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GB1491499A - Process and catalyst for conversion of carbon monoxide and steam to hydrogen and carbon dioxide - Google Patents

Process and catalyst for conversion of carbon monoxide and steam to hydrogen and carbon dioxide

Info

Publication number
GB1491499A
GB1491499A GB47155/74A GB4715574A GB1491499A GB 1491499 A GB1491499 A GB 1491499A GB 47155/74 A GB47155/74 A GB 47155/74A GB 4715574 A GB4715574 A GB 4715574A GB 1491499 A GB1491499 A GB 1491499A
Authority
GB
United Kingdom
Prior art keywords
steam
dew point
catalyst
hydrogen
carbon dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB47155/74A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1491499A publication Critical patent/GB1491499A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1491499 Producing H 2 /CO mixtures EXXON RESEARCH & ENG CO 31 Oct 1974 [23 Nov 1973 (2)] 47155/74 Heading C5E [Also in Division B1] Hydrogen and carbon dioxide are produced by catalytic contact of a carbon monoxide-steam mixture at a temperature above the dew point temperature of the steam and in the range 200-700‹ F., wherein at least a portion of the reaction zone is 30-70‹ F. above the dew point temperature of the reaction mixture at the inlet to the reaction zone, and at a pressure below the dew point pressure of the steam and in the range of atmospheric to 3000 p.s.i.g. using a catalyst comprising a certain alkali metal component, a Re, V, Mo, W and/or Co component, a sulphide component and a carrier of specified surface area and pore properties (see Division B1). The reaction may be effected at a space velocity of at least 300 vol./vol./hr<SP>-1</SP>. Reference is made to Specifications 1,281,051 and 1,388,061.
GB47155/74A 1973-11-23 1974-10-31 Process and catalyst for conversion of carbon monoxide and steam to hydrogen and carbon dioxide Expired GB1491499A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41838873A 1973-11-23 1973-11-23
US41866273A 1973-11-23 1973-11-23

Publications (1)

Publication Number Publication Date
GB1491499A true GB1491499A (en) 1977-11-09

Family

ID=27024116

Family Applications (1)

Application Number Title Priority Date Filing Date
GB47155/74A Expired GB1491499A (en) 1973-11-23 1974-10-31 Process and catalyst for conversion of carbon monoxide and steam to hydrogen and carbon dioxide

Country Status (6)

Country Link
JP (1) JPS5084490A (en)
DE (1) DE2453784A1 (en)
ES (1) ES431970A1 (en)
FR (1) FR2252285B1 (en)
GB (1) GB1491499A (en)
IN (1) IN141846B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6777117B1 (en) 1999-03-18 2004-08-17 Matsushita Electric Works, Ltd. Catalysts for water gas shift reaction, method for removing carbon monoxide in hydrogen gas and electric power-generating system of fuel cell
WO2013072659A1 (en) * 2011-11-18 2013-05-23 Johnson Matthey Public Limited Company Process for increasing hydrogen content of synthesis gas
AU2012397690B2 (en) * 2012-12-28 2016-04-21 Mitsubishi Heavy Industries Engineering, Ltd. CO shift catalyst, CO shift reactor, and method for purifying gasification gas

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2469206A1 (en) * 1979-11-12 1981-05-22 Shell France Alumina transition metal catalyst prodn. for use in water gas reaction - by dissolving metal or cpd. in melt of aluminium cpd. and thermal decomposition
DE3160447D1 (en) * 1980-02-07 1983-07-28 Studiengesellschaft Kohle Mbh Process for producing hydrogen from carbon monoxide and water
JP3473898B2 (en) 1999-04-22 2003-12-08 松下電器産業株式会社 Hydrogen purification equipment
KR20020074464A (en) 1999-12-28 2002-09-30 마쯔시다덴기산교 가부시키가이샤 Apparatus for forming hydrogen
DE10013895A1 (en) 2000-03-21 2001-10-04 Dmc2 Degussa Metals Catalysts Cerdec Ag Water gas shift reaction, useful in mobile unit in vehicle for removing carbon monoxide from gas mixture containing hydrogen for fuel cell, uses catalyst based on noble metal coating on inert carrier
DE10013894A1 (en) 2000-03-21 2001-10-04 Dmc2 Degussa Metals Catalysts Process for the catalytic conversion of carbon monoxide in a hydrogen-containing gas mixture with improved cold start behavior and catalyst therefor
DE10132064A1 (en) * 2001-07-05 2003-01-30 Viessmann Werke Kg Process for operating an apparatus for producing hydrogen and apparatus for carrying out the process
JP4537091B2 (en) * 2004-03-01 2010-09-01 エヌ・イーケムキャット株式会社 Catalyst for removing carbon monoxide from hydrogen gas
JP4569408B2 (en) * 2005-07-25 2010-10-27 堺化学工業株式会社 Water gas shift reaction catalyst and method for removing carbon monoxide gas from hydrogen gas using the same
GB201109376D0 (en) * 2011-06-06 2011-07-20 Johnson Matthey Plc Water-gas shift catalyst
US20150291899A1 (en) * 2012-12-28 2015-10-15 Mitsubishi Heavy Industries, Ltd. Co shift catalyst, co shift reactor, and method for purifying gasification gas
JP7020306B2 (en) * 2018-06-13 2022-02-16 日本製鉄株式会社 A method for producing a water-gas shift reaction catalyst, a method for producing a water-gas shift reaction catalyst, and a method for producing hydrogen.

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6777117B1 (en) 1999-03-18 2004-08-17 Matsushita Electric Works, Ltd. Catalysts for water gas shift reaction, method for removing carbon monoxide in hydrogen gas and electric power-generating system of fuel cell
WO2013072659A1 (en) * 2011-11-18 2013-05-23 Johnson Matthey Public Limited Company Process for increasing hydrogen content of synthesis gas
CN103946151A (en) * 2011-11-18 2014-07-23 庄信万丰股份有限公司 Process for increasing hydrogen content of synthesis gas
US20140284525A1 (en) * 2011-11-18 2014-09-25 Johnson Matthey Public Limited Company Process for increasing hydrogen content of synthesis gas
US9193590B2 (en) 2011-11-18 2015-11-24 Johnson Matthey Public Limited Company Process for increasing hydrogen content of synthesis gas
CN103946151B (en) * 2011-11-18 2015-11-25 庄信万丰股份有限公司 For increasing the method for the hydrogen richness of synthetic gas
AU2012338627B2 (en) * 2011-11-18 2015-12-24 Johnson Matthey Public Limited Company Process for increasing hydrogen content of synthesis gas
AU2012397690B2 (en) * 2012-12-28 2016-04-21 Mitsubishi Heavy Industries Engineering, Ltd. CO shift catalyst, CO shift reactor, and method for purifying gasification gas

Also Published As

Publication number Publication date
JPS5084490A (en) 1975-07-08
IN141846B (en) 1977-04-23
ES431970A1 (en) 1976-11-01
FR2252285A1 (en) 1975-06-20
DE2453784A1 (en) 1975-05-28
FR2252285B1 (en) 1979-03-16

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee