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GB2251978A - Forming a colour filter on a semiconductor substrate having a pixel matrix - Google Patents

Forming a colour filter on a semiconductor substrate having a pixel matrix Download PDF

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Publication number
GB2251978A
GB2251978A GB9114523A GB9114523A GB2251978A GB 2251978 A GB2251978 A GB 2251978A GB 9114523 A GB9114523 A GB 9114523A GB 9114523 A GB9114523 A GB 9114523A GB 2251978 A GB2251978 A GB 2251978A
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GB
United Kingdom
Prior art keywords
layer
forming
lens
inter
colour filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB9114523A
Other versions
GB9114523D0 (en
Inventor
No Seok Yang
Han Su Park
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Samsung Electronics Co Ltd
Original Assignee
Samsung Electronics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung Electronics Co Ltd filed Critical Samsung Electronics Co Ltd
Publication of GB9114523D0 publication Critical patent/GB9114523D0/en
Publication of GB2251978A publication Critical patent/GB2251978A/en
Withdrawn legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/30Coatings
    • H10F77/306Coatings for devices having potential barriers
    • H10F77/331Coatings for devices having potential barriers for filtering or shielding light, e.g. multicolour filters for photodetectors
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/40Optical elements or arrangements
    • H10F77/413Optical elements or arrangements directly associated or integrated with the devices, e.g. back reflectors

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Optical Filters (AREA)
  • Solid State Image Pick-Up Elements (AREA)
  • Liquid Crystal (AREA)

Abstract

A method of manufacturing a colour filter on a flat surface (39) of a semiconductor substrate having a matrix of pixels (32, 33, 34) comprises forming a discrete colour filter region (41, 45, 49) on the flat surface over each of the pixels and forming at least one inter-layer 43, 47, 51 between the discrete colour filter regions, forming a lens layer on the uppermost inter-layer, and forming lens patterns 54 which are flat at each portion corresponding to a respective underlying pixel and have a varying thickness at the edges of these flat portions, by photographically exposing and developing the lens layer, and forming lenses by thermal treatment of the lens patterns. This minimizes the effect of temperature in the thermal process, and allows the focal length of the lenses to be selected regardless of the thickness of the lenses. <IMAGE>

Description

FORMING A COLOUR FILTER ON A SEMICONDUCTOR SUBSTRATE HAVING A PIXEL MATRIX The present invention relates to a method of manufacturing a colour filter on a flat surface of a semiconductor substrate having a matrix of pixels, and to an image-sensing device formed thereby, and is particulary useful in a solid-state colour image-sensing device.
Recently, solid state image-sensing devices, which are able to replace electron tubes and thus are spotlighted as the image-sensing devices of the next generation, have been able to achieve colour sensing by forming a colour filter at an upper surface of an optical -to-electrical converter region.
As for the particular image-sensing element, MOS transistors, phototransistors, and CCDs (Charged Coupled Devices) have mainly been used.
In the image-sensing devices using CCDs, which are mainly used in small-sized movie camera, many pixels are required, and they need a high sensitivity, hence the development of a technology for forming focusing lenses on the colour filter.
The colour filters are divided into two types: an organic filter made by dyeing organic materials such as casein and gelatine, and an inorganic filter using optical interference.
Figures 1 (A)-(D) show the steps of manufacturing a conventional colour filter.
Referring to Fig. 1(A), a silicon substrate 1 has concave and convex portions. At the surfaces of the concave portions, photodiodes 2, 3 and 4 are formed, and at the convex surfaces a conducting layer 5 and an insulating layer 7 are formed.
On this CCD, a smoothing layer 9 of a transparent material such as polyimide is formed, and on this smoothing layer 9 a dyed layer 11, which is made of casein or gelatine containing a specified amount of ammonium, is formed over the region corresponding to the photodiode 2. The dyed layer 11 is dyed with magenta, cyan or yellow. Next, an inter-layer 13 is formed by depositing polyimide (the same composition as the smoothing layer) on the entire surface of the above-described structure.
Referring to Fig. 1(B), dyed layers 15 and 19 and inter-layers 17 and 21 are sequentially formed on the inter-layer 13 in the same manner. The inter-layer 17 is used to prevent the colours from mixing between the dyed layers 15 and 19.
Subsequently, a lens layer 23 is formed by depositing a light-sensitive material such as acrylic resin and then exposing this photographically. In this lens layer 23, only the parts other than the parts over the photodiodes 2, 3 and 4 are exposed, by using a mask 25.
Referring to Fig. 1(C), the exposed parts are removed by a development process after removing the mask 25, and thus lens patterns 24 are formed on the photodiodes 2, 3 and 4.
Referring to Fig. 1(D), lenses 27, 28 and 29 corresponding to respective photodiodes 2, 3 and 4 are formed by a thermal process. During this thermal process, the edges of the lens patterns 24 begin to melt. The thermal process is undertaken at a low and then a high temperature. Under the low temperature process, the edges of the lens patterns 24 are made molten; then by the high-temperature process, the lenses 27, 28 and 29 are made gradually to adopt a specified curvature over their whole surface.
On the other hand, the focal length of the lenses is changed as a function of their thickness. That is, if the lenses 27, 28 and 29 are thick, the focal length is short, and if the lenses are thin, the focal length is long.
Thus, if the focal length is to be long, the lenses 27, 28 and 29 must be formed thinly by the high temperature process, while if the focal length is to be short, the lenses 27, 28 and 29 must be formed thickly by the low-temperature process.
The problem is that if the thermal process is carried out at the high temperature to form thin lenses, the shape variation is severe, thereby making the process unstable; while if the process is carried out at the low temperature to form thick lenses, the shape of the lenses is not complete, thereby making the formation of lenses difficult.
The present invention has been made in consideration of this problem, and provides a method of manufacturing a colour filter on a flat surface of a semiconductor substrate having a matrix of pixels beneath that surface, comprising the steps of: forming a discrete colour filter region on the flat surface over each of said pixels and forming at least one inter-layer between the discrete colour filter regions, forming a light-sensitive lens layer on a flat surface of the inter-layer, or of the highest inter-layer, and forming lens patterns, which are flat at each portion corresponding to a respective underlying pixel and have a multiple level thickness gradation at the edges of these flat portions, by exposing and developing said lens layer, and forming lenses by thermal treatment of said lens patterns.
The invention also provides a colour image-sensing device manufactured in accordance with this method, comprising a semiconductor substrate having a matrix of pixels being optical-to-electrical converters, colour filter regions over respective pixels and separated by at least one inter-layer, and a layer of lenses over the, or the uppermost, inter-layer, each lens being centred over a corresponding pixel and having a flat portion, of uniform thickness, overlying the pixel, and an edge portion whose surface has a predetermined radius of curvature.
With the benefit of the invention, the yield may be improved by making the processes for forming lenses stable in such a manner as to minimize the effect of the temperature of the thermal process. Further, the sensitivity of the pixels may be improved by controlling the focal length of the lenses, which is possible regardless of their thickness, by changing their shape.
A preferred embodiment of the present invention will now material as that of the first inter-layer 43.
After this, a lens layer 53 of novolac light-sensitive resin is formed. The lens layer 53 is then exposed to light through a mask 55 of which the light transmissivity varies as a function of position. The light transmissivity, in this example, varies stepwise with a repeated periodic pattern as shown in detail in the graph at the bottom of Figure 2(B), which shows the transmissivity increasing from 0% stepwise to 50%, 75% and 90%, and then decreasing by the same steps in reverse. (This represents a diametric section through each lens pattern, which is circular in plan).
In the mask 55, the portions corresponding to the photodiodes 32, 33 and 34 have zero transmissivity, and, with increasing distance from the centres of those portions, the transmissivity increases.
As shown in Figure 2(C), lens patterns 54 are formed by developing the lens layer 53 after removing the mask 55. Thus the lens patterns 54 are formed by a photographic technique.
At this time, the lens patterns 54 are formed with step-shaped edges, because the degree of exposure in the pattern is differentiated by the mask 55 and thus the degree of removal of material from the lens layer 53 is on the upper surface of the smoothing layer 39, as a layer 0.4-1.2pm in thickness.
Subsequently, a first dyed layer 41 is formed by spreading a dyeing material on the entire surface of the structure. This dyeing material reacts with the dyed layer pattern, and is therefore held there, but does not react on the smoothing layer 39. The unwanted dyeing material remaining on the smoothing layer 39 is then removed by deionized water. The dyeing material used for the first dyed layer 41 is one of the colours magenta, cyan and yellow. For example, the first dyed layer 41 is dyed with magenta to obtain the magenta spectrum.
Next, a first inter-layer 43 of lpm thickness is formed on the entire surface of structure using the same material as for the smoothing layer 39.
As shown in Figure 2(B), second and third dyed layers 45 and 49 at positions corresponding to the second and third photodiodes 33 and 34 are formed on the first inter-layer 43 in the same manner, and they are dyed respectively with cyan and yellow for obtaining the cyan and yellow spectra.
Second and third inter-layers 47 and 51 are formed on the first and third dyed layers 45 and 49 using the same material as that of the first inter-layer 43.
After this, a lens layer 53 of novolac light-sensitive resin is formed. The lens layer 53 is then exposed to light through a mask 55 of which the light transmissivity varies as a function of position. The light transmissivity, in this example, varies stepwise with a repeated periodic pattern as shown in detail in the graph at the bottom of Figure 2(B), which shows the transmissivity increasing from 0% stepwise to 50%, 75% and 90%, and then decreasing by the same steps in reverse. (This represents a diametric section through each lens pattern, which is circular in plan).
In the mask 55, the portions corresponding to the photodiodes 32, 33 and 34 have zero transmissivity, and, with increasing distance from the centres of those portions, the transmissivity increases.
As shown in Figure 2(C), lens patterns 54 are formed by developing the lens layer 53 after removing the mask 55. Thus the lens patterns 54 are formed by a photographic technique.
At this time, the lens patterns 54 are formed with step-shaped edges, because the degree of exposure in the pattern is differentiated by the mask 55 and thus the degree of removal of material from the lens layer 53 is differentiated in the developing process of the lens layer 53.
The lens patterns 54 are flat at the portions corresponding to the photodiodes 32, 33 and 34, since material from these portions is not removed; as the distance increases from there, the removal ratio increases.
As shown in Figure 2(D), first, second, and third lenses 57, 58 and 59 are formed by a thermal process from the lens patterns 54.
With this thermal process, since the step heights are relatively small, the portions of each lens, apart from the central flat portions, are smoothly curved and have a predetermined radius of curvature.
The flat portions of the lenses 57, 58 and 59 transmit linearly the incident light without reflection and the other portions refract the incident light to focus it on the photodiodes 32, 33 and 34.
To summarize, the focal length of each lens is changed according to the structure of the colour filters, and the portions of the lens patterns other than the portions corresponding to the photodiodes are formed with a step-shape by using a mask which controls the amount of exposure as a function of position.
Next, by a low-temperature thermal process, the central lens portions corresponding to the photodiodes of the lens patterns are left flat, while the other portions are smoothed by melting to adopt a specified radius of curvature.
These lenses can have a predetermined focal length by controlling the radius of curvature regardless of the thickness of the lenses.
Thus, the present invention improves the yield by minimizing the effect of the thermal process temperature in forming the lenses and also improves the sensitivity of the colour filter since it can easily control the focal length regardless of the thickness of lens.
Although the invention has been illustrated in terms of an improvement in a specific manufacturing method using three dyed layers separated by inter-layers, it will be appreciated that alternative colour filter structures are feasible, provided that they match the pixels and present a flat surface for the lens formation.
Moreover, the nature of the gradation of thickness of the lenses is selectable - it may be stepped, but continuous gradation, still providing multiple level thickness, is also feasible. Further, although the edges of the lenses are said to have a predetermined radius of curvature, it will be appreciated that the same advantages may be obtained where these edge surfaces are not precisely part-spherical, ie where their curvature is predetermined but is not of a unique radius.

