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GB2146354A - Tin-base bearing alloy with refined structure - Google Patents

Tin-base bearing alloy with refined structure Download PDF

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Publication number
GB2146354A
GB2146354A GB08422934A GB8422934A GB2146354A GB 2146354 A GB2146354 A GB 2146354A GB 08422934 A GB08422934 A GB 08422934A GB 8422934 A GB8422934 A GB 8422934A GB 2146354 A GB2146354 A GB 2146354A
Authority
GB
United Kingdom
Prior art keywords
oto
alloy
tin
titanium
balance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08422934A
Other versions
GB2146354B (en
GB8422934D0 (en
Inventor
John Ernest Lanham
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Darchem Ltd
Original Assignee
Darchem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Darchem Ltd filed Critical Darchem Ltd
Publication of GB8422934D0 publication Critical patent/GB8422934D0/en
Publication of GB2146354A publication Critical patent/GB2146354A/en
Application granted granted Critical
Publication of GB2146354B publication Critical patent/GB2146354B/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C13/00—Alloys based on tin
    • C22C13/02—Alloys based on tin with antimony or bismuth as the next major constituent
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02—Parts of sliding-contact bearings
    • F16C33/04—Brasses; Bushes; Linings
    • F16C33/06—Sliding surface mainly made of metal
    • F16C33/12—Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • F16C33/121—Use of special materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2204/00—Metallic materials; Alloys
    • F16C2204/30—Alloys based on one of tin, lead, antimony, bismuth, indium, e.g. materials for providing sliding surfaces
    • F16C2204/34—Alloys based on tin
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2326/00—Articles relating to transporting
    • F16C2326/30—Ships, e.g. propelling shafts and bearings therefor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2360/00—Engines or pumps
    • F16C2360/22—Internal combustion engines

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Sliding-Contact Bearings (AREA)

Abstract

A tin based white metal bearing alloy in which the microstructure of the alloy is refined by the addition of 0.005 to 0.5% Titanium by weight. The alloy contains in wt.% Sb 2-15 Cu 1-10 Cd 0-7 Ni 0-2 Ag 0-1 Pb trace-15 Ti 0.005-0.5 Te/Be 0-1 Co 0-1 Mg 0-1 Mn 0-2 As 0-1 Sn balance

Description

SPECIFICATION Improved materials This invention relates two improved alloy materials for use as bearing materials in which the main component is tin.
We have found that, by the use or Titanium in tin-containing white metal bearing alloys the microstructure of the alloy is refined and, as such, the bearing properties of the alloy are greatly improved.
Therefore, according to the present invention there is provided an alloy comprising, by weight, 2.0 to 15.0% Antimony; 1.0 to 10.0% Copper; O to 7.0% Cadmium; O to 2.0% Nickel; O to 1.0% Silver; trace to 15.0% Lead; 0.005 to 0.5% Titanium; Oto 1 % Tellumium or Beryllium; Oto 1% Cobalt; Oto 1% Magnesium; Oto 2% Manganese, Oto 1 % Arsenic and Tin the balance.
More particularly the invention includes an alloy comprising, by weight, 2.0 to 15.0% Antimony; 1.0 to 10.0% Copper; Oto 2.0% Cadmium; O to 2.0% Nickel; Oto 1.0% Silver; trace to 5% Lead; 0.005 to 0.5 Titanium; and Tin the balance. The alloy is preferably a tin-based white metal alloy in which the balance of tin exceeds 75% byweight.
According to another aspect of the invention there is provided a tin-based white metal alloy in which the nucleation within the alloy is seeded by the addition of 0.005 to 0.5% Titanium.
Thefollowing are examples of alloys in accordance with the invention: EXAMPLE 1 Antimony (Sb) 7.60% Copper (Cu13.10% Titanium (Ti) 0.18% Lead (Pb) trace Tin (Sn) balance EXAMPLE 2 Antimony (Sb) 8.70% Copper (Cu) 3.85% Cadmium (Cd) 1.00% Silver (Ag) 0.05% Nickel (Ni) 0.17% Titanium (Ti) 0.22% Lead (Pb) trace Tin (Sn) balance The alloys disclosed have an improved refined grain structure which has the advantagethatthe bearing properties ofthe alloys are enhanced.
The Titanium component has been found to produce the refinement of Cu6Sn5 distribution over a range of cooling conditions. This is believed to stem fromthecrystal structure lattice parameters of the Titanium crystals offering a closer match to the Cu6Sn5 structure for seed purposes in the nucleation process.
The preferred bearing alloys may be used in applications such as bearings for marine diesel engineswherethe high strength tin-based alloys substantially free of lead provide high standards of performance.
CLAIMS:
1. An alloy comprising, byweight,2.0 to 15.0% Antimony; 1.0to 10.0% Copper; Oto7.0% Cadmium; Oto 2.0% Nickel; Oto 1.0% Silver; trace to 15.0% Lead; 0.005 to 0.5% Titanium; Oto 1 % Tellumium or Beryllium; Oto 1% Cobalt; Oto 1% Magnesium; Oto 2% Manganese, O to 1% Arsenic and Tin the balance.
2. An alloyaccordingto claim 1 comprising Oto 2.0% Cadmium.
3. An alloy according to claim 7 comprising trace to 5.0% Lead.
4. More particularly the invention includes an alloy comprising, by weight, 2.0 to 15.0% Antimony; 1.0 to 10.0% Copper; Oto 2.0% Cadmium; Oto 2.0% Nickel; Oto 1.0% Silver; trace to 5% Lead; 0.005 toO.5 Titanium; and Tin the balance.
5. An alloy according to any one of the preceding claims wherein the balance of Tin exceeds 75% by weight.
6. A tin-based white metal alloy in which the nucleation within the alloy is seeded by the addition of 0.005 to 0.5% Titanium.
7. An alloy as set forth in accordance with any one of Examples 1 or2.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (7)

**WARNING** start of CLMS field may overlap end of DESC **. SPECIFICATION Improved materials This invention relates two improved alloy materials for use as bearing materials in which the main component is tin. We have found that, by the use or Titanium in tin-containing white metal bearing alloys the microstructure of the alloy is refined and, as such, the bearing properties of the alloy are greatly improved. Therefore, according to the present invention there is provided an alloy comprising, by weight, 2.0 to 15.0% Antimony; 1.0 to 10.0% Copper; O to 7.0% Cadmium; O to 2.0% Nickel; O to 1.0% Silver; trace to 15.0% Lead; 0.005 to 0.5% Titanium; Oto 1 % Tellumium or Beryllium; Oto 1% Cobalt; Oto 1% Magnesium; Oto 2% Manganese, Oto 1 % Arsenic and Tin the balance. More particularly the invention includes an alloy comprising, by weight, 2.0 to 15.0% Antimony; 1.0 to 10.0% Copper; Oto 2.0% Cadmium; O to 2.0% Nickel; Oto 1.0% Silver; trace to 5% Lead; 0.005 to 0.5 Titanium; and Tin the balance. The alloy is preferably a tin-based white metal alloy in which the balance of tin exceeds 75% byweight. According to another aspect of the invention there is provided a tin-based white metal alloy in which the nucleation within the alloy is seeded by the addition of 0.005 to 0.5% Titanium. Thefollowing are examples of alloys in accordance with the invention: EXAMPLE 1 Antimony (Sb) 7.60% Copper (Cu13.10% Titanium (Ti) 0.18% Lead (Pb) trace Tin (Sn) balance EXAMPLE 2 Antimony (Sb) 8.70% Copper (Cu) 3.85% Cadmium (Cd) 1.00% Silver (Ag) 0.05% Nickel (Ni) 0.17% Titanium (Ti) 0.22% Lead (Pb) trace Tin (Sn) balance The alloys disclosed have an improved refined grain structure which has the advantagethatthe bearing properties ofthe alloys are enhanced. The Titanium component has been found to produce the refinement of Cu6Sn5 distribution over a range of cooling conditions. This is believed to stem fromthecrystal structure lattice parameters of the Titanium crystals offering a closer match to the Cu6Sn5 structure for seed purposes in the nucleation process. The preferred bearing alloys may be used in applications such as bearings for marine diesel engineswherethe high strength tin-based alloys substantially free of lead provide high standards of performance. CLAIMS:
1. An alloy comprising, byweight,2.0 to 15.0% Antimony; 1.0to 10.0% Copper; Oto7.0% Cadmium; Oto 2.0% Nickel; Oto 1.0% Silver; trace to 15.0% Lead; 0.005 to 0.5% Titanium; Oto 1 % Tellumium or Beryllium; Oto 1% Cobalt; Oto 1% Magnesium; Oto 2% Manganese, O to 1% Arsenic and Tin the balance.
2. An alloyaccordingto claim 1 comprising Oto 2.0% Cadmium.
3. An alloy according to claim 7 comprising trace to 5.0% Lead.
4. More particularly the invention includes an alloy comprising, by weight, 2.0 to 15.0% Antimony; 1.0 to 10.0% Copper; Oto 2.0% Cadmium; Oto 2.0% Nickel; Oto 1.0% Silver; trace to 5% Lead; 0.005 toO.5 Titanium; and Tin the balance.
5. An alloy according to any one of the preceding claims wherein the balance of Tin exceeds 75% by weight.
6. A tin-based white metal alloy in which the nucleation within the alloy is seeded by the addition of 0.005 to 0.5% Titanium.
7. An alloy as set forth in accordance with any one of Examples 1 or2.
GB08422934A 1983-09-12 1984-09-11 Tin-base bearing alloy with refined structure Expired GB2146354B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB838324353A GB8324353D0 (en) 1983-09-12 1983-09-12 Materials

Publications (3)

Publication Number Publication Date
GB8422934D0 GB8422934D0 (en) 1984-10-17
GB2146354A true GB2146354A (en) 1985-04-17
GB2146354B GB2146354B (en) 1986-12-10

Family

ID=10548642

Family Applications (2)

Application Number Title Priority Date Filing Date
GB838324353A Pending GB8324353D0 (en) 1983-09-12 1983-09-12 Materials
GB08422934A Expired GB2146354B (en) 1983-09-12 1984-09-11 Tin-base bearing alloy with refined structure

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB838324353A Pending GB8324353D0 (en) 1983-09-12 1983-09-12 Materials

Country Status (2)

Country Link
JP (1) JPS61238935A (en)
GB (2) GB8324353D0 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5102748A (en) * 1991-05-03 1992-04-07 Taracorp, Inc. Non-leaded solders
EP0702095A1 (en) * 1994-08-18 1996-03-20 Billiton Witmetaal B.V. Alloy for a slide bearing or the like, and a bearing based on such an alloy
EP0717121A3 (en) * 1994-11-12 1996-07-03 Elektro Thermit Gmbh
WO1998032886A1 (en) * 1997-01-29 1998-07-30 Alpha Fry Limited Lead-free tin alloy
WO2009108975A1 (en) * 2008-03-03 2009-09-11 Miba Gleitlager Gmbh Plain bearing alloy consisting of a tin-based white metal
WO2013048664A1 (en) 2011-09-30 2013-04-04 Siemens Industry, Inc. White metal babbitt for rolling mill bushing
DE102013006388A1 (en) 2013-04-15 2014-10-16 Zollern Bhw Gleitlager Gmbh & Co. Kg Slide bearing alloy based on tin

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT515099B1 (en) * 2014-01-31 2015-06-15 Miba Gleitlager Gmbh Multilayer plain bearings
CN105750757A (en) * 2016-03-22 2016-07-13 苏州虎伏新材料科技有限公司 Welding material for surfacing to obtain Sn-based babbitt alloy wear-resisting layer
CN105734338B (en) * 2016-03-22 2017-11-24 苏州虎伏新材料科技有限公司 A kind of tin-base babbit and preparation method thereof
JP6998557B2 (en) * 2017-09-29 2022-01-18 パナソニックＩｐマネジメント株式会社 Solder alloy and joint structure using it

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1021975A (en) * 1964-08-27 1966-03-09 Chobei Taguchi Improvement of white metal

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS501687A (en) * 1973-05-07 1975-01-09

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1021975A (en) * 1964-08-27 1966-03-09 Chobei Taguchi Improvement of white metal

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5102748A (en) * 1991-05-03 1992-04-07 Taracorp, Inc. Non-leaded solders
EP0702095A1 (en) * 1994-08-18 1996-03-20 Billiton Witmetaal B.V. Alloy for a slide bearing or the like, and a bearing based on such an alloy
NL9401339A (en) * 1994-08-18 1996-04-01 Billiton Witmetaal Alloy for a plain bearing or the like, and a bearing based on such an alloy.
EP0717121A3 (en) * 1994-11-12 1996-07-03 Elektro Thermit Gmbh
US5705126A (en) * 1994-11-12 1998-01-06 Elektro-Thermit Gmbh Friction bearing alloy
AU685685B2 (en) * 1994-11-12 1998-01-22 Ecka Granulate Gmbh & Co. Kg Friction bearing alloy
WO1998032886A1 (en) * 1997-01-29 1998-07-30 Alpha Fry Limited Lead-free tin alloy
WO2009108975A1 (en) * 2008-03-03 2009-09-11 Miba Gleitlager Gmbh Plain bearing alloy consisting of a tin-based white metal
WO2013048664A1 (en) 2011-09-30 2013-04-04 Siemens Industry, Inc. White metal babbitt for rolling mill bushing
DE102013006388A1 (en) 2013-04-15 2014-10-16 Zollern Bhw Gleitlager Gmbh & Co. Kg Slide bearing alloy based on tin
WO2014169890A1 (en) 2013-04-15 2014-10-23 Zollern Bhw Gleitlager Gmbh & Co. Kg Tin-based sliding bearing alloy
US10190630B2 (en) 2013-04-15 2019-01-29 Zollern Bhw Gleitlager Gmbh & Co. Kg Tin-based sliding bearing alloy

Also Published As

Publication number Publication date
GB2146354B (en) 1986-12-10
JPS61238935A (en) 1986-10-24
GB8422934D0 (en) 1984-10-17
GB8324353D0 (en) 1983-10-12

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Legal Events

Date Code Title Description
732E Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977)
PCNP Patent ceased through non-payment of renewal fee

Effective date: 20010911