GB1465104A - Process for the preparation of fibrids of olefinically unsatu rated monomers and fibrids obtained thereby - Google Patents
Process for the preparation of fibrids of olefinically unsatu rated monomers and fibrids obtained therebyInfo
- Publication number
- GB1465104A GB1465104A GB1895974A GB1895974A GB1465104A GB 1465104 A GB1465104 A GB 1465104A GB 1895974 A GB1895974 A GB 1895974A GB 1895974 A GB1895974 A GB 1895974A GB 1465104 A GB1465104 A GB 1465104A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fibrids
- ethylene
- compound
- polyiminoalane
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 239000002904 solvent Substances 0.000 abstract 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- 125000005287 vanadyl group Chemical group 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 230000000379 polymerizing effect Effects 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 abstract 1
- -1 ethylene Chemical class 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052739 hydrogen Chemical group 0.000 abstract 1
- 239000001257 hydrogen Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/12—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
- D21H5/20—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of organic non-cellulosic fibres too short for spinning, with or without cellulose fibres
- D21H5/202—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of organic non-cellulosic fibres too short for spinning, with or without cellulose fibres polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/38—Formation of filaments, threads, or the like during polymerisation
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/12—Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/14—Polyalkenes, e.g. polystyrene polyethylene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Artificial Filaments (AREA)
- Nonwoven Fabrics (AREA)
- Paper (AREA)
Abstract
1465104 Polymers in fibrid form SNAMPROGETTI SpA 30 April 1974 [30 April 1973] 18959/74 Heading C3P Polymers in the form of particles of fibrid form are prepared by polymerizing at least one olefinically unsaturated compound in a solvent medium for the unsaturated compound(s) which is a non-solvent for the resulting polymer in the presence of a catalyst comprising (a) a vanadium or titanium compound and (b) a reducing aluminium compound AlR x X 3-x where R is hydrocarbyl, X is hydrocarbyl, halogen or hydrogen and x is 0 to 3 or a polyiminoalane having repeating units -(AlH-NR)-, the atomic ratio of aluminium to transition metal being 1 : 1 to 200 : 1 and the concentration of transition metal compound being 0À001 to 5 millimoles/litre, the solvent medium undergoing stirring to achieve dissipation of heat of polymerization which is produced. The solvent may be a hydrocarbon or halogenated hydrocarbon. The material polymerized may be an olefin, e.g. ethylene, or a mixture thereof with butadiene. The products may be used, optionally in admixture with cellulose fibrids, in the manufacture of paper-like products. Examples describe the preparation fibrids by polymerizing ethylene in heptane with catalysts comprising (2-4 and 7-10) titanium tetrachloride and polyiminoalane, (13-26) vanadyl trichloride and polyiminoalane, and (27, 29 and 30) vanadyl trichloride and ethyl aluminium sesquichloride ; ethylene in methylene chloride with catalysts comprising (32-34) vanadyl trichloride and ethyl aluminium sesquichloride; and ethylene/ butadiene in heptane with a catalyst comprising (35) triisopropyl vanadate and ethyl aluminium dichloride.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT23559/73A IT985609B (en) | 1973-04-30 | 1973-04-30 | PROCESS FOR THE PREPARATION OF POLYALFAOLEFIN FIBERS AND FIBERS OF THIS OBTAINED |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1465104A true GB1465104A (en) | 1977-02-23 |
Family
ID=11208135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1895974A Expired GB1465104A (en) | 1973-04-30 | 1974-04-30 | Process for the preparation of fibrids of olefinically unsatu rated monomers and fibrids obtained thereby |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS5014788A (en) |
| BE (1) | BE814316A (en) |
| CA (1) | CA1049196A (en) |
| CH (1) | CH606128A5 (en) |
| DD (1) | DD112457A5 (en) |
| DE (1) | DE2420943A1 (en) |
| FR (1) | FR2227281B1 (en) |
| GB (1) | GB1465104A (en) |
| IT (1) | IT985609B (en) |
| LU (1) | LU69957A1 (en) |
| NL (1) | NL7405776A (en) |
| SE (1) | SE405017B (en) |
| ZA (1) | ZA742715B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1015582B (en) * | 1974-07-01 | 1977-05-20 | Snam Progetti | PROCESS FOR THE POLYMERIZATION OF ETHYLENE |
-
1973
- 1973-04-30 IT IT23559/73A patent/IT985609B/en active
-
1974
- 1974-04-23 CH CH556074A patent/CH606128A5/xx not_active IP Right Cessation
- 1974-04-24 FR FR7414187A patent/FR2227281B1/fr not_active Expired
- 1974-04-26 DD DD178148A patent/DD112457A5/xx unknown
- 1974-04-29 NL NL7405776A patent/NL7405776A/xx not_active Application Discontinuation
- 1974-04-29 BE BE143715A patent/BE814316A/en unknown
- 1974-04-29 CA CA74198622A patent/CA1049196A/en not_active Expired
- 1974-04-29 LU LU69957A patent/LU69957A1/xx unknown
- 1974-04-30 SE SE7405812A patent/SE405017B/en unknown
- 1974-04-30 ZA ZA00742715A patent/ZA742715B/en unknown
- 1974-04-30 DE DE2420943A patent/DE2420943A1/en active Pending
- 1974-04-30 JP JP49047788A patent/JPS5014788A/ja active Pending
- 1974-04-30 GB GB1895974A patent/GB1465104A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2227281A1 (en) | 1974-11-22 |
| DD112457A5 (en) | 1975-04-12 |
| NL7405776A (en) | 1974-11-01 |
| CH606128A5 (en) | 1978-10-31 |
| FR2227281B1 (en) | 1977-06-24 |
| IT985609B (en) | 1974-12-10 |
| SE405017B (en) | 1978-11-13 |
| ZA742715B (en) | 1975-05-28 |
| AU6753774A (en) | 1975-10-09 |
| JPS5014788A (en) | 1975-02-17 |
| DE2420943A1 (en) | 1974-11-14 |
| BE814316A (en) | 1974-08-16 |
| LU69957A1 (en) | 1974-08-06 |
| CA1049196A (en) | 1979-02-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |