GB2093015A - Dry composition for use in a fibre spraying composition - Google Patents
Dry composition for use in a fibre spraying composition Download PDFInfo
- Publication number
- GB2093015A GB2093015A GB82043319A GB8204319A GB2093015A GB 2093015 A GB2093015 A GB 2093015A GB 82043319 A GB82043319 A GB 82043319A GB 8204319 A GB8204319 A GB 8204319A GB 2093015 A GB2093015 A GB 2093015A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- parts
- composition
- bonding agent
- fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 44
- 238000005507 spraying Methods 0.000 title claims abstract description 18
- 239000000835 fiber Substances 0.000 title description 8
- 239000007767 bonding agent Substances 0.000 claims abstract description 23
- 239000004927 clay Substances 0.000 claims abstract description 20
- 239000000919 ceramic Substances 0.000 claims abstract description 19
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 11
- 239000010452 phosphate Substances 0.000 claims abstract description 11
- 239000007787 solid Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052681 coesite Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 229910052682 stishovite Inorganic materials 0.000 claims description 7
- 229910052905 tridymite Inorganic materials 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical class [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000000470 constituent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 229920000609 methyl cellulose Polymers 0.000 description 4
- 239000001923 methylcellulose Substances 0.000 description 4
- 235000010981 methylcellulose Nutrition 0.000 description 4
- 238000005452 bending Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
- F27D1/0003—Linings or walls
- F27D1/0006—Linings or walls formed from bricks or layers with a particular composition or specific characteristics
- F27D1/0009—Comprising ceramic fibre elements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00146—Sprayable or pumpable mixtures
- C04B2111/00155—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00551—Refractory coatings, e.g. for tamping
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Products (AREA)
- Paints Or Removers (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Fertilizers (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Abstract
A dry composition for use in a spraying composition for producing heat-resistant or refractory linings comprises 100 parts by weight ceramic fibres in loosened form, 2 to 20 parts by weight clay and/or other conventional refractory constituents, 0 to 10 parts by weight fire clay powder, 2 to 8 parts by weight phosphate bonding agent, calculated as P2O5 and 1 to 4 parts by weight solid organic bonding agent.
Description
SPECIFICATION
Dry composition for use in a fibre spraying composition
The invention relates to a dry composition for use in fibre spraying compositions for producing refractory or heat-resistant linings.
It is known to use ceramic fibres in so called fibre spraying compositions. For this purpose ceramic fibres and large quantities of water are first mixed and then either sprayed on to walls or on to ceilings with the aid of a spraying device to produce a refractory or heat-resistant lining or they may be sprayed into hollow spaces.
DE-AS 26 18 81 3 discloses fibre spraying compositions which, in addition to a large proportion of inorganic fibres and low proportions of bonding agent and other inorganic additives, additionally contain a chemical additive bonder, whereby these fibre spraying compositions contain additionally 5 to 20% by weight of an oil to avoid the formation of dust.
In another method, dry ceramic fibres and water are fed separately to the head of a spraying device, mixed with one another in the head of this spraying device and then sprayed on to walls or ceilings or sprayed into hollow spaces. Furthermore, it is also known to add further additives such as bonding agent and other conventional additives to the slurry described above of ceramic fibres in water.
Due to the large quantities of water which are required when spraying it is, however, difficult homogeneously to mix these additives, such as a bonding agent and other conventional additives, with the fibres in the spraying device and to obtain a sprayed composition which adheres adequately to the surface on which it is sprayed.
It is an object of the present invention to provide a dry composition or mixture for use as a fibre spraying composition which can be applied to walls of both metal piate and of brickwork in a layer of a thickness of 30 cm. It is a further object that the composition should be capable of being immediately heated to high temperatures without having to be subjected to a prior drying process.
According to the present invention there is provided a dry composition for use in spraying compositions for the production of refractory or heat-resistant linings containing the following components in an intimately mixed state: a) 100 parts by weight ceramic fibres, b) 2 to 20 parts by weight clay and/or Awl203 and/or Si02 and/or aluminium hydroxides and/or magnesia and/or titanium dioxide and/or chromium oxide, c) 0 to 10 parts by weight fire clay powder, d) 2 to 8 parts by weight of a phosphate bonding agent, calculated as P2Os, and e) 1 to 4 parts by weight of a solid organic bonding agent.
The ceramic fibres in the composition in accordance with the invention can be all the conventional fibres of this type, e.g. mineral fibres, such as rock wool, or fibres based on aluminium silicate, preferably with a particularly high Awl203 content in the region of 45 to 95% by weight. Naturally mixtures of different ceramic fibres can also be used.The fibres are, however, preferably based on Al203 and Si02 with at least 40% by weight Awl203 and are preferably capable of being used at temperatures in excess of 1 100'C. This will in general exclude inorganic fibres based on, for instance, basalt, slag and glass and natural asbestos fibres whose use temperature is below 11 00 C, but such fibres may be used as a subsidiary component in addition to those whose use temperature is above 11 00 C.
Advantageously the ceramic fibres are present in loosened form. For this purpose, commercial fibres are put in the state in which they are usually delivered in an impact mixer (e.g. a
Turbulent-Rapid Mixer manufactured by Drais), in which the fibres which are commonly delivered as fibre bundles are converted into loosened fibres. Such an impact mixer comprises a mixing unit with rapidly rotating knife heads by means of which any agglomerates which may be present in conventional fibres, which are frequently partially present in a strongly compressed form, are loosened, without the fibres being thereby unacceptably crushed or comminuted.
The clay present in the composition in accordance with the invention can be a conventional clay or a special bonding clay, e.g. bentonite. This clay is preferably used in an amount of 5 to 20 parts by weight 10 to 100 parts by weight of the ceramic fibres and advantageously 8 to 1 5 parts by weight clay are used.
The components which may be present in the composition in addition to or instead of the clay are, in accordance with the invention, Awl203 and/or Si02 and/or magnesia and/or titanium dioxide and/or chromium oxide, all of which are preferably present in very finely divided form, and/or aluminium hydroxides. These are components whose use is known in the refractory field. The term "very finely divided" used in conjunction with the components referred to above means that these components are present in a very finely ground state or in the colloidal state.
The very finely divided refractory materials preferably have a grain size of less than 50 ym, more preferably less than 10 ym. Particularly when using such materials in the colloidal state, such as colloidal SiO2 or colloidal aluminium oxide, it is possible to use only small quantities of bonding agent, that is to say close to the lower threshold value of 1 part by weight of an organic bonding agent and 2 parts by weight of a phosphate bonding agent. The use of approximately the same parts by weight of phosphate bonding agent and methyl cellulose as organic bonding agent is particularly preferred.It is also particularly advantageous to use a mixture of clay and one or more of the other refractory components referred to above, the quantity of these other refractory components being preferably 1 to 3 parts by weight and the remainder clay so that the amount stipulated in the main claim of 2 to 20 parts by weight of refractory components is present. Additionally 0 to 10 parts by weight fire clay powder are present in the composition in accordance with the invention. This can be any desired finely ground fire clay and preferably the maximum grain size of the powder is < 63 ,um and particularly preferably < 44 ,um.
Additionally 2 to 8 parts by weight and preferably 3 to 6 parts by weight of phosphate bonding agent are present in the composition in accordance with the invention, the given quantities in parts by weight referring to P205 in the bonding agent or mixture of bonding agents. An example of suitable phosphate bonding agents is sodium polyphosphate with a degree of polymerisation of n24 and preferably with a degree of polymerisation of 6 to 10. This sodium polyphosphate is used in solid form. A further phosphate bonding agent is monaluminium phosphate that is a commercial product available in solid ground form.
A solid organic bonding agent is present in the composition in accordance with the invention.
For this purpose all organic bonding agents commonly used in this field may be used, for instance methyl cellulose, sulphite lye or waste or molasses.
In the production of the dry composition in accordance with the invention the individual components are put into a mixer in any desired order. For this purpose a conventional mixer or an impact mixer as was described above can be used. Instead of using fibres which have already been loosened for producing the compositions in accordance with the invention, commercial ceramic fibres can also be put into such an impact mixer together with the other components and the loosening of the ceramic fibres and the intimate mixing with the other components carried out in it simultaneously.
The dry compositions in accordance with the invention can be sprayed with a conventional spraying machine of the type which is common in concrete processing technology. For this, the water necessary for setting is fed to the spray nozzle. Since the compositions in accordance with the invention are in the form of an intimate mixture with bonding agents homogeneously distributed within them the quantity of water which is required is much less than with known dry compositions which can also be sprayed in this manner.
Certain specific embodiments of the invention will now be described in more detail by way of example with reference to the following Examples.
In the Examples ceramic fibres A and B were used which had the following chemical composition:
Fibres A) Al203 = 47%; Si02 = 53%
Fibres B) Awl203 = 95%; Si02 = 5%.
Example I
The following composition was used:
Parts by weight
Ceramic fibres A 100
Bonding clay (with 35% Awl203) 10
Fire clay powder < 63 jum 10
Solid sodium polyphosphate 6
Solid methyl cellulose 2
These compounds were thoroughly mixed for 20 minutes in an Eirich mixer.
The dry mixture was sprayed in a spraying machine, to the nozzle of which it was fed by pressurized air and there mixed with water also fed to the nozzle.
Sprayed thicknesses on perpendicular walls of metal plate of 30 cm could be produced with this composition. The sprayed mass could be heated immediately without particular drying.
Such a sprayed on mass had the properties given in the following table, the different columns containing the properties after heating at a given temperature for a given period of time:
Table I
Freshly 300"C 1000"C 1200"C State sprayed 8 h 12 h 24 h
Weight per unit volume (g/cm3) 0.86 0.57 0.56 0.65
Cold bending strength (N/mm2) n.m. 0.5 0.6 1.3
Cold compression strength (N/mm2) n.m. 0.5 1.0 2.3
Thermal conductivity (W/m OK) at 400"C 0.15
at 600"C 0.18
at 1000on 0.20
at 1100 C0.21 n.m. = not measurable.
Example 2
The following composition was used:
Parts by weight
Ceramic fibres B 75
Ceramic fibres A 25
Bonding clay with 35% Awl203 10
Solid monoaluminium phosphate 6
Solid sodium polyphosphate 2
Methyl cellulose 3
First the ceramic fibres were converted in an impact mixer for 1 5 minutes into loosened fibres. Then the other components were added and mixed for a further 3 minutes in the impact mixer.
After processing in accordance with the method of Example 1 the following properties were measured in the sprayed mass:
Table II
Freshly 300"C 1000"C 1400"C State sprayed 8 h 1 2 h 24 h
Weight per unit volume (g/cm3) 0.6 0.4 0.4 0.5
Cold bending strength (N/mm2) n.m. 0.4 0.4 0.7
Cold compression strength (N/mm2) n.m. 0.5 0.7 2.0
Claims (5)
1. Dry composition for use in spraying compositions for the production of refractory or heatresistant linings containing the following components in an intimately mixed state: a) 100 parts by weight ceramic fibres, b) 2 to 20 parts by weight clay and/or Al203 and/or Si02 and/or aluminium hydroxides and/or magnesia and/or titanium dioxide and/or chromium oxide, c) 0 to 10 parts by weight fire clay powder, d) 2 to 8 parts by weight of a phosphate bonding agent, calculated as P205, and e) 1 to 4 parts by weight of a solid organic bonding agent.
2. Composition as claimed in Claim 1 in which the ceramic fibres are present in loosened form.
3. Composition as claimed in Claim 1 or Claim 2 in which the clay is bentonite.
4. Composition as claimed in any one of Claims 1 to 3 in which the phosphate bonding agent is sodium polyphosphate or monaluminium phosphate.
5. Dry composition for use in spraying compositions for the production of refractory or heat resistant linings substantially as specifically herein described with reference to any one of the accompanying examples.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3105533A DE3105533C2 (en) | 1981-02-16 | 1981-02-16 | Dry matter for use as fiber injection molding compound |
Publications (1)
Publication Number | Publication Date |
---|---|
GB2093015A true GB2093015A (en) | 1982-08-25 |
Family
ID=6124955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB82043319A Withdrawn GB2093015A (en) | 1981-02-16 | 1982-02-15 | Dry composition for use in a fibre spraying composition |
Country Status (12)
Country | Link |
---|---|
JP (1) | JPS57145082A (en) |
BE (1) | BE892034A (en) |
DD (1) | DD202281A5 (en) |
DE (1) | DE3105533C2 (en) |
FR (1) | FR2499968A1 (en) |
GB (1) | GB2093015A (en) |
IT (1) | IT8247786A0 (en) |
NL (1) | NL8200604A (en) |
NO (1) | NO820439L (en) |
PL (1) | PL235101A1 (en) |
SE (1) | SE8200857L (en) |
ZA (1) | ZA821014B (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1985001676A1 (en) * | 1983-10-17 | 1985-04-25 | Manville Service Corporation | Insulation system |
US4547403A (en) * | 1983-10-17 | 1985-10-15 | Manville Service Corporation | Method for applying a layer of fiber on a surface |
US4640848A (en) * | 1985-08-26 | 1987-02-03 | Kennecott Corporation | Spray-applied ceramic fiber insulation |
US4664969A (en) * | 1986-05-30 | 1987-05-12 | Manville Corporation | Method for spray applying a refractory layer on a surface and the layer produced thereby |
US4673594A (en) * | 1984-10-12 | 1987-06-16 | Manville Service Corporation | Method for applying a layer of fiber on a surface and a refractory material produced thereby |
US4737192A (en) * | 1983-10-17 | 1988-04-12 | Manville Service Corporation | Refractory binder, method for making same, and product produced thereby |
US4770707A (en) * | 1984-10-12 | 1988-09-13 | Manville Corporation | Method for forming a layer of refractory fibers on a surface and material produced thereby |
US4822679A (en) * | 1985-08-26 | 1989-04-18 | Stemcor Corporation | Spray-applied ceramic fiber insulation |
US4833025A (en) * | 1988-03-07 | 1989-05-23 | Manville Corporation | Method for applying a refractory layer on a surface and the layer produced thereby |
CN107721397A (en) * | 2017-11-01 | 2018-02-23 | 安徽马钢耐火材料有限公司 | A kind of pink fused alumina chamotte and preparation method thereof |
US20230312415A1 (en) * | 2021-08-24 | 2023-10-05 | Unifrax I Llc | Light weight ceramic aggregates made by agglomerating ceramic fibers |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2133194A5 (en) * | 1971-04-13 | 1972-11-24 | Produits Refractaires | |
DE2230429A1 (en) * | 1972-06-22 | 1974-01-10 | Vyzk Ustav Stavebnich Hmot V B | Large fibre-board prodn - using a starch-phosphoric acid react prod as binder |
FR2349551A1 (en) * | 1976-04-30 | 1977-11-25 | Alsacienne Atom | Porous refractory mouldings resistant to molten aluminium or iron - contain ceramic fibres and e.g. alumina, bonded by metal phosphate |
-
1981
- 1981-02-16 DE DE3105533A patent/DE3105533C2/en not_active Expired
-
1982
- 1982-02-01 JP JP57013433A patent/JPS57145082A/en active Pending
- 1982-02-05 BE BE0/207241A patent/BE892034A/en not_active IP Right Cessation
- 1982-02-12 IT IT8247786A patent/IT8247786A0/en unknown
- 1982-02-12 SE SE8200857A patent/SE8200857L/en not_active Application Discontinuation
- 1982-02-15 DD DD82237420A patent/DD202281A5/en unknown
- 1982-02-15 GB GB82043319A patent/GB2093015A/en not_active Withdrawn
- 1982-02-15 FR FR8202452A patent/FR2499968A1/en not_active Withdrawn
- 1982-02-15 NO NO820439A patent/NO820439L/en unknown
- 1982-02-16 ZA ZA821014A patent/ZA821014B/en unknown
- 1982-02-16 NL NL8200604A patent/NL8200604A/en not_active Application Discontinuation
- 1982-02-16 PL PL23510182A patent/PL235101A1/xx unknown
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1985001676A1 (en) * | 1983-10-17 | 1985-04-25 | Manville Service Corporation | Insulation system |
US4547403A (en) * | 1983-10-17 | 1985-10-15 | Manville Service Corporation | Method for applying a layer of fiber on a surface |
US4737192A (en) * | 1983-10-17 | 1988-04-12 | Manville Service Corporation | Refractory binder, method for making same, and product produced thereby |
US4673594A (en) * | 1984-10-12 | 1987-06-16 | Manville Service Corporation | Method for applying a layer of fiber on a surface and a refractory material produced thereby |
US4770707A (en) * | 1984-10-12 | 1988-09-13 | Manville Corporation | Method for forming a layer of refractory fibers on a surface and material produced thereby |
US4640848A (en) * | 1985-08-26 | 1987-02-03 | Kennecott Corporation | Spray-applied ceramic fiber insulation |
US4822679A (en) * | 1985-08-26 | 1989-04-18 | Stemcor Corporation | Spray-applied ceramic fiber insulation |
US4664969A (en) * | 1986-05-30 | 1987-05-12 | Manville Corporation | Method for spray applying a refractory layer on a surface and the layer produced thereby |
US4833025A (en) * | 1988-03-07 | 1989-05-23 | Manville Corporation | Method for applying a refractory layer on a surface and the layer produced thereby |
CN107721397A (en) * | 2017-11-01 | 2018-02-23 | 安徽马钢耐火材料有限公司 | A kind of pink fused alumina chamotte and preparation method thereof |
US20230312415A1 (en) * | 2021-08-24 | 2023-10-05 | Unifrax I Llc | Light weight ceramic aggregates made by agglomerating ceramic fibers |
Also Published As
Publication number | Publication date |
---|---|
ZA821014B (en) | 1983-01-26 |
SE8200857L (en) | 1982-08-17 |
IT8247786A0 (en) | 1982-02-12 |
FR2499968A1 (en) | 1982-08-20 |
DE3105533C2 (en) | 1982-10-28 |
DD202281A5 (en) | 1983-09-07 |
JPS57145082A (en) | 1982-09-07 |
NO820439L (en) | 1982-08-17 |
DE3105533A1 (en) | 1982-08-19 |
BE892034A (en) | 1982-05-27 |
NL8200604A (en) | 1982-09-16 |
PL235101A1 (en) | 1982-10-11 |
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