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GB2012781A - Hydroxyl-containing compositions and their polymerisation - Google Patents

Hydroxyl-containing compositions and their polymerisation

Info

Publication number
GB2012781A
GB2012781A GB79396A GB7900396A GB2012781A GB 2012781 A GB2012781 A GB 2012781A GB 79396 A GB79396 A GB 79396A GB 7900396 A GB7900396 A GB 7900396A GB 2012781 A GB2012781 A GB 2012781A
Authority
GB
United Kingdom
Prior art keywords
compositions
phenolic hydroxyl
groups
compound containing
allyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB79396A
Other versions
GB2012781B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Priority to GB79396A priority Critical patent/GB2012781B/en
Publication of GB2012781A publication Critical patent/GB2012781A/en
Application granted granted Critical
Publication of GB2012781B publication Critical patent/GB2012781B/en
Expired legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/0275—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with dithiol or polysulfide compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/04—Polythioethers from mercapto compounds or metallic derivatives thereof
    • C08G75/045—Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/12—Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Paints Or Removers (AREA)

Abstract

Polymerisable compositions comprise a) a compound containing in the same molecule both at least one phenolic hydroxyl group and at least two groups chosen from allyl, methallyl, and 1-propenyl groups, e.g., 2,2-bis(3-allyl-4-hydroxy- phenyl)propane or bis(3-(1-propenyl)- 4-hydroxyphenyl)methane. b) a compound containing at least two mercaptan groups per molecule, e.g., pentaerythritol tetrathioglycollate, and c) a heat-activated crosslinking agent for phenol-aldehyde novolac resins. The compositions are caused to polymerise by the action of irradiation or free-radical catalysts. The polymers so obtained, containing more than one phenolic hydroxyl group, can be subsequently crosslinked in situ by heating. The compositions are useful in various two-stage operations, such as the production of multilayer printed circuits. Polymerisable compositions may also comprise d) a compound as a) but containing at least two phenolic hydroxyl groups, e) a compound containing more than two mercaptan groups per molecule. On irradiation or on heating with a free radical catalyst, these compositions crosslink; they are useful in forming coatings on polar substrates.
GB79396A 1978-01-20 1979-01-05 Hydroxyl containing compositions and their polymerisation Expired GB2012781B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB79396A GB2012781B (en) 1978-01-20 1979-01-05 Hydroxyl containing compositions and their polymerisation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB259778 1978-01-20
GB79396A GB2012781B (en) 1978-01-20 1979-01-05 Hydroxyl containing compositions and their polymerisation

Publications (2)

Publication Number Publication Date
GB2012781A true GB2012781A (en) 1979-08-01
GB2012781B GB2012781B (en) 1982-03-17

Family

ID=26237609

Family Applications (1)

Application Number Title Priority Date Filing Date
GB79396A Expired GB2012781B (en) 1978-01-20 1979-01-05 Hydroxyl containing compositions and their polymerisation

Country Status (1)

Country Link
GB (1) GB2012781B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0069069A2 (en) * 1981-06-19 1983-01-05 Ciba-Geigy Ag Polymerisable compositions and polymerisation products resulting therefrom
WO1992021651A1 (en) * 1991-06-04 1992-12-10 University Of Surrey Novel propenyl-functionalized aromatic compounds
WO1998058295A1 (en) * 1997-06-19 1998-12-23 Macdermid Acumen, Inc. A PHOTORESIST DEVELOPABLE IN AQUEOUS BASE MADE FROM AN ACID FUNCTIONAL β-HYDROXY THIOL RESIN AND AN UNSATURATED RESIN
WO1998058294A1 (en) * 1997-06-19 1998-12-23 Macdermid Acumen, Inc. Photocurable composition based on acid functional, primary resinous mercaptans
EP2088163A1 (en) * 2006-11-21 2009-08-12 Showa Denko K.K. Curable composition containing hydroxyl group-containing thiol compound and cured product thereof
WO2013167576A3 (en) * 2012-05-07 2014-03-20 Mercene Labs Ab Method for the manufacture of coated articles and coated articles

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0069069A2 (en) * 1981-06-19 1983-01-05 Ciba-Geigy Ag Polymerisable compositions and polymerisation products resulting therefrom
EP0069069A3 (en) * 1981-06-19 1983-02-09 Ciba-Geigy Ag Polymerisable compositions and polymerisation products resulting therefrom
WO1992021651A1 (en) * 1991-06-04 1992-12-10 University Of Surrey Novel propenyl-functionalized aromatic compounds
WO1998058295A1 (en) * 1997-06-19 1998-12-23 Macdermid Acumen, Inc. A PHOTORESIST DEVELOPABLE IN AQUEOUS BASE MADE FROM AN ACID FUNCTIONAL β-HYDROXY THIOL RESIN AND AN UNSATURATED RESIN
WO1998058294A1 (en) * 1997-06-19 1998-12-23 Macdermid Acumen, Inc. Photocurable composition based on acid functional, primary resinous mercaptans
US5925719A (en) * 1997-06-19 1999-07-20 Macdermid, Incorporated Photoresist developable in aqueous base made from acid-functional β-hydroxy thiol resin
EP2088163A1 (en) * 2006-11-21 2009-08-12 Showa Denko K.K. Curable composition containing hydroxyl group-containing thiol compound and cured product thereof
EP2088163A4 (en) * 2006-11-21 2010-11-03 Showa Denko Kk Curable composition containing hydroxyl group-containing thiol compound and cured product thereof
US8053167B2 (en) 2006-11-21 2011-11-08 Showa Denko K.K. Curable compositions containing hydroxythiol compound, and cured products thereof
WO2013167576A3 (en) * 2012-05-07 2014-03-20 Mercene Labs Ab Method for the manufacture of coated articles and coated articles
US9523019B2 (en) 2012-05-07 2016-12-20 Mercene Labs Ab Method and formulations for the manufacture of coated articles and composites
US9862857B2 (en) 2012-05-07 2018-01-09 Mercene Labs Ab Method and formulations for the manufacture of coated articles and composites
RU2650683C2 (en) * 2012-05-07 2018-04-17 Мерсен Лабс Аб Method and compositions for manufacture of coated articles and composite materials

Also Published As

Publication number Publication date
GB2012781B (en) 1982-03-17

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee