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GB1464994A - Yarns fibres and films based on poly-vinylidene fluoride - Google Patents

Yarns fibres and films based on poly-vinylidene fluoride

Info

Publication number
GB1464994A
GB1464994A GB2467474A GB2467474A GB1464994A GB 1464994 A GB1464994 A GB 1464994A GB 2467474 A GB2467474 A GB 2467474A GB 2467474 A GB2467474 A GB 2467474A GB 1464994 A GB1464994 A GB 1464994A
Authority
GB
United Kingdom
Prior art keywords
vinylidene fluoride
acid
poly
fibres
yarns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2467474A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Textile SA
Original Assignee
Rhone Poulenc Textile SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Textile SA filed Critical Rhone Poulenc Textile SA
Publication of GB1464994A publication Critical patent/GB1464994A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/48—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/002—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using basic dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/004—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using dispersed dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1464994 Poly(vinylidene fluoride)/methylmethacrylate copolymer compositions RHONEPOULENC-TEXTILE 4 June 1974 [6 June 1973] 24674/74 Heading C3P Yarns, fibres and films are made from a cornposition comprising poly(vinylidene fluoride) and a copolymer which contains at least 60% by weight of methylmethacrylate and 5 to 40% by weight of at least one ethylenically unsaturated monomer copolymerizable therewith, or an alkali metal salt of such acid or acids, said mixture containing at least 40 milliequivalents of an acid per kilogram of polymer mixture and at least 80% by weight of the vinylidene fluoride homopolymer, based on the total weight of the polymer mixture. The acid may be carboxylic or sulphonic with acrylic acid, methacrylic acid, 2-sulphoethyl methacrylate and 2-acrylamino-2- methyl-propane sulphonic acid being preferred. The poly(vinylidene fluoride) preferably has a melt flow index (the amount of polymer extruded at 250‹ C. in 1 minute through a 2 mm. nozzle at 10 kg./sq. cm.) of at least 10 at 250‹ C. The fibres and yarns are prepared by extruding the polymer composition from a solution in an aprotic polar organic solvent as filaments and setting the filaments by a wet, dry or semi-melt method. Films are obtained by forming the same solution into a film and setting by the same methods. The yarns, fibres or films may then be stretched in one or more stages, before or after washing and subsequently heat-treated. The products have good affinity for plastosoluble and cationic dyes. In the Examples, poly(vinylidene fluoride) and copolymers of methylmethacrylate with (1) and (5) 2-acrylamido-2-methyl propane sulphonic acid, (2) and (4) 2-sulphoethyl methacrylate; (3) methacrylic acid, were dissolved in dimethylformaldehyde, extruded into filaments and dyed.
GB2467474A 1973-06-06 1974-06-04 Yarns fibres and films based on poly-vinylidene fluoride Expired GB1464994A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7320667A FR2232622B1 (en) 1973-06-06 1973-06-06

Publications (1)

Publication Number Publication Date
GB1464994A true GB1464994A (en) 1977-02-16

Family

ID=9120624

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2467474A Expired GB1464994A (en) 1973-06-06 1974-06-04 Yarns fibres and films based on poly-vinylidene fluoride

Country Status (16)

Country Link
US (1) US3941860A (en)
JP (1) JPS5033244A (en)
AR (1) AR204321A1 (en)
BE (1) BE815959A (en)
BR (1) BR7404592D0 (en)
CA (1) CA1037637A (en)
CH (1) CH570471A5 (en)
DE (1) DE2427393A1 (en)
DK (1) DK142240B (en)
ES (1) ES427037A1 (en)
FR (1) FR2232622B1 (en)
GB (1) GB1464994A (en)
IE (1) IE39404B1 (en)
IT (1) IT1014840B (en)
LU (1) LU70247A1 (en)
NL (1) NL7407496A (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2268094B1 (en) * 1974-04-16 1976-10-08 Rhone Poulenc Textile
JPS54106622A (en) * 1978-01-31 1979-08-21 Kureha Chem Ind Co Ltd Monofilaments of vinylidene fluoride resin
DE2837751C2 (en) * 1978-08-30 1983-12-15 Dynamit Nobel Ag, 5210 Troisdorf Method and device for producing monofilaments from polyvinylidene fluoride
DE2907074C2 (en) * 1979-02-23 1982-08-19 Dynamit Nobel Ag, 5210 Troisdorf Screw extruder for polyvinylidene fluoride monofilaments
DE2914606B2 (en) * 1979-04-11 1981-06-11 Dynamit Nobel Ag, 5210 Troisdorf String made of plastic, process for their manufacture and use of a string with certain properties
JPS55157155U (en) * 1979-04-27 1980-11-12
US4606871A (en) * 1980-07-23 1986-08-19 Minnesota Mining And Manufacturing Company Method of making a film from pyroelectric and isotropic piezoelectric polymer blends
AU7438181A (en) * 1980-10-03 1982-04-08 Dynamit Nobel Aktiengesellschaft Plastics cord
DE3045844C2 (en) * 1980-12-05 1986-01-02 Hoechst Ag, 6230 Frankfurt Permanently heat-resistant molded articles containing fluorocarbon polymers
JPS6187765A (en) * 1984-10-06 1986-05-06 Kansai Paint Co Ltd Highly weather resistant electrodeposition coating composition
DE19638416C1 (en) * 1996-09-19 1997-11-13 Gore W L & Ass Gmbh Microporous fluoro-polymer blend with thermoplastic to increase strength
US20060061005A1 (en) * 2004-09-22 2006-03-23 Henry Peng Method of producing layered polymeric articles

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3340222A (en) * 1963-06-28 1967-09-05 Du Pont Hydrofluorocarbon polymer filmforming composition
US3253060A (en) * 1964-08-03 1966-05-24 Pennsalt Chemicals Corp Molding compositions comprising polyvinylidene fluoride and polymethyl methacrylate
GB1065780A (en) * 1965-02-15 1967-04-19 American Cyanamid Co Poly(vinylidene fluoride) compositions

Also Published As

Publication number Publication date
CA1037637A (en) 1978-08-29
FR2232622A1 (en) 1975-01-03
JPS5033244A (en) 1975-03-31
AR204321A1 (en) 1975-12-22
IE39404L (en) 1974-12-06
CH570471A5 (en) 1975-12-15
DK142240C (en) 1981-02-23
LU70247A1 (en) 1974-10-17
ES427037A1 (en) 1976-07-16
DK299974A (en) 1975-02-03
NL7407496A (en) 1974-12-10
BE815959A (en) 1974-12-05
DE2427393A1 (en) 1975-01-16
US3941860A (en) 1976-03-02
DK142240B (en) 1980-09-29
IE39404B1 (en) 1978-09-27
IT1014840B (en) 1977-04-30
FR2232622B1 (en) 1976-04-23
BR7404592D0 (en) 1975-01-21

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee