GB1603394A - Organic rubber pressure rolls - Google Patents

Description

(54) ORGANIC RUBBER PRESSURE ROLLS (71) We, XEROX CORPORATION of Xerox Square, Rochester, New York, United States of America, a corporation organised under the laws of the State of New York, United States of America, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement :- This application relates to a heated pressure fusing apparatus used in xerographic copying machines, and in particular to an improved pressure roll used in conjunction with a fuser roll for providing a nip through which copy sheets are moved so that toner images contact the fuser roll.

Generally in xerography, a xerographic surface comprising a layer of photoconductive electrical insulation material affixed to a conductive backing is used to support electrostatic images. In the usual method of carrying out the process the xerographic surface is electrostatically charged uniformly across its surface and then exposed to a light pattern of the image being reproduced thereby to discharge the surface in the areas where the light strikes the layer. The undischarged areas of the layer thus form an electrostatic charge pattern in conformity with the configuration of the original light pattern. The latent electrostatic image is developed by contacting it with a finely-divided electrostatically attractable powder (toner). The powder is held to the image by the electrostatic charges on the layer. It is then transferred to a sheet of paper or other suitable support member and affixed thereto to form a permanent print.

There are various ways of fusing or affixing the toner particules to the support member, one of which is by the employment of heat. In order to affix or fuse electroscopic toner materials permanently onto a support member by heat, it is necessary to elevate the temperature of the toner material to a point at which the constituents of the toner material coalesce and become tacky. This action causes the toner to adhere to the support member. In both xerographic and the electrographic recording arts, the use of thermal energy for fixing toner images onto a support member is old and well known.

U. K. Patent 1,475,638 describes and claims pressure rolls comprising a rigid core; a layer of resilient material adhered to the rigid core; and an outer layer over the resilient layer, the outer layer comprising a copolymer of perfluoroalkyl perfluorovinvl ether with tetrafluoroethylene. It discloses that the elastomeric resilient material is a heat-resistant, organosiloxane polymer commonly known as silicone rubber. Silicone rubber is generally considered adequate for this purpose, and pressure rolls prepared with silicone rubber as the resilient layer generallv perform as pressure rolls for a substantial number of hours, especially when coated with a copolymer of perfluoroalkyl perfluorovinyl ether with tetrafluoroethvlene.

However, coated pressure rolls having a silicone rubber resilient layer must be end capped so that the silicone rubber will not be contacted by silicone oil or fluids which are normally applied as offset preventing liquids or fluids to the outer surface of the fuser roll. When silicone rubber is exposed to silicone oil, the silicone rubber swells, and the integrity of the rubber deteriorates, thereby decreasing its effectiveness under the pressures and temperatures normales encountered in pressure-fusing systems. Silicone oil applied to the fuser roll eventually carries over to the pressure roll causing the foregoing disadvantages unless the pressure rolls are end capped to prevent exposure of the silicone rubber resilient layer to silicone oil.

This precaution results in added expense in the preparation of pressure rolls.

It is an object of the present invention to provide a pressure roll having substantially-improved life compared with known pressure rolls.

According to the invention there is provided a pressure roll as is claimed in the appended claims.

There is also provided a fuser apparatus for fixing toner images to copy sheets, the apparatus comprising a heated fuser roll structure ; a pressure roll for pressure engagement with the fuser roll structure to form a nip through which the copy sheets pass with the toner images contacting the heated fuser roll structure ; the pressure roll comprising a rigid core; a layer of long-life, durable, non-softening organic rubber adhered to the rigid core and an outer protective sleeve material having a high flex life over the organic rubber layer, the sleeve material providing a barrier to air so that the organic rubber is relatively free from oxidative degradation.

As used herein the term"organic rubber"is defined as a natural or synthetic rubber or elastomer or derivatives thereof characterized by a substantially carboncontaining base unit having carbon-to-carbon bonds. The carbon-to-carbon backbone may be unsaturated or saturated. This definition exclues polysiloxane rubbers and elastomers.

The invention will now be described by way of example with reference to the accompanying drawings wherein: Figure I is a schematic representation of an automatic xerographic reproducing machine incorporating a heated pressure fusing apparatus utilizing the improved pressure roll materials according to the present invention, and Figure 2 is a side-elevation of a typical fusing apparatus including fuser roll, oil metering assembly and pressure roll utilizing the improved resilient layer of the present invention.

Referring now to Figure I of the drawings, there is shown an embodiment of the invention in a suitable environment such as an automatic xerographic reproduction machine. The automatic reproducing machine inclues a xerographic plate 10 formed in the shape of a drum. The plate has a photoconductive layer or light-receiving surface on a conductive backing, and is journaled in a frame to rotate in the direction indicated by the arrow. The rotation causes the plate surface to pass sequentially through a series of xerographic processing stations. For purpose of the present disclosure, and exemplary of a typical utility for the pressure or backup roll, the several xerographic processing stations in the path of movement of the plate may be described functionally as follows : A charging station A where a uniform electrostatic charge is deposited onto the photoconductive ; An exposure station B at which a light or radiation pattern of a document to be reproduced is projected onto the plate surface to dissipate the charge in the exposed areas to form a latent electrostatic image of the document to be reproduced; A developer station C at which xerographic developing material, including toner particles having an electrostatic charge opposite to that of the latent electrostatic image, is cascaded over the latent electrostatic image to form a powdered image in configuration of a document being reproduced ; A transfer station D at which the powdered image is electrically transferred from the plate surface to a transfer material such as paper which is then passed through a heated pressure fusing apparatus F which has an improved pressure or backup roll according to the present invention as bill bue described more fulls hereinafter as mounted in a fuser assembly, and A drum cleaning and discharge station E at which the plate surface is cleaned to remove residual toner particles remaining thereon and to discharge completely any residual electro-static charge remaining thereon.

For further details of the xerographic processing stations described above, reference is made to U. S. Patent 3,645,615 and U. S. Patent 3, 937, 637.

Referring now in particular to Figure 2, there is shown a tu picas heated pressure fusing apparatus which inclues the improved pressure or backup roll 18 of the present invention. The heated pressure fusing apparatus includes a heated fuser roll 16 and a backup or pressure roll 18. The fuser roll is a hollow circular cvlinder including a metallic core 20 which is covered with a laver 22 made out of Teflon, a trademark of duPont Corporation of Wilmington, Delaware, or other suitable materials known in the art. A quartz lamp 24 located inside the fuser roll is a source of thermal energy for the fusing apparatus. Power to the lamp is controlled by a thermal sensor (not shown) which contacts the periphery of the fuser roll, as described for example in U. S. Patent 3,357,249. The pressure or backup roll is also a circular cylinder in its undeformed state, and is made up of a metal core 30 surrounded by a thick organic rubber layer 32 and then by another layer 34 made of Teflon or other suitable material to prevent the permeation of air into the layer 32 and subsequent oxidation degradation thereof.

As discussed above, the fuser roll structure 16 with its outer surface having a relatively-low affinity for tackified toner particles, provided by f) uorocarbon polymer layer 22 of, for example, tetrafluorethylene (abbreviated TFE) on the rigid cylindrical member 20. The TFE layer may be on the order of 1. 0-1. 5 mils thick, and the member 20 is preferably fabricated from a thermally-conductive material such as copper or aluminum. When copper is employed, it should be coated with aluminum or nickel prior to the application of the TFE. The particular manner in which the fuser roll structure 16 is fabricated forms no part of the present invention. Accordingly, such fabrication thereof may be in accordance with wellknown processes, for example, those set forth in U. S. Patents 3,437,032 and 3,776,760. While the fuser structure is disclosed as having a TFE layer, it may be fabricated without the layer and may simply comprise a bare metal surface, or the surface may be covered with a thin layer of elastomeric material.

Although end caps or closures (not shown) may be used at the ends of pressure roll 18, as illustrated in U. K. Patent I, 475, 638, end caps or closures are not required on the pressure rolls of the present invention because the organic rubber layer 32 adhered to the rigid core 30 does not swell from contact with silicone oil used as an offset-preventing fluid 51 metered onto fuser roll surface 22, residual quantities of which transfer from fuser roll 16 to pressure roll 18.

When the two rollers 16 and 18 are engaged as shown in Figure 2, the applied load deforms the rubber in the pressure roll to provide a nip of finite angular extent. A copy sheet 40 electrostatically bearing the toner images 42 on its underside is brought into the nip of the rolls, with the toner images contacting the fuser roll surface. The mechanism for driving the rolls and for lowering and raising rolls into contact can be such as that described for example in U. K. Patent 1, 122, 628 or any suitable mechanical camming device. As a sheet of material is advanced between the rolls 16 and 18 the toner images on a support material are contacted by the heated peripheral surface of the roll 16, causing the toner images to become tackified which would tend to cause the toner to offset onto the roll except that it is partially prevented from doing so by the Teflon or other coating on the roll, and by the thin film of offset-preventing fluid, such as silicone oil, applied to the surface of the roll by an oil-dispensing apparatus generally designated 45.

Oil-dispensing apparatus 45 inclues a wicking assembly 48, an oil pan 50 for maintaining a supply of silicone oil 51, and an applicator roll 52 which is driven by an oil-dispensing motor 58 during the fusing operation. The use of an offsetpreventing fluid on the fuser roll, and the particular manner of applying the offsetpreventing fluid, form no part of the present invention, and any offset-preventing techniques may be adapted for use with the instant invention.

Other typical fusing apparatuses which necessitate the metering of offsetpreventing fluid on the fuser member surface are well known in the art. For example, in U. S. Patent 3,937,637 the polyethylene and other polymer release materials applied to the surface of the bare metal fuser rolls can be metered by the metering blade constructed of a fluoroelastomer copolymer of vinylidene fluoride and hexafluoropropylene and having at least one surface-contacting edge having a radial curve extending longitudinal the contacting edge. In U. K. Patent 1, 475, 638 there is disclosed another typical fuser system wherein a pressure roll having a rigid core, a layer of resilient material adhered to the core, and an outer layer over the resilient layer, the outer layer comprising a copolymer of perfluoroalkyl perfluorovinyl ether with tetrafluoroethylene. Silicone rubber is disclosed as the resilient layer in U. K. Patent 1, 475,638, and exemplary mounting means, offsetpreventing fluid applicator means and other machine parameters are disclosed therein.

In certain preferred embodiments the pressure or backup roll has approximately the same overall dimensions as the fuser roll structure, and it comprises a rigid, generally-cylindrical core element 30 having an outside diameter ou 1 1/2 inches (3.8 cm). A 0.73 inch (1. 85 cm) laver 32 of a heat-resistant, long-life. durable, non-softening organic rubber is adhered to core 30. A 0.019 inch (0. 0n cm) outer layer or sleeve 34 of heat-resistant, air-impermeable material having a relatively-low affinity for tackified toner is provided over the organic rubber layer.

The combined thickness and resilience of the layers 32 and 34 is such as to allow for deformation thereof by the fuser roll structure in order to yield a suitable length for the nip formed between pressure roll 18 and fuser roll 16, (i. e. an area coextensive with the concave portion of the backup roll). A felt pad (not shown) and support therefor (not shown) may be supported to the fuser assembly frame so that the pad contacts the surface of the backup roll. Thus, any contamination such as toner may be removed from the backup roll during its rotation.

It will be appreciated that as portions of the pressure or backup roll pass through the nip area, the layers 32 and 34 are mechanically stressed due to the Hexing thereof. At the present time the useful life of a backup roll 18 appears to be limited by the failure of the resilient silicone rubber layer 32, the main mode of failure being the cohesive failure of the rubber, that is the rubber splits or ruptures for any of various reasons due to softening from extended use and/or heat build-up within the rubber and the like.

Although known pressure rolls exemplified by U. K. Patent 1, 475, 638 perform well, especially with sleeves having a high flex life, the compression deflection characteristics of the silicone rubber resilient layer are such that the failure of the rolls relates to the silicone rubber, especially in view of increased copier speeds. As copier speed increases significantly, the compression deflection of the silicone rubber layer substantially decreases with time, causing failure of the rubber and decreased fusing performance due to the resulting nip width and nip pressure changes.

In order to increase the life of the pressure or backup roll, it has been found that organic rubbers can be used as the resilient layer in the pressure roll. More specifically, organic rubbers which have a compression deflection change of less than IO ; o after prolonged use, for example operating at a nip pressure of 70-140 Tonne/m2 at 320 F (160 C) for 100 hours, increase the life of the pressure roll by two to five times over the pressure rolls having silicone rubber as a resilient layer.

The compression deflection decrease is critical, and when an organic rubber has a compression deflection decrease of less than 10 ., after operating at a nip pressure load of about 77 tonne/m2 at 320 F (160 C) for 100 hours, the organic rubber will produce the improved pressure roll when it is adhered to a rigid core and covered with an outer protective layer of high flex life material which provides a barrier to air. When air is excluded from organic rubbers, they are generally relatively free from oxidative degradation, which can cause deterioration of rubber integrity and shortened life.

Compression deflection is an empirical measurement used to measure the overall hardness of a pressure roll, and is the force required to depress or deflect the composite roll a specified distance. Typically, a circular foot, e. g. I inch (2.5 cm.) wide, is driven a certain distance into the roll and the force required to achieve this compression deflection is recorded.

Flex fatigue life is defined as the number of cycles a strip of material, for example FEP, PFA Teflon, or TFE, will undergo before splitting when flexed under specified conditions, for example, 90 degress under 10 strain between two gripper jaws at an elevated temperature, e. g., 20 mil radius jaws at 330 F (165 C).

Known materials, such as the FEP employed in the production of prior art backup rolls, provide rolls having sleeves or outer layers whose flex life is on the order of 10, 000 to 60,000 cycles. The improved sleeve material of U. K. Patent 1, 475, 638, a copolymer of perfluoroalkyl perfluorovinyl ether and tetrafluoroethylene, yields 1. 5 million flex fatigue cycles. In accordance with the present invention, commonly-known sleeve materials of desired thicknesses may be used to coat the pressure rolls. These include FEP, TFE, PFA, Teflon and fluoroelastomer copolymer. Preferred thicknesses range from about 5.0 to about 30 mils.

The organic rubbers useful as the resilient layer adhered to the rigid core of the pressure rolls of the present invention must be the organic rubbers characterized by only minimal compression deflection decreases with time. This measurement has been described above. Exemplary of this class of long-life, durable, non-softening organic rubbers are chloroprene rubber, nitrile rubber. isoprene rubber, chlorobutyl rubber, ethylene propylene terpolymer rubber (EPDM), butadiene rubber, ethylene propylene rubber, butvl rubber, butadiene/acrylonitrite rubber, ethylene acrylic rubber, styrene butadiene rubber and synthetic polyisoprene rubber.

Among the organic rubber compositions which are useful in accordance with the present invention, and which have only slight or minimal compression deflection decrease, for example less than 10 /O with time, are those crosslinked organic rubbers which are cured in a free-radical crosslinking system comprising a free radical initiator. Exemplary of such a system is a peroxide-cured organic rubber. These organic rubber crosslinking systems are non-sulfur curing systems, and organic rubbers which are sulfur-cured are less desirable and generally do not meet the compression deflection decrease requirements of the present invention.

Examples of free radical initiators are dicumyl peroxide, azobisisobutyronitrile, 1, 3-diphenylquanidine, aa'bis (t-butylperoxy) diisopropyl benzene, benzoyl peroxide, 2, 5-dimethyl-2-5-bis (t-butylperoxy) hexane or hexyne-3, and di-tbutyl peroxide.

Other preferred organic rubber compositions found useful as a resilient layer in pressure rolls according to the present invention are the organic rubbers which are crosslinked or cured in a system or process where the free radical cross-linking is carried out in the presence of a co-agent which is a reactive monomer itself and which adds to the polymer radical formed by the free radical initiator. This type of coagent promotes trimolecular crosslinking. Triallyl cyanurate and triallyl isocyanurate are exemplary of such coagents which promote trimolecular crosslinking, that is, which join three, rather than merely two, polymer chains together. Examples of other coagents include trifunctional acrylates, such as trimethyl propane trimethacrylate, N, N'-m-phenylenediamulimide, butylenedimethacrylate, 1, 2-polybutadiene, organotitanates, pentaerythritol tetramethacrylate, and trifunctional organosiloxanes.

The basic mechanism for the free radical crosslinking used in the curing of the organic rubbers in accordance with the present invention is well known in the art.

Although the invention is not limited to any particular theory, the peroxide thermally decomposes homolytically to form free radicals which then react with the polymer by addition or abstraction to form radicals on the polymer backbone.

The two polymer radicals can then combine to form the desired, thermally-stable, carbon-carbon bonds. Because polymer-free radicals are energetic, and many polymers (particularly polypropylene and propylene copolymers) will undergo chain scission or cleavage reactions, leading to molecular weight reductions and property loss, in preferred embodiments certain coagents may be used to prevent or to take advantage of this energetic activity of the free radicals. The function of the coagents is to increase the efficiency of the crosslinking reaction by adding to the polymer radical favoring trimolecular crosslinking. The coagent function is shown below :

-ONO DNO NON N N FREERADfCAL 0 0 C O GEN T ~ < , > COAGENT TRIMOLECULAR CROSSLINK As illustrated above, the coagent becomes a part of the polymer chain. It is for this reason that it is designated a reactive monomer coagent or a reactive comonomer.

One preferred composition for the layer of crosslinked organic rubber adhered to the rigid core, is an organic rubber composition comprising an organic rubber; 10 to 100 parts by weight or a particulate, surface-active filler per 100 parts of organic rubber; about 10 to 100 parts by weight plasticizing agent per 100 parts of organic rubber ; 5 to 40 parts by weight of a cure activator per 100 parts of organic rubber ; and 0.5 part to 3.0 parts by weight antioxidant per 100 parts of organic rubber; the organic rubber composition being heat cured in the presence of a free radical initiator agent and a reactive monomer coagent which adds to the polymer radical. Fillers, plasticizers, cure activators, antioxidants, and other additives well known in the art of compounding rubber compositions may be incorporated in the organic rubber compositions to provide more desirable characteristics and properties. More detailed characteristics of these additives and their effect on the organic rubber can be found under the topic of"Rubber Compounding"and Rubber Chemicals"in Volume 17 of the Kirk-Othmer, Encyclopedia of Chemical Technology, pp. 510-660.

Fillers or reinforcing agents may be added to increase the strength and integrity of the organic rubber. Carbon blacks, silicas and the like may be added to increase abrasion resistance, tensile and tear strength and fatigue resistance. The concentration of the surface-active filler is a function of the hardness or the compression deflection. In compounding the organic rubber the desired compression deflection may be attained by adjusting the concentration of the surface-active filler and the plasticizer. Generally, 30 to 60 parts by weight of filler material per 100 parts of organic rubber are preferred in rubbers of the present invention to yield a rubber of 35-55 Shore A2 durometer hardness. Generally, most grades of carbon black are commonly used as reinforcing agents. Clays, silicas, calcium silicate, and zinc oxide are examples of non-black filles.

Plasticizers may also be used in the preferred organic rubber compositions of the present invention. The plasticizers contribute to the relatively-low hardness, for example 30-60 parts plasticizer will yield a Shore A2 hardness of 45-55.

Petroleum-based process oils are commonly used for this purpose. Highly-refined, principally paraffinic oils with high aniline points are best suited for use in the peroxide crosslinked system. Generally, 40 to 60 parts by weight plasticizer and 50 parts carbon black per 100 parts of organic rubber are preferred to provide a 40- 50 Shore A2 durometer. Exemplary plasticizers are derived from petroleum, coal tars, pine tars or resins, ester-plasticizers, liquid rubbers, fats and oils, and synthetic resins. Chemical plasticizers are well known in the art.

The concentration of black required is a function of the hardness, the amount of plasticizer used and the overall property balance desired. Using 45 Shore A as a target value, a level of 40-50 phr (parts per 100 parts rubber) provides an adequate property balance. Other compounding ingredients, particularly the cure/coagent ingredient, may affect hardness.

Various plasticizer/carbon black combinations are possible while maintaining constant hardness. Other factors such as tensile strength, compound economics, dynamic heat buildup, adhesion interactions and processability, determine the degree of extension tolerable. Table I shows that at constant carbon black levels a higher plasticizer content results in an increased internal heat buildup (AT) on flex.

It is believed that this is due to increased loss in the polymer network being transformed into heat. Excessive hysteresis loss can lead to internal fractures and cohesive rubber failure because of the generation of heat.

Cure activators may be added to the organic rubber composition to serve as long-ter aging protectants and to shorten cure time. Zinc oxide is one of the preferred cure activators,: however, any well-known cure activators may be used in the present invention and include magnesium oxide, Fe203, cadium oxide and lead oxide.

Zinc oxide has been long recognized for its exceptional performance as an additive for preventing heat degradation of natural and synthetic polymers.

Zinc oxide is available in many physical forms in the rubber industry. A number of concentrated masterbatches, propionic acid-coated and dry blend formulations are in use and enhance dispersion characteristics in a polymeric matrix. Experiments have shown that two dry forms of zinc oxide and 90 "active dry dispersion on clay provide acceptable results in the formulation. Five to 40 parts by weight cure activator per 100 parts organic rubber is a preferred range for the organic rubber composition of the present invention.

Antioxidants are also commonly used in the compounding of rubbers, and in the organic rubbers of this invention, it is generally preferred to use 0.5 to 3.0 parts by weight antioxidant per 100 parts of organic rubber. Examples of antioxidants include such secondary aromatic amines as diphenylamine, N-phenyl-2 naphthylamine, N, N'-diphenyl-p-phenylenediamine 2,2'-methylene-bis (4-ethyl-6-t-butyl phenol) or tri (nonylated phenyl) phosphite. One preferred antioxidant is polymerized 1, 2-dihydro2, 2,4-trimethyl quinoline manufactured by the R. T. Vanderbuilt Co. under the trade designation AgeRite Resin D. It is the most commonly used antioxidant in peroxide-cured ethylene propylene terpolymer formulations because of compatability with free-radical (peroxide) cure systems.

Alternative antioxidants such as substituted phenols or aromatic amines, are very effective radical traps and therefore significantly retard peroxide-initiated cures. A preferred concentration of AgeRite Resin D is 1. 0 part by weight per 100 parts of the organic rubber.

The adhesive used to adhere the organic rubber to the core, and to adhere the sleeve to the organic rubber, is not a part of this invention, and techniques well known in the art may be used to obtain the proper adhesion. One preferred metal primer/rubber adhesive system is Chemlok 205/236 which may be applied to the metal core. Chemlok 250 is a reliable adhesive for holding the protective sleeve to the organic rubbers. Chemlok is a tradename of Hughson Chemical Company. The rubber composition may be placed upon the core in any suitable manner, one of the preferred methods being the extrusion of the uncured organic rubber into a mold. The curing is then effected by placing the mold in a forced-air oven at elevated temperatures. The cure should be carried out for a time sufficient to reach an adequate state of cure at the core/rubber interface. One preferred curing time and temperature is 4-7 hours in an oven at 340 F (171 C). Faster cures can be obtained by increasing the oven temperature or with molds of different designs that would permit more efficient heat transfer. Maximum cure temperature is limited to the rubber degradation temperature and attendant property losses. Curing techniques and procedures can be easily worked out by one skilled in the art.

The following examples further define, describe and compare exemplary organic rubbers for pressure rolls. Tests were carried out on fixtures taken from a Xerox 9200 duplicator (Xerox is a registered trademark of Xerox Corporation).

The test fixtures comprise fuser assemblies similar to the assembly shown in Figure 2 with minor variations. Pressure rolls having various resilient rubber layers were tested. The test rolls were set to a 0.67 inch (1. 7 cm) nip with no end cooling and were 15 inches in length and 3 inches in diameter. The tests were run at speeds characteristic of the Xerox 9200 duplicator and were continuous. Unless otherwise specified, the tests were conducted with fuser rolls at 320 F (160 C). The speed of the pressure roll engaged under 1000-1200 pounds total load was 120 rpm or 7200 copies per hour.

Pressure rolls were made by extruding the rubber into a mold holding the primed metallic (steel) core and the primed PFA Teflon sleeve. The rubber was cured in an oven at 340 F (171 C) for 5 hours. Generally sleeves of 20 mils thickness may be adhered to the rubbers by conventional techniques.

EXAMPLE I Rigid steel cores were coated with ethylene propylene diene rubber (EPDM), supplied by B. F. Goodrich under the tradename EPCAR 346, using a two-part adhesive material at the metailrubber interface and simultaneously covered with a 20 mil PFA Teflon sleeve. This rubber had a high crosslink density after curing.

Four rolls having the EPDM rubber resilient layer were placed in test fixtures as described above. The rolls attained lifetimes greater than 500 hours. Four of the rolls were run at the standard fixture set point of 3) 0 F (160 C), two of them for more than 200 hours, and additionally for more than 250 hours at 360 F (180 C).

The rolls were retired after 500 hours with no failures. Silicone oil was applied to the fuser roll as a release agent. No problems were observed from silicone oil contact with the pressure roll.

Under the same conditions a roll made in a manner similar to the above rolls, but with silicone rubber replacing the EPDM rubber, had a life of only 80 hours, the tests being terminated as a result of cohesive rubber failure.

EXAMPLE II Pressure rolls were prepared as in Example I using polychloroprene (Neoprene) rubber as the resilient organic rubber layer. One Neoprene roll coated with a PFA Teflon protective outer layer exceeded 500 hours in the fixture test with no failure. Another Neoprene rubber roll was removed after 300 hours for sleeve debonding (not a rubber failure).

EXAMPLE III Rolls were made as in Example I using chlorobutyl rubber as the resilient layer. The rolls were made with chlorobutyl base rubber (uncured) supplied by Exxon under the trade designation Exxon 1066. The cured rolls varied in performance, and rolls of chlorobutyl rubber appearing to have a higher crosslink density (based upon lower compression set and low elongation) were run in test fixtures in excess of 300 hours. Rolls in which the chlorobutyl rubber appeared to have a lower crosslink density failed within 3 hours in the test fixtures.

EXAMPLE IV Rolls similar to those of Example III were made using nitrile rubber. The rolls were coated with base rubbers supplied by B. F. Goodrich under the trade designation BFG 1092 and Goodrich NG12. Observations similar to those of Example III were made for the pressure rolls having a neoprene rubber resilient layer and a PFA Teflon protective coating.

EXAMPLE V To ethylene (74 mole %) propylene (24 mole %) and a nonconjugated diene, 5-ethylidene-2-nonbornene (about 2 mole',') known as EPDM and supplied by B. F. Goodrich under the trade designation EPCAR 346 was added a carbon black (ASTM N-550); a nonstaining paraffinic oil plasticizer supplied by Sun Oil Company under the trade designation Sunpar 150 oil ; Zinc oxide cure activator ; polymerized 1,2-dihydro-2,2,4-trimethyl quinoline antioxidant supplied by R.

T. Vanderbilt Company under the trade designation AgeRite Resin D; dicumyl peroxide free radical initiator agent (crosslinking agent) supplied by Hercules, Inc. under the trade designation DiCup 40C (a 40% active form); and triallyl cyanurate reactive monomer as a coagent used in conjunction with the peroxide free radical initiator supplied by American Cyanamid. The ingredients were added to the formulation in the quantities designated in Table I below, which compares the effect of plasticizer/carbon black filler on the physical properties of the EPDM rubber. The rubbers were cured for 5 hours in an oven at 340 F (171 C). Quantities are shown in parts by weight per 100 parts of EPDM.

TABLE I Effect of Plasticizer/Carbon Black Ratio on Physical Properties of EPDM Formulation A B C D E EPDM 100 100 100 100 100 N550 Carbon Black 30 30 40 45 45 Plasticizer 40 55 50 40 60 Zinc Oxide to 10 10 10 10 Antioxidant Coagent 2 2 2 2 2 Initiator 10 10 10 10 10 Mechanical Properties Hardness, A 46 38 45 54 40 C/D(15%) 78 59 68 100 60 100%M.(psi) 155 300% M, (psi) 705 /0 Elong. % 420 Tensile (psi) 1180 Tear, (pli) 75 heat Buildup, AT (F ) 39 46 52 54 61 C/D=compression deflection in pounds M=modulus in pounds per square inch Elong. =elongation in percent As shown in Table 1, various plasticizer/carbon black combinations are possible while maintaining constant hardness. Other factors such as tensile strength, compound economics, dynamic heat buildup, adhesion interactions, processability, etc,, determine the degree of extension tolerable. Table I shows that at constant black levels a higher plasticizer content results in an increased internal heat buildup (aT) on flex.

Pressure rolls having resilient rubber layers made from Formulation A-C and E in Table t were prepared as the rolls in Example I. All four rolls coated with PFA Teflon performed greater than 500 hours in the test fixtures.

EXAMPLE VI Rubber formulations were prepared as in Example V to study the effect of the coagent/peroxide initiator on the EPDM rubber. Quantities in parts by weight per 100 parts of EPDM and comparisons of mechanical properties for four formulations are shown in Table 2 below.

TABLE 2 Effect of Reactive Monomer Coagent and/or Varying Peroxide Concentration on Physical Properties Formulations A B C D EPDM 100 100 100 100 N550 Black 40 40 40 40 Plasticizer 50 50 50 50 Zinc Oxide 10 10 10 10 Antioxidant I I I I Coagent 2 none 2 2 Initiator 10 10 7 13 Properties Durometer, A 45 39 39 47 C/D 68 54 54 71 100% Mod 155 105 105 185 300% Mod 705 285 345 980 Elongation 420 830 665 320 Tensile Strength 1180 1175 1055 1080 Tear, DieC 75 100 90 65 AT ( F) 52 ! 02 87 38 The physical effects of the low state of cure, which results from the absence of coagent and/or decreased peroxide initiator concentration, is clearly shown in Table 2.

In comparison with the control formulation (A), compounds prepared with no coagent (B) and with a 30 peroxide reduction (C), show very low state of cure as is evidenced by reduced durometer and modulus properties and increased tear and extensibility. The dynamic heat buildup (AT) is very strongly influence by crosslink density as these compounds clearly show.

Pressure rolls were made according to Example I using the rubber formulations of Table 2. Roll A performed for over 500 hours in the test fixture; rolls B and C had cohesive rubber failure ; and roll D failed because of debonding.

Failure to run in the test fixture for 100 hours constitutes failure of the pressure roll.

EXAMPLE VII Pressure rolls were prepared with EPDM rubber as the resilient rubber layer in accordance with the techniques described in Example I. The rubber layer was covered with a preformed sleeve of various coating materials. A suitable adhesive was used to bond the sleeve to the rubber. The sleeves had a thickness of about 20 mils. Sleeve materials included: (I) fluorinated ethylene propylene (FEP) (2) PFA Teflon Each of the foregoing rolls had a lifetime of over 500 hours when operated in the test fixture.

The data from the foregoing examples show that pressure rolls can be prepared from long-life, durable, non-softening organic rubbers adhered to a rigid core and covered by an outer protective sleeve. When organic rubbers having a compression deflection decrease of less than 10% after operating in the test fixture for 100 hours, are covered with PFA Teflon (copolymer of perfluoroalkyl perfluorovinyl ether and tetrafluoroethylene) sleeve materials, substantiallyimproved lifetimes can be achieved because of the nature of the resilient organic rubber layer. It is significant that there is little decrease in the compression deflection value of the resilient organic rubber layer during the lifetime of the pressure roll.

It has also been shown that one of the parameters which can affect the property of the organic rubber, so that there is only minimal decrease (less than 10%) in compression deflection during the lifetime of the pressure roll, is the crosslink density of the organic rubber, and organic rubbers having high crosslink density prolong the lifetime of the pressure rolls a significant amount of time. As shown in the examples, this parameter can be controlled by the curing agents used to cure or crosslink the rubber.

In accordance with the stated objects, there has been demonstrated an improved pressure or backup roll for a fusing apparatus. The improvement is realized by using the designated classes of organic rubbers as the resilient layer of the pressure roll, resulting in increased pressure roll lifetimes and reduced cost because organic rubbers are cheaper than silicone rubbers, and because there is less down-time required for replacing pressure rolls. The use of the specified organic rubbers also permits the use of conventional sleeve or coating materials, and furthermore, the specified organic rubbers are not attacked or deteriorated by the silicone oil offset-preventing liquids used in the fuser system.

Claims (18)

1. WHAT WE CLAIM IS :- I. A pressure roll for apparatus used for fusing toner images to support sheets, including: a rigid core; a layer of crosslinked organic rubber (as hereinbefore defined) adhered to the rigid core, the rubber having been cured in a free-radical crosslinking system comprising a free-radical initiating agent, and an outer protective layer of a synthetic resinous flexible material over the rubber layer, the outer layer being substantially impermeable to air so that the organic rubber is protected from oxidative degradation.
2. 2. The pressure roll according to Claim 1, wherein the organic rubber comprises chloroprene rubber, nitrile rubber, isoprene rubber, butadiene rubber, butyl rubber, chlorobutyl rubber, ethylene propylene rubber, butadiene/acrylonitrile rubber, ethylene propylene diene rubber, or ethylene acrylic rubber.
3. 3. The pressure roll according to Claim I or 2, wherein the organic rubber had a compression deflection decrease of less than 10 , Ó after operating at a nip pressure load of about 77 tonne/m2 at 320 F (160 C) for 100 hours.
4. 4. The pressure roll according to any preceding claim wherein the free-radical initiating agent is dicumyl peroxide.
5. 5. The pressure roll according to any preceding claim, wherein the rubbercuring system included a coagent to increase the efficiency of the crosslinking rection the coagent being a reactive monomer which added to the polymer radical.
6. 6. The pressure roll according to Claim 5, wherein the coagent was a reactive monomer which promoted trimolecular crosslinking.
7. 7. The pressure roll according to Claim 5, wherein the coagent was triallyl cyanurate.
8. 8. The pressure roll according to Claim 5, wherein the coagent was triallyl isocyanurate.
9. 9. The pressure roll according to any of claims I3, wherein the crosslinked organic rubber composition comprises: an organic rubber ; 10 to 100 parts by weight of a particulate, surface-active filler per 100 parts of organic rubber ; 10 to 100 parts by weight plasticizing agent per 100 parts of organic rubber; 5 to 40 parts by weight of a cure activator per 100 parts of organic rubber, and 0.5 to 3.0 parts by weight antioxidant per 100 parts of organic rubber; the organic rubber composition being heat cured in the presence of a free-radical initiator agent and a reactive monomer coagent which adds to the polymer radical.
10. 10. The pressure roll according to preceding claim, wherein the free radical initiator comprises 8 to 15 parts by weight (40 ,, active) per 100 parts of organic rubber.
11. Il. The pressure roll according to preceding claim wherein the coagent comprises 0.5 to 3.0 parts by weight per 100 parts of organic rubber.
12. 12. The pressure roll according to any one of Claims 9 to 11, wherein the particulate, surface-active filler is carbon black.
13. 13. The pressure roll according to any one of Claims 9 to 12, wherein the plasticizing agent is a petroleum-based, non-staining, paraffinic oil.
14. 14. The pressure roll according to any one of Claims 9 to 13, wherein the cure activator is zinc oxide.
15. 15. The pressure roll according to any one of Claims 9 to 14, wherein the antioxidant comprises aromatic amines, substituted phenols or polymerized 1, 2dihydro-2,2,4-trimethyl quinoline.
16. 16. A pressure roll according to Claim 1, wherein the crosslinked organic rubber composition comprises: ethylene propylene diene rubber; 35 to 55 parts by weight carbon black per 100 parts of rubber ; 45 to 55 parts by weight petroleumbased paraffinic oil plasticizer per 100 parts of rubber ; 15 to 30 parts by weight zinc oxide per 100 parts of rubber ; and 0.5 to 2.0 parts by weight polymerized 1, 2dihydro-2,2,4-trimethyl quinoline ; the organic rubber composition being heat cured in the presence of 8 to 13 parts by weight dicumyl peroxide per 100 parts of rubber, with 1. 0 to 3.0 parts by weight triallyl cyanurate per 100 parts of rubber.
17. 17. The pressure roll according to any preceding claim, wherein the outer protective layer comprises fluorinated ethylene propylene resin, a copolymer of vinylidene fluoride and hexafluoropropylene, a copolymer of perfluoroalkyl pernuoroviny) ether with tetrafluoroethylene, or polytetrafluoroethylene.
18. 18. Apparatus for fusing toner images to copy sheets, comprising a heated fuser roll and a pressure roll for pressure engagement with the fuser roll to form a nip through which copy sheets pass with the toner images contacting the heated fuser roll ; the pressure roll being in accordance with any one of Claims I to 17.