Claims (13)

1. A method of manufacturing a colour filter on a flat surface of a semiconductor substrate having a matrix of pixels beneath that surface, comprising the steps of: forming a discrete colour filter region on the flat surface over each of said pixels and forming at least one inter-layer between the discrete colour filter regions, forming a light sensitive lens layer on a flat surface of the inter-layer, or of the highest inter-layer, and forming lens patterns, which are flat at each portion corresponding to a respective underlying pixel and have a multiple level thickness gradation at the edges of these flat portions, by exposing and developing said lens layer, and forming lenses by thermal treatment of said lens patterns.
2. A method according to Claim 1, in which the substrate is an image-sensing device of which each pixel is an optical-to-electrical converter.
3. A method according to Claim 1 or 2, comprising the previous step of forming a smoothing layer over the matrix of pixels thereby to form the said flat surface.
4. A method according to Claim 1, 2 or 3, in which the colour filter-forming step comprises: forming a dyed layer on the flat surface over one of said pixels and forming an inter-layer on said dyed layer; and repeating the above process at least twice for forming further successive dyed layers and inter-layers separating the dyed layers; whereby dyed layers of at least three different colours are formed on the semiconductor substrate over respective pixels.
5. A method according to any preceding claim, wherein the lens layer is exposed through a mask which has a transmissivity varying gradually with position even over a single lens pattern.
6. A method according to Claim 5, wherein said mask has substantially zero transmissivity at the portions overlying respective pixels, while the transmissivity increases with distance from those portions.
7. A method according to any preceding claim, wherein said thermal treatment is carried out at the low temperature typical of conventional thick-lens formation# as described herein with reference to Figures 1(A) to 1(D).
8. A method according to any preceding claim, wherein said lenses are flat at each portion overlying a respective pixel, and have a predetermined radius of curvature at the other portions, corresponding to the edges of the lenses.
9. A method according to any preceding claim, in which the said thickness gradation of the lens patterns, before thermal treatment, is a stepwise gradation with at least three steps of thickness.
10. A method according to any preceding claim, in which the colour filter regions are formed photolithographically using a selective dyeing process over the said flat surface or over a respective inter-layer, as the case may be.
11. A colour image-sensing device manufactured in accordance with any preceding method, comprising a semiconductor substrate having a matrix of pixels being optical-to-electrical converters, colour filter regions over respective pixels and separated by at least one inter-layer, and a layer of lenses over the, or the uppermost, inter-layer, each lens being centred over a corresponding pixel and having a flat portion, of uniform thickness, overlying the pixel, and an edge portion whose surface has a predetermined radius of curvature.
12. A method of manufacturing a colour filter on a semiconductor substrate, substantially as described herein with reference to Figures 2(A) and 2(B) of the accompanying drawings.
13. An image-sensing device substantially as described herein with reference to Figures 2(A) and 2(B) of the accompanying drawings.
GB9114523A 1990-12-31 1991-07-05 Forming a colour filter on a semiconductor substrate having a pixel matrix Withdrawn GB2251978A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019900022929A KR930003687B1 (en) 1990-12-31 1990-12-31 Manufacturing method of color filter

Publications (2)

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GB9114523D0 GB9114523D0 (en) 1991-08-21
GB2251978A true GB2251978A (en) 1992-07-22

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KR (1) KR930003687B1 (en)
GB (1) GB2251978A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0593197A1 (en) * 1992-10-06 1994-04-20 Matsushita Electronics Corporation Solid state colour imaging device and method of manufacturing the same
CN1089951C (en) * 1994-01-28 2002-08-28 松下电器产业株式会社 Solid photographic device and manufacture of same
US20100162813A1 (en) * 2008-12-27 2010-07-01 Hon Hai Precision Industry Co., Ltd. Sensor assembly

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0124025A2 (en) * 1983-04-26 1984-11-07 Kabushiki Kaisha Toshiba Solid-state color imaging device and process for fabricating the same
EP0242663A2 (en) * 1986-04-18 1987-10-28 EASTMAN KODAK COMPANY (a New Jersey corporation) Light sensing devices with lenticular pixels

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5968967A (en) * 1982-10-13 1984-04-19 Toshiba Corp Manufacturing method of solid-state imaging device
JPH01246505A (en) * 1988-03-29 1989-10-02 Canon Inc Solid state image pickup element
JPH02282702A (en) * 1989-04-25 1990-11-20 Seiko Epson Corp Manufacture of lens array

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0124025A2 (en) * 1983-04-26 1984-11-07 Kabushiki Kaisha Toshiba Solid-state color imaging device and process for fabricating the same
EP0242663A2 (en) * 1986-04-18 1987-10-28 EASTMAN KODAK COMPANY (a New Jersey corporation) Light sensing devices with lenticular pixels

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0593197A1 (en) * 1992-10-06 1994-04-20 Matsushita Electronics Corporation Solid state colour imaging device and method of manufacturing the same
US5404005A (en) * 1992-10-06 1995-04-04 Matsushita Electronic Corporation Solid state imaging device and method of manufacturing same
CN1089951C (en) * 1994-01-28 2002-08-28 松下电器产业株式会社 Solid photographic device and manufacture of same
US20100162813A1 (en) * 2008-12-27 2010-07-01 Hon Hai Precision Industry Co., Ltd. Sensor assembly
US8253242B2 (en) * 2008-12-27 2012-08-28 Hon Hai Precision Industry Co., Ltd. Sensor assembly

Also Published As

Publication number Publication date
KR930003687B1 (en) 1993-05-08
GB9114523D0 (en) 1991-08-21
KR920013001A (en) 1992-07-28
JPH04234705A (en) 1992-08-24

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