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GB1466600A - Copolymer-containing layers useful in photogrpahy and coating compositions for their manufacture - Google Patents

Copolymer-containing layers useful in photogrpahy and coating compositions for their manufacture

Info

Publication number
GB1466600A
GB1466600A GB3698374A GB3698374A GB1466600A GB 1466600 A GB1466600 A GB 1466600A GB 3698374 A GB3698374 A GB 3698374A GB 3698374 A GB3698374 A GB 3698374A GB 1466600 A GB1466600 A GB 1466600A
Authority
GB
United Kingdom
Prior art keywords
copolymer
weight
alkyl
units
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3698374A
Inventor
Donald Arthur Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US525272A external-priority patent/US3459790A/en
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Priority to GB3698374A priority Critical patent/GB1466600A/en
Publication of GB1466600A publication Critical patent/GB1466600A/en
Expired legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
    • G03C8/24—Photosensitive materials characterised by the image-receiving section
    • G03C8/26—Image-receiving layers
    • G03C8/28—Image-receiving layers containing development nuclei or compounds forming such nuclei
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F20/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10—Esters
    • C08F22/12—Esters of phenols or saturated alcohols
    • C08F22/24—Esters containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • C08F220/585—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine and containing other heteroatoms, e.g. 2-acrylamido-2-methylpropane sulfonic acid [AMPS]
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
    • G03C1/053—Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
    • G03C8/02—Photosensitive materials characterised by the image-forming section

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1466600 Coatings EASTMAN KODAK CO 22 Aug 1974 36983/74 Addition to 1181508 Heading B2E [Also in Divisions C3 and G2] Supports of particular use, in photography comprise a coating comprising copolymer containing (A) at least 50% by weight of units of the formula wherein R<SP>1</SP> is H or methyl and R<SP>2</SP> is alkyl, (B) 3-30% by weight of units of the formula wherein R<SP>3</SP> is H or methyl and M is a cation (e.g. H, NH 4 , alkali metal or organic ammonium), and (c) 2-20% by weight of units of the formula wherein either R<SP>4</SP> is H or alkyl and R<SP>5</SP> is R<SP>6</SP> being alkylene and X being aliphatic acyl or -CN, or R<SP>4</SP> is R<SP>7</SP> being alkylene containing at least two carbon atoms in the alkylene chain and X is as previously defined, and R<SP>5</SP> is alkyl, cycloalkyl or aryl, said copolymer containing at least 0.1% by weight of active methylene groups (i.e. methylene groups bonded directly to two electron-withdrawing groups, e.g. carboxyl groups). The layers may also include a hydrophilic colloid binder, e.g. gelatin, and can be applied to a support from an aqueous dispersion or latex of the copolymer, optionally also containing the binder. The copolymer layer can, if desired, be hardened by treatment with such compounds as formaldehyde, mucochloric acid, an aziridine, a vinyl sulphonyl compound, or a hardener derived from dioxane, an oxy-polysaccharide or an oxy plant gum; such hardener can be incorporated in the copolymer dispersion (latex). An Example illustrates the preparation and application of a copolymer of n-butyl acrylate, 2-acryloylamino-2, 2-dimethylethane-1-sulphonic acid and 2-acetoacetoxy ethyl methacrylate.
GB3698374A 1965-12-20 1974-08-22 Copolymer-containing layers useful in photogrpahy and coating compositions for their manufacture Expired GB1466600A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3698374A GB1466600A (en) 1965-12-20 1974-08-22 Copolymer-containing layers useful in photogrpahy and coating compositions for their manufacture

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US525272A US3459790A (en) 1965-12-20 1965-12-20 Polymerizable acrylic acid esters containing active methylene groups
GB3698374A GB1466600A (en) 1965-12-20 1974-08-22 Copolymer-containing layers useful in photogrpahy and coating compositions for their manufacture

Publications (1)

Publication Number Publication Date
GB1466600A true GB1466600A (en) 1977-03-09

Family

ID=42137543

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3698374A Expired GB1466600A (en) 1965-12-20 1974-08-22 Copolymer-containing layers useful in photogrpahy and coating compositions for their manufacture

Country Status (1)

Country Link
GB (1) GB1466600A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0015880A2 (en) * 1979-03-09 1980-09-17 Ciba-Geigy Ag Receiving elements containing graft gelatin polymers as dyestuff mordants, and photographic material containing the same
EP0015879A2 (en) * 1979-03-09 1980-09-17 Ciba-Geigy Ag Receiving elements containing a water-permeable binder as dyestuff mordant, and photographic materials containing the same
EP0035614A1 (en) * 1980-03-12 1981-09-16 Imperial Chemical Industries Plc Improvements in photographic film materials and processes for their production
EP0095695A2 (en) * 1982-05-29 1983-12-07 Hoechst Aktiengesellschaft Aqueous dispersions of synthetic materials based on copolymers of ethylenically unsaturated compounds
US5254441A (en) * 1991-10-01 1993-10-19 Eastman Kodak Company Development inhibitor reflector layers
US5298376A (en) * 1991-10-01 1994-03-29 Eastman Kodak Company Photographic silver halide material with improved color saturation
EP0675402A1 (en) * 1994-03-31 1995-10-04 Kodak-Pathe Protective top layer and photographic materials containing this top layer
EP0789267A1 (en) * 1996-02-12 1997-08-13 EASTMAN KODAK COMPANY (a New Jersey corporation) Imaging element comprising an electrically-conductive layer
EP0789268A1 (en) * 1996-02-12 1997-08-13 Eastman Kodak Company Imaging element comprising an electrically-conductive layer
US5948606A (en) * 1994-03-31 1999-09-07 Eastman Kodak Company Protective top layer and photographic products containing this top layer

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0015880A2 (en) * 1979-03-09 1980-09-17 Ciba-Geigy Ag Receiving elements containing graft gelatin polymers as dyestuff mordants, and photographic material containing the same
EP0015879A2 (en) * 1979-03-09 1980-09-17 Ciba-Geigy Ag Receiving elements containing a water-permeable binder as dyestuff mordant, and photographic materials containing the same
EP0015880A3 (en) * 1979-03-09 1981-07-22 Ciba-Geigy Ag Receiving elements containing graft gelatin polymers as dyestuff mordants, and photographic material containing the same
EP0015879B1 (en) * 1979-03-09 1983-10-19 Ciba-Geigy Ag Receiving elements containing a water-permeable binder as dyestuff mordant, and photographic materials containing the same
EP0035614A1 (en) * 1980-03-12 1981-09-16 Imperial Chemical Industries Plc Improvements in photographic film materials and processes for their production
EP0095695A3 (en) * 1982-05-29 1984-03-07 Hoechst Aktiengesellschaft Aqueous dispersions of synthetic materials based on copolymers of ethylenically unsaturated compounds
EP0095695A2 (en) * 1982-05-29 1983-12-07 Hoechst Aktiengesellschaft Aqueous dispersions of synthetic materials based on copolymers of ethylenically unsaturated compounds
US5254441A (en) * 1991-10-01 1993-10-19 Eastman Kodak Company Development inhibitor reflector layers
US5298376A (en) * 1991-10-01 1994-03-29 Eastman Kodak Company Photographic silver halide material with improved color saturation
EP0675402A1 (en) * 1994-03-31 1995-10-04 Kodak-Pathe Protective top layer and photographic materials containing this top layer
FR2718257A1 (en) * 1994-03-31 1995-10-06 Kodak Pathe Protective overcoat and photographic products comprising this overcoat.
US5948606A (en) * 1994-03-31 1999-09-07 Eastman Kodak Company Protective top layer and photographic products containing this top layer
EP0789267A1 (en) * 1996-02-12 1997-08-13 EASTMAN KODAK COMPANY (a New Jersey corporation) Imaging element comprising an electrically-conductive layer
EP0789268A1 (en) * 1996-02-12 1997-08-13 Eastman Kodak Company Imaging element comprising an electrically-conductive layer

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE Patent expired