, the substrate is medical glassware, such as phials.
When the label, usually in the form of indicia, such as a barcode, is etched in the ceramic material prior to firing, such etching can be carried out upon the decal. Alternatively, etching can be carried out upon the ceramic material after the decal has been released from its support sheet and applied to the substrate prior to firing. Otherwise, the ceramic material can be etched after it has been fired to the substrate.
Thus, a decal can be laser etched to provide the desired label before its application to the substrate.
Alternatively, the ceramic material can be transferred from the decal, namely released from the backing sheet, on to the substrate, preferably by removing it from a paper backing sheet in water, positioning the ceramic label on the substrate and then allowing it to dry. The ceramic label can then be etched in si to on the substrate and then fired.
Any outer film, such as a thin, low-temperature film, is burnt away during the firing process. Preferably, once the ceramic label has been transferred on to or otherwise applied to the substrate in any of the above-mentioned ways, the ceramic material and substrate should preferably be allowed around twelve hours to dry before firing and/or etching.
When the ceramic material is etched post-firing, it can be transferred on to the substrate, allowed to dry for twelve hours and fired and then etched to produce the desired label.
The laser etching at either stage preferably removes portions of the outermost layer of the ceramic material to produce the desired indicia or other design for the label. Preferably, the indicia are that of a barcode label. The removal of portions of the outermost layer of ceramic material allows corresponding portions of the substrate or lower layer of ceramic material to show through and be revealed.
As indicated hereinabove, a typical example of a fireable substrate is a glass phial. This can be fired according to many different temperature and time regimes. One such regime is to heat up the phial and ceramic material from room temperature to 450 C over a fifteen minute period, followed by a constant temperature period of 560 C for thirty minutes and, finally, a cool-down period of 45 minutes.
2s Once firing and etching, or vice versa, has taken place, a ceramic label so-provided is very firmly attached to the phial and there is very little or no lip defining the edge of the label.
According to a second aspect of the present invention, there is provided a decal for use in applying an etchable ceramic label to a fireable substrate, the decal comprising a layer of etchable ceramic material releasably attached to a backing sheet.
The ceramic material can be etched, preferably by laser, before or after its release from the backing sheet. The backing sheet is preferably a paper sheet.
A film, such as a thin, low-temperature film, may lo be applied to the outer surface of the ceramic material to facilitate handling of the decal but is removed by firing.
The decal may be soaked in water to release the etched or etchable ceramic material layer(s) from the backing sheet for positioning on the substrate.
The thickness of the layer may be in the region of 50u, so as to prevent or at least substantially reduce undesired burning through by the laser at the etching stage.
A third aspect of the present invention resides in a ceramic label decal comprising a layer of etched ceramic material releasably attached to a backing sheet.
Preferably, the ceramic layer has been etched by laser.
The decal may include another ceramic layer intermediate the etched outer ceramic layer and the backing sheet, which may or may not be etchable but may be of different colour to that of the outer layer.
Again, a film which is removed by any subsequent s firing procedure, may be provided on the outer surface of the or the outer ceramic material layer.
Also, the backing sheet may be of paper with the etched ceramic layer(s) being releasable therefrom by, lo say, applying water to the decal.
In order that the invention may be more fully understood, preferred embodiments thereof will now be described, by way of example and with reference to the accompanying drawings in which: Figure 1 is a crosssectional view of a decal in accordance with the second aspect of the invention; Figure 2 is a cross-sectional view of the decal of Figure 1 applied as a label to a glass surface in accordance with the first aspect of the invention; 25Figure 3 is a cross-sectional view of a decal in accordance with the third aspect of the invention; and Figure 4 is a cross-sectional view of the decal of Figure 3 applied as a label to a glass surface in accordance with the first aspect of the invention.
In Figure 1, a decal, indicated generally at 10, comprises a paper backing sheet 1, a layer of white ceramic print 2, a layer of black ceramic print 3 and a thin film 4. A ceramic label per se derived from the decal 10 comprises the two layers of ceramic print 2,3.
Once the decal 10 is soaked in water, the ceramic label 2,3 and the thin film 4 are released from the paper backing sheet 1, in order that the ceramic label 2,3 can be transferred on to a surface of a glass phial (not shown).
Figure 2 shows the ceramic label 2,3 as released IS from the sheet 1 and transferred on to the surface of a glass phial 5 and fired. The thin film 4 has been removed by the firing process leaving behind the ceramic label 2,3 carrying the print layers.
In addition, the outer ceramic print 3 has been laser etched to the required design to remove portions 6 of the black ceramic print layer 3, so that the white ceramic print layer 2 can show through. Thus, a typical form of a barcode, namely a white background 2s with a black marking thereon, is provided on the substrate phial 5.
Figure 3 is another embodiment of the invention, whereby laser etching has taken place while the ceramic label was in the form of the decal 10 described above in relation to Figure 1. Thus, the laser etching process has removed portions 7 of both the thin film 4 and the black ceramic print layer 3, so that the white ceramic print 2 can show through.
In Figure 4, the etched ceramic label 2,3 and thin film 4 have been transferred on to the glass surface 5.
The ceramic label 2,3 is fired to the glass surface 5 by heating the soapplied ceramic label 2,3 lo and substrate 5 from room temperature to 450 C over a fifteen minute period, followed by a constant temperature period of 560 C for thirty minutes and, finally, a cool-down period of 45 minutes.
Claims (41)
1. A method of applying a ceramic label to a fireable substrate, the method comprising applying to the substrate an etched or etchable ceramic material, as herein defined, and firing the material to the substrate, wherein the ceramic material is laser etched prior to or after its being fired to the substrate.
2. A method according to claim l, wherein the ceramic material is applied directly to the substrate.
3. A method according to claim l or 2, wherein the ceramic material is applied to the substrate as a continuous layer for subsequent etching before or after its being fired to the substrate.
4. A method according to claim l, 2 or 3, wherein another ceramic material is provided as a layer intermediate the now outer ceramic material and the substrate.
5. A method according to claim 4, wherein the intermediate ceramic material layer is not etched.
6. A method according to claim 4, wherein the intermediate ceramic layer is etched prior to or after firing the outer ceramic layer along with the substrate and the intermediate layer itself.
7. A method according to any preceding claim, wherein the or each ceramic layer, as the case may be, is provided as a decal.
8. A method according to claim 7, wherein the ceramic decal layer comprises one or more layers of ceramic material on a support sheet, such as paper backing sheet.
9. A method according to claim 8, wherein the one or more layers of ceramic material is/are detachably secured to the support sheet.
10. A method according to claim 7, 8 or 9, wherein the ceramic layer or the outer layer, as the case may be, is provided with a film, for example, a thin, low- temperature film, which facilitates handling of the decal.
11. A method according to any of claims 7 to 10, wherein the decal is soaked in water, to release the ceramic layer(s) from the support sheet, and is then positioned on the substrate where it is allowed to dry.
12. A method according to any preceding claim, wherein, when applying ceramic material directly to the substrate, subsequent layers of laser etchable ceramic material are applied one on top of the other and allowed to dry.
13. A method according to any preceding claim, wherein multiple layers of ceramic material, whether they are applied directly to the substrate or by means of a decal, are of different colours.
14. A method according to claim 13, wherein the thickness of each coloured layer is in the region of 50.
lo
15. A method according to any preceding claim, wherein the substrate is glassware or is made of a ceramic or metallic material.
16. A method according to any preceding claim, IS wherein the substrate is medical glassware, such as a phial.
17. A method according to claim 7 or any claim dependent upon claim 7, wherein, when a label, usually in the form of indicia, such as a barcode, is etched in the ceramic material prior to firing, such etching is carried out upon the decal.
18. A method according to claim 7 or any claim 2s dependent upon claim 7, wherein etching is carried out upon the ceramic material after the decal has been released from its support sheet and applied to the substrate prior to firing.
19. A method according to any of claims 1 to 16, wherein the ceramic material is etched after it has been fired to the substrate.
20. A method according to claim 7 or any of claims 8 to 16 when dependent upon claim 7, wherein the ceramic material is transferred from the decal on to the substrate, positioned thereon, allowed to dry, etched in si to on the substrate and then fired.
21. A method according to any preceding claim, wherein, once the ceramic material has been transferred on to or otherwise applied to the substrate, as the case may be, the ceramic material and substrate is allowed about twelve hours to dry before firing and/or etching.
22. A method according to claim 21, wherein, when the ceramic material is etched post-firing, it is transferred on to the substrate, allowed to dry for twelve hours, fired and then etched to produce the desired label.
23. A method according to any preceding claim, wherein the laser etching is carried out to remove portions of the outermost layer of ceramic material, to produce desired indicia or other design for the label.
24. A method according to any preceding claim, wherein portions of the outermost layer of ceramic material are removed to allow corresponding portions of the substrate or lower layer of ceramic material to be exposed and revealed. =
25. A method according to any preceding claim, wherein the substrate is a glass phial.
26. A method according to claim 25, wherein the phial and ceramic material are heated to 450 C over a fifteen minute period, followed by a constant temperature period of 560 C for thirty minutes and, finally, a cool-down period of forty five minutes.
27. A method according to claim 25 or 26, wherein the - so-provided ceramic label is firmly attached to the - phial, with very little or no lip defining the edge of the label.
28. A method of applying a ceramic label to a = substrate, substantially as hereinbefore described.
29. A decal for use in applying an etched or etchable ceramic label to a fireable substrate, the decal comprising a layer of etchable ceramic material releasably attached to a backing sheet. -
30. A decal according to claim 29, wherein ceramic material can be etched, preferably by laser, before or after its release from the backing sheet.
31. A decal according to claim 29 or 30, wherein the backing sheet is a paper sheet.
32. A decal according to claim 29, 30 or 31, wherein a film, such as a thin, low-temperature film, has been applied to the outer surface of the ceramic material, to facilitate handling of the decal, but is removable by firing.
33. A decal according to any of claims 29 to 32 lo capable of being soaked in water to release the etched or etchable ceramic material layer(s) from the backing sheet for subsequent positioning on the substrate.
34. A decal according to any of claims 29 to 33, wherein thickness of the ceramic layer is in the region of 50,u.
35. A ceramic label decal comprising a layer of etched ceramic material releasably attached to a I backing sheet.
36. A decal according to claim 35, wherein the ceramic layer has been etched by laser.
2s
37. A decal according to claim 35 or 36 including another ceramic layer intermediate the etched outer ceramic layer and the backing sheet.
38. A decal according to claim 37, wherein the intermediate ceramic layer is of a different colour to that of the outer ceramic layer.
39. A decal according to any of claims 35 to 38, wherein a film, which is removed by any subsequent firing, is provided on the outer surface of the or the outer ceramic material layer, as the case may be.
40. A decal according to any of claims 35 to 39, wherein the backing sheet is of paper with the etched ceramic layer(s) being releasable therefrom.
41. A ceramic label decal substantially as hereinbefore described with reference to the accompanying drawings.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0407500A GB2401581B (en) | 2004-04-02 | 2004-04-02 | Ceramic labelling |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0407500A GB2401581B (en) | 2004-04-02 | 2004-04-02 | Ceramic labelling |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB0407500D0 GB0407500D0 (en) | 2004-05-05 |
| GB2401581A true GB2401581A (en) | 2004-11-17 |
| GB2401581B GB2401581B (en) | 2005-12-28 |
Family
ID=32247739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB0407500A Expired - Fee Related GB2401581B (en) | 2004-04-02 | 2004-04-02 | Ceramic labelling |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2401581B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010029402A1 (en) * | 2008-09-10 | 2010-03-18 | Onofrio Acone | Bottle shields |
| US9844951B2 (en) | 2010-04-30 | 2017-12-19 | Becton Dickinson France | Method for marking a transparent container |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5683786A (en) * | 1996-04-25 | 1997-11-04 | Health Card Technologies, Inc. | Microscope slide having bar code indicia inscribed thereon |
| US20020102362A1 (en) * | 2001-02-01 | 2002-08-01 | Jinghua Schneider | Process for providing permanent, solvent and caustic proof, multi-colored sample identification markings directly onto glass laboratory container surfaces |
| US20030039590A1 (en) * | 2001-08-27 | 2003-02-27 | Lodge Daniel B. | Glass vials with data matrix codes and method of making the same |
-
2004
- 2004-04-02 GB GB0407500A patent/GB2401581B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5683786A (en) * | 1996-04-25 | 1997-11-04 | Health Card Technologies, Inc. | Microscope slide having bar code indicia inscribed thereon |
| US20020102362A1 (en) * | 2001-02-01 | 2002-08-01 | Jinghua Schneider | Process for providing permanent, solvent and caustic proof, multi-colored sample identification markings directly onto glass laboratory container surfaces |
| US20030039590A1 (en) * | 2001-08-27 | 2003-02-27 | Lodge Daniel B. | Glass vials with data matrix codes and method of making the same |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010029402A1 (en) * | 2008-09-10 | 2010-03-18 | Onofrio Acone | Bottle shields |
| US8071199B2 (en) | 2008-09-10 | 2011-12-06 | Onofrio Acone | Bottle labels |
| RU2507603C2 (en) * | 2008-09-10 | 2014-02-20 | Онофрио АКОНЕ | Bottle labels |
| US9844951B2 (en) | 2010-04-30 | 2017-12-19 | Becton Dickinson France | Method for marking a transparent container |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2401581B (en) | 2005-12-28 |
| GB0407500D0 (en) | 2004-05-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4615754A (en) | Substrateless decorative emblem and method of making | |
| EP0433137B1 (en) | Method for the durable identification of glass sheets, use of the process and vehicle windows with such an identification | |
| CA1319039C (en) | Apparatus and method for manufacture of adhesive label | |
| GB2230492A (en) | Ornamental stickers | |
| RU99122689A (en) | METHOD AND DEVICE FOR PROCESSING GLASS | |
| GB2401581A (en) | A ceramic label and a method of applying it to a substrate | |
| JPH0354591A (en) | Sheet for forming calcination pattern and label for calcination | |
| CZ2001661A3 (en) | Objects with decorated border and process of their manufacture by making use of hot printing process | |
| AU2005244274B2 (en) | Improvements in animal identification marking | |
| EP1526001B1 (en) | Method for decorating objects | |
| ES2217695T3 (en) | Decals | |
| EP1640426A2 (en) | Heat-resistant label | |
| EP0138809B1 (en) | Heat transfer pad decoration and substrates therefor | |
| KR100310386B1 (en) | Manufacturing process of plate-glass for decoration by using transfer paper | |
| JP2002264548A (en) | BAKING SHEET FOR Al AN ITS BAKING SHEET | |
| JPS6322696A (en) | Heating discharge offset transfer material and method of decorating article by using said material | |
| EP1438730A1 (en) | Marking of hot glass using a carrier ribbon bearing a laser ablated coating pattern | |
| US6555258B1 (en) | Image transfer sheet | |
| JPH0542799A (en) | Painting method for mesh tone fabric | |
| TW200615167A (en) | Film ink support media and sublimation decoration process | |
| JPH07299955A (en) | Hot stamp printing method to metal product | |
| KR100283446B1 (en) | Identifing object for heat treated products and forming method thereof | |
| KR100389685B1 (en) | Transcription Film Of Candle And Method For Preparing Thereof | |
| JP2004181729A (en) | Cover sheet and its manufacturing method | |
| JPH0737596B2 (en) | Transfer material exhibiting metallic luster and method for producing substrate having metallic luster |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20100402 |