GB1443502A - Electrode - Google Patents
ElectrodeInfo
- Publication number
- GB1443502A GB1443502A GB441875A GB441875A GB1443502A GB 1443502 A GB1443502 A GB 1443502A GB 441875 A GB441875 A GB 441875A GB 441875 A GB441875 A GB 441875A GB 1443502 A GB1443502 A GB 1443502A
- Authority
- GB
- United Kingdom
- Prior art keywords
- powder
- tio
- electrode
- sintering
- applying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000843 powder Substances 0.000 abstract 6
- 239000011248 coating agent Substances 0.000 abstract 5
- 238000000576 coating method Methods 0.000 abstract 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 4
- 230000003213 activating effect Effects 0.000 abstract 3
- 238000005245 sintering Methods 0.000 abstract 3
- 239000000126 substance Substances 0.000 abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 abstract 2
- 239000002585 base Substances 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 abstract 2
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 239000012300 argon atmosphere Substances 0.000 abstract 1
- 238000004210 cathodic protection Methods 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000010285 flame spraying Methods 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000004767 nitrides Chemical class 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 238000007750 plasma spraying Methods 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000013535 sea water Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 238000005476 soldering Methods 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000003466 welding Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
- C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
- C25B11/067—Inorganic compound e.g. ITO, silica or titania
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
- C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/097—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds comprising two or more noble metals or noble metal alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Powder Metallurgy (AREA)
- Mechanical Engineering (AREA)
Abstract
1443502 Electrodes SIGRI ELEKTROGRAPHIT GmbH 31 Jan 1975 [2 Feb 1974 16 March 1974 25 April 1974] 4418/75 Heading C7B [Also in Division C1] An electrode, for use in a chlor-alkali mercury or diaphragm cell, production of chlorate or hypochlorite, oxidation of organic substances, extraction of salt from sea water or cathodic protection, comprises a base structure formed of TiO x where x is 0.25 to 1.50, at least partially covered by a surface coating containing at least one activating substance, e.g. Pd, Pt, Ir, Ru, Os, Rh, Au, Ag and/or oxides, nitrides, sulphides thereof. The electrode 1 may comprise rectangular top and bottom surfaces, either parallel Fig. 2 (not shown), or with the top surface 5 inclined to the bottom; formed in the bottom and extending between sides 3, 4 may be grooves 2 whose depth uniformly increases. Ribbed reinforcing elements may be provided on the grooves. The electrode is produced by compressing a TiO x powder (or mixture of Ti and rutile powder with polyvinyl alcohol binder), sintering at 900 to 1500C in an inert e.g. argon atmosphere and applying the activating substance(s). At least part of the surface of the base structure not covered by the surface coating may be provided with a sintered Ti coating for connection to Ti current-supply rods or bars e.g. by soldering or welding. The Ti coating may be formed by (a) covering the TiO x powder with a layer of Ti powder and compressing the superimposed powder layers and sintering, (b) applying Ti powder with etherified cellulose binder to the shaped sintered TiO x body and sintering, or (c) applying the Ti to the shaped sintered body by flame or plasma spraying. For an activating surface coating, the shaped body may be coated with an acid alcoholic solution of RuCl 3 (H 2 O) 1.5 and H 2 PtCl 6 and heated in argon to burn in the layer.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2405010A DE2405010C3 (en) | 1974-02-02 | 1974-02-02 | Sintered electrode for electrochemical processes and methods of manufacturing the electrode |
DE2412828A DE2412828C2 (en) | 1974-03-16 | 1974-03-16 | Electrode for electrochemical processes |
DE2420011A DE2420011C2 (en) | 1974-04-25 | 1974-04-25 | Sintered electrode for electrochemical processes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1443502A true GB1443502A (en) | 1976-07-21 |
Family
ID=27185757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB441875A Expired GB1443502A (en) | 1974-02-02 | 1975-01-31 | Electrode |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS5642675B2 (en) |
CA (1) | CA1040137A (en) |
CH (1) | CH613995A5 (en) |
FR (1) | FR2259921B1 (en) |
GB (1) | GB1443502A (en) |
IT (1) | IT1031341B (en) |
NL (1) | NL7417054A (en) |
NO (1) | NO141419C (en) |
SE (1) | SE398894B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0047595A1 (en) * | 1980-09-10 | 1982-03-17 | Marston Palmer Ltd. | Electrochemical cell |
US4912286A (en) * | 1988-08-16 | 1990-03-27 | Ebonex Technologies Inc. | Electrical conductors formed of sub-oxides of titanium |
US4964966A (en) * | 1988-03-01 | 1990-10-23 | Moreland Peter J | Electrode and construction thereof |
EP0443230A1 (en) * | 1990-02-20 | 1991-08-28 | Atraverda Limited | Electrochemical cell and process |
WO2017050867A1 (en) * | 2015-09-25 | 2017-03-30 | Akzo Nobel Chemicals International B.V. | Electrode |
CN108026650A (en) * | 2015-09-25 | 2018-05-11 | 阿克苏诺贝尔化学品国际有限公司 | Electrode |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51117978A (en) * | 1975-04-09 | 1976-10-16 | Sekisui Chem Co Ltd | Electrode |
US4032427A (en) * | 1975-11-03 | 1977-06-28 | Olin Corporation | Porous anode separator |
DD137365A5 (en) * | 1976-03-31 | 1979-08-29 | Diamond Shamrock Techn | ELECTRODE |
LU75407A1 (en) * | 1976-07-16 | 1978-02-08 | ||
FR2439826A1 (en) * | 1978-10-24 | 1980-05-23 | Anger Roger | Moulded dimensionally stable anode - based on mixts. of metals and resin binders |
DE3106587C2 (en) * | 1981-02-21 | 1987-01-02 | Heraeus Elektroden GmbH, 6450 Hanau | Electrode and its use |
FR2541691B1 (en) * | 1983-02-25 | 1989-09-15 | Europ Composants Electron | ELECTRODE FOR ELECTROLYTIC BATH |
ITMI20120873A1 (en) * | 2012-05-21 | 2013-11-22 | Industrie De Nora Spa | ELECTRODE FOR EVOLUTION OF GASEOUS PRODUCTS AND METHOD FOR ITS ACHIEVEMENT |
US10414674B2 (en) * | 2017-01-18 | 2019-09-17 | Wisconsin Alumni Research Foundation | Bismuth-based chloride-storage electrodes |
WO2019176956A1 (en) * | 2018-03-12 | 2019-09-19 | 三菱マテリアル株式会社 | Titanium base material, method for producing titanium base material, electrode for water electrolysis, and water electrolysis device |
KR20220044191A (en) * | 2019-08-01 | 2022-04-06 | 미쓰이금속광업주식회사 | Catalyst layer for fuel cell, manufacturing method thereof, and fuel cell provided with same |
-
1974
- 1974-12-09 NO NO744435A patent/NO141419C/en unknown
- 1974-12-31 NL NL7417054A patent/NL7417054A/en not_active Application Discontinuation
-
1975
- 1975-01-29 CH CH104375A patent/CH613995A5/en not_active IP Right Cessation
- 1975-01-31 SE SE7501094A patent/SE398894B/en not_active IP Right Cessation
- 1975-01-31 CA CA219,144A patent/CA1040137A/en not_active Expired
- 1975-01-31 IT IT19809/75A patent/IT1031341B/en active
- 1975-01-31 GB GB441875A patent/GB1443502A/en not_active Expired
- 1975-02-03 JP JP1419775A patent/JPS5642675B2/ja not_active Expired
- 1975-02-03 FR FR7503334A patent/FR2259921B1/fr not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0047595A1 (en) * | 1980-09-10 | 1982-03-17 | Marston Palmer Ltd. | Electrochemical cell |
JPS5779189A (en) * | 1980-09-10 | 1982-05-18 | Imi Marston Ltd | Electrode material for electrochemical reaction and electrochemical apparatus |
JPH0225994B2 (en) * | 1980-09-10 | 1990-06-06 | Ebonetsukusu Tekunorojiizu Inc | |
US4964966A (en) * | 1988-03-01 | 1990-10-23 | Moreland Peter J | Electrode and construction thereof |
US4912286A (en) * | 1988-08-16 | 1990-03-27 | Ebonex Technologies Inc. | Electrical conductors formed of sub-oxides of titanium |
EP0438839A1 (en) * | 1988-08-16 | 1991-07-31 | Atraverda Limited | Electrical conductors formed of sub-oxides of titanium |
EP0443230A1 (en) * | 1990-02-20 | 1991-08-28 | Atraverda Limited | Electrochemical cell and process |
WO2017050867A1 (en) * | 2015-09-25 | 2017-03-30 | Akzo Nobel Chemicals International B.V. | Electrode |
CN108026650A (en) * | 2015-09-25 | 2018-05-11 | 阿克苏诺贝尔化学品国际有限公司 | Electrode |
CN108026650B (en) * | 2015-09-25 | 2020-12-11 | 阿克苏诺贝尔化学品国际有限公司 | Electrode for electrochemical cell |
US11041249B2 (en) | 2015-09-25 | 2021-06-22 | Nouryon Chemicals International B.V. | Electrode |
US11326266B2 (en) | 2015-09-25 | 2022-05-10 | Nouryon Chemicals International B.V. | Electrode |
Also Published As
Publication number | Publication date |
---|---|
JPS50109176A (en) | 1975-08-28 |
SE7501094L (en) | 1975-08-04 |
IT1031341B (en) | 1979-04-30 |
SE398894B (en) | 1978-01-23 |
NL7417054A (en) | 1975-08-05 |
FR2259921A1 (en) | 1975-08-29 |
NO141419C (en) | 1980-03-05 |
NO141419B (en) | 1979-11-26 |
NO744435L (en) | 1975-08-05 |
CA1040137A (en) | 1978-10-10 |
CH613995A5 (en) | 1979-10-31 |
FR2259921B1 (en) | 1979-01-05 |
JPS5642675B2 (en) | 1981-10-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |