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GB2067197A - Method of obtaining phtalonitriles - Google Patents

Method of obtaining phtalonitriles

Info

Publication number
GB2067197A
GB2067197A GB8106247A GB8106247A GB2067197A GB 2067197 A GB2067197 A GB 2067197A GB 8106247 A GB8106247 A GB 8106247A GB 8106247 A GB8106247 A GB 8106247A GB 2067197 A GB2067197 A GB 2067197A
Authority
GB
United Kingdom
Prior art keywords
oxide
phtalonitriles
obtaining
weigth
xylol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8106247A
Other versions
GB2067197B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VNII NEFTEKHIM PROTSESSOV
Original Assignee
VNII NEFTEKHIM PROTSESSOV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VNII NEFTEKHIM PROTSESSOV filed Critical VNII NEFTEKHIM PROTSESSOV
Publication of GB2067197A publication Critical patent/GB2067197A/en
Application granted granted Critical
Publication of GB2067197B publication Critical patent/GB2067197B/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/28—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing six-membered aromatic rings, e.g. styrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

A method of obtaining phtalonitriles consists in subjecting xylol to oxidizing ammonolysis at a temperature of 340 to 480`C in the presence of a catalyst of the following composition in% by weigth: antimony oxide: 1-25; bismuth oxide: 1-20; vanadium oxide or: molybdenum oxide: 0.2-15, iron oxide: 0.1-25, carrier: balance.
GB8106247A 1979-03-06 1979-07-02 Method of obtaining phtalonitriles Expired GB2067197B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NLAANVRAGE7901780,A NL178870C (en) 1979-03-06 1979-03-06 PROCESS FOR THE PREPARATION OF PHTHALONITRILLES AND THE CATALYST TO BE USED THEREIN
PCT/SU1979/000042 WO1981000107A1 (en) 1979-03-06 1979-07-02 Method of obtaining phtalonitriles
FR7923673A FR2465714A1 (en) 1979-03-06 1979-09-24 PROCESS FOR PREPARING PHTHALONITRILES

Publications (2)

Publication Number Publication Date
GB2067197A true GB2067197A (en) 1981-07-22
GB2067197B GB2067197B (en) 1983-05-18

Family

ID=27250953

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8106247A Expired GB2067197B (en) 1979-03-06 1979-07-02 Method of obtaining phtalonitriles

Country Status (7)

Country Link
JP (1) JPS582233B2 (en)
DE (1) DE2953735C2 (en)
FR (1) FR2465714A1 (en)
GB (1) GB2067197B (en)
NL (1) NL178870C (en)
SE (1) SE442508B (en)
WO (1) WO1981000107A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0082620A2 (en) * 1981-12-21 1983-06-29 The Standard Oil Company Nitrogenation of hydrocarbons to produce cyclic imides and dinitriles

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2545246B2 (en) * 1983-02-18 1988-03-11 Mors LOCKER AND DISSIGNER DEVICE FOR UTILITY OBJECTS, SUCH AS LUGGAGE CARTS
US4641739A (en) * 1984-09-07 1987-02-10 Mors Device for locking and releasing objects intended for public use, such as luggage carts
JPH0629231B2 (en) * 1987-04-08 1994-04-20 日東化学工業株式会社 Method for producing chlorobenzonitriles
DE3843568C1 (en) * 1988-12-23 1989-12-21 Hgz - Maschinenbau Ag, Daellikon, Zuerich, Ch
DE4133697A1 (en) * 1991-10-11 1993-04-15 Hgz Maschinenbau Ag COFFEE MACHINE
FR2687144B1 (en) * 1992-02-06 1995-05-19 Rhone Poulenc Chimie PROCESS FOR AMMOXIDATION OF SATURATED HYDROCARBONS.
EP2113498A1 (en) 2008-04-25 2009-11-04 Basf Se Method for partial oxidation or ammoxidation with an iron molybdate catalyst
FR3002227B1 (en) * 2013-02-20 2021-10-01 Arkema France GAS PHASE AND GAS LIQUID NITRILATION PROCESS

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3414631A (en) * 1965-06-10 1968-12-03 Standard Oil Co Oxydehydrogenation process
US3338952A (en) * 1965-11-15 1967-08-29 Standard Oil Co Process for the catalytic ammoxidation of olefins to nitriles
US3497545A (en) * 1966-03-10 1970-02-24 Halcon International Inc Preparation of polynitriles by ammoxidation of polyalkyl substituted aromatic hydrocarbons utilizing recycle of unreacted hydrocarbons and intermediate nitriles
FR1526405A (en) * 1966-05-18 1968-05-24 Lummus Co Process for the production of aromatic polynitriles
DE1643630B1 (en) * 1967-07-19 1971-07-01 Basf Ag Process for the production of aromatic nitriles
GB1229283A (en) * 1967-07-19 1971-04-21
DE1930880B2 (en) * 1969-06-18 1980-02-21 Chemische Werke Huels Ag, 4370 Marl Process for the production of iso- and / or terephthalic acid dinitriles
BE756614A (en) * 1969-09-26 1971-03-01 Degussa CATALYST FOR THE PREPARATION OF AROMATIC OR HETEROAROMATIC NITRILS
DE2039497C3 (en) * 1970-08-08 1974-01-17 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Process for the production of antimony-containing catalysts and the use of the catalysts for the production of aromatic and heteroaromatic nitriles
US3803204A (en) * 1972-03-27 1974-04-09 Standard Oil Co Preparation of aromatic nitriles
NL7610318A (en) * 1976-06-01 1977-12-05 Sun Ventures Inc PROCEDURE FOR AMMOXYDERING ORGANIC COMPOUNDS TO NITRILES.
DE2627068C3 (en) * 1976-06-16 1980-01-17 Institut Neftechimitscheskich Processov Imeni Akademika Ju. G. Mamedalieva Akademii Nauk Azerbaidschanskoj Ssr, Baku (Sowjetunion) Process for the production of phthalic acid dinitrile

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0082620A2 (en) * 1981-12-21 1983-06-29 The Standard Oil Company Nitrogenation of hydrocarbons to produce cyclic imides and dinitriles
EP0082620A3 (en) * 1981-12-21 1984-05-02 The Standard Oil Company Nitrogenation of hydrocarbons to produce cyclic imides and dinitriles

Also Published As

Publication number Publication date
NL7901780A (en) 1980-09-09
FR2465714A1 (en) 1981-03-27
JPS582233B2 (en) 1983-01-14
NL178870B (en) 1986-01-02
SE442508B (en) 1986-01-13
WO1981000107A1 (en) 1981-01-22
GB2067197B (en) 1983-05-18
DE2953735T1 (en) 1982-01-28
DE2953735C2 (en) 1985-09-26
FR2465714B1 (en) 1981-11-06
NL178870C (en) 1986-06-02
SE8101271L (en) 1981-02-26
JPS56500775A (en) 1981-06-11

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Legal Events

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PCNP Patent ceased through non-payment of renewal fee