GB191422521A - Derivatives of p-dimethylaminophenylarsinic Acid. - Google Patents
Derivatives of p-dimethylaminophenylarsinic Acid.Info
- Publication number
- GB191422521A GB191422521A GB191422521DA GB191422521A GB 191422521 A GB191422521 A GB 191422521A GB 191422521D A GB191422521D A GB 191422521DA GB 191422521 A GB191422521 A GB 191422521A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- dimethylaminophenylarsinic
- nitrophenylarsinic
- dimethylamino
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- REQOQZGUOQVZJJ-UHFFFAOYSA-N [4-(dimethylamino)phenyl]arsinic acid Chemical class CN(C)C1=CC=C(C=C1)[AsH](O)=O REQOQZGUOQVZJJ-UHFFFAOYSA-N 0.000 title abstract 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 229910017604 nitric acid Inorganic materials 0.000 abstract 3
- LREQVCHNCIXCSG-UHFFFAOYSA-N [4-(dimethylamino)-3-nitrophenyl]arsinic acid Chemical compound CN(C)C1=C(C=C(C=C1)[AsH](O)=O)[N+]([O-])=O LREQVCHNCIXCSG-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical group CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 abstract 1
- RQFVPPUOTXPFCK-UHFFFAOYSA-N 4-chloroarsonoyl-N,N-dimethylaniline Chemical compound CN(C1=CC=C(C=C1)[AsH](=O)Cl)C RQFVPPUOTXPFCK-UHFFFAOYSA-N 0.000 abstract 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- OEYOHULQRFXULB-UHFFFAOYSA-N arsenic trichloride Chemical compound Cl[As](Cl)Cl OEYOHULQRFXULB-UHFFFAOYSA-N 0.000 abstract 1
- VJWWIRSVNSXUAC-UHFFFAOYSA-N arsinic acid Chemical class O[AsH2]=O VJWWIRSVNSXUAC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/66—Arsenic compounds
- C07F9/70—Organo-arsenic compounds
- C07F9/74—Aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
22,521. Thompson, W. P., [Soc. Anon. des Etablissements Poulene frÞres]. Nov. 14. Arsinic acids.-4-Dimethylaminophenylarsinic acid is nitrated by means of dilute nitric acid or a nitrate in the presence of dilute sulphuric acid; one molecular proportion of nitric acid gives either 4-dimethylamino-3-nitrophenylarsinic acid, or 4-N-methylnitrosaminophenylarsinic acid, or a mixture thereof; excess of nitric acid gives a mixture of two dinitro compounds. The 4-dimethylamino-3-nitrophenylarsinic acid on heating with caustic alkali solution yields 4-oxy-3-nitrophenylarsinic acid. The parent substance 4-dimethylaminophenylarsinic acid is obtained by treating dimethylaniline with arsenic trichloride and oxidizing the resulting 4-dimethylaminophenylarsinic chloride. Specification 13,485/10 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB191422521T | 1914-11-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB191422521A true GB191422521A (en) | 1916-02-14 |
Family
ID=32587005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB191422521D Expired GB191422521A (en) | 1914-11-14 | 1914-11-14 | Derivatives of p-dimethylaminophenylarsinic Acid. |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB191422521A (en) |
-
1914
- 1914-11-14 GB GB191422521D patent/GB191422521A/en not_active Expired
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