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GB208712A - Improvements in or relating to methods of lining electrolytic cells for refining metals - Google Patents

Improvements in or relating to methods of lining electrolytic cells for refining metals

Info

Publication number
GB208712A
GB208712A GB31946/23A GB3194623A GB208712A GB 208712 A GB208712 A GB 208712A GB 31946/23 A GB31946/23 A GB 31946/23A GB 3194623 A GB3194623 A GB 3194623A GB 208712 A GB208712 A GB 208712A
Authority
GB
United Kingdom
Prior art keywords
aluminium
cell
bath
alumina
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31946/23A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Howmet Aerospace Inc
Original Assignee
Aluminum Company of America
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aluminum Company of America filed Critical Aluminum Company of America
Publication of GB208712A publication Critical patent/GB208712A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08Cell construction, e.g. bottoms, walls, cathodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/24Refining

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

208,712. Aluminum Co. of America, (Assignees of Hoopes, W., Edwards, J. D., and Horsfield, B. T.). Dec. 21, 1922, [Convention date]. Aluminium, obtaining. - A cell for refining metals by electrolysis has a refractory insulating lining formed by establishing in the cell a bath of fused material suitable for use as an electrolyte and containing a refractory material, such as alumina, desired as a constituent of the lining, and depositing from the mixture a crust containing such material on the walls of the cell. The cell comprises a metal shell divided into two water-jacketed sections 13, 14 insulated from one another, the former being connected to a source of current. The section 13 is provided with a heat-insulating layer 23 and a bowl-shaped layer 24 of carbon. A conductor 26 is secured to the shell and plates 25 welded to the shell ensure good contact with the carbon layer. A number of upper carbon electrodes 29, secured to a conductor 31, are provided. When the cell is to be used for refining aluminium, the bath may be composed of a mixture of alumina and fluorides of aluminium, barium, sodium, strontium, calcium and magnesium. A suitable mixture comprises 9 parts by weight of aluminium fluoride. 9 parts by weight of bariuin fluoride, 7 parts by weight of sodium fluoride, and sufficient alumina to saturate the mixture. The cooling action of the circulating water in the jackets causes a crystalline crust, which is chiefly alumina, to form on the sides of the shell. During the operation of the cell for refining, the bath mixture will be situated between an upper layer of pure aluminium and a lower layer of an alloy containing. aluminium and the thickness of the lining 32 will always be increasing, due to oxygen entering the bath through the oxidation of sodium formed at the cathode. The crust may be broken away when it becomes too thick thus forming a convenient method of removing excess alumina from the bath. Specifications 208,710 and 208,711 are referred to.
GB31946/23A 1922-12-21 1923-12-20 Improvements in or relating to methods of lining electrolytic cells for refining metals Expired GB208712A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US208712XA 1922-12-21 1922-12-21

Publications (1)

Publication Number Publication Date
GB208712A true GB208712A (en) 1925-03-12

Family

ID=21801043

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31946/23A Expired GB208712A (en) 1922-12-21 1923-12-20 Improvements in or relating to methods of lining electrolytic cells for refining metals

Country Status (1)

Country Link
GB (1) GB208712A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992003598A1 (en) * 1990-08-20 1992-03-05 Comalco Aluminium Limited Ledge-free aluminium smelting cell
CN109108049A (en) * 2018-08-01 2019-01-01 湘潭大学 Containing sodium, the method for transformation of fluorochemical and system in a kind of aluminium electroloysis dangerous waste slag
CN113423668A (en) * 2018-12-21 2021-09-21 康宁公司 Bus bar design to allow high current input for low resistivity glass

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992003598A1 (en) * 1990-08-20 1992-03-05 Comalco Aluminium Limited Ledge-free aluminium smelting cell
CN109108049A (en) * 2018-08-01 2019-01-01 湘潭大学 Containing sodium, the method for transformation of fluorochemical and system in a kind of aluminium electroloysis dangerous waste slag
CN109108049B (en) * 2018-08-01 2021-06-18 湘潭大学 A kind of conversion method and system of sodium-containing and fluorine-containing compounds in aluminum electrolysis hazardous waste residue
CN113423668A (en) * 2018-12-21 2021-09-21 康宁公司 Bus bar design to allow high current input for low resistivity glass
CN113423668B (en) * 2018-12-21 2023-01-31 康宁公司 Bus bar design to allow high current input for low resistivity glass

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