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GB1443008A - Hydrocarbon isomerization catalyst and method of preparation and use thereof - Google Patents

Hydrocarbon isomerization catalyst and method of preparation and use thereof

Info

Publication number
GB1443008A
GB1443008A GB4527873A GB4527873A GB1443008A GB 1443008 A GB1443008 A GB 1443008A GB 4527873 A GB4527873 A GB 4527873A GB 4527873 A GB4527873 A GB 4527873A GB 1443008 A GB1443008 A GB 1443008A
Authority
GB
United Kingdom
Prior art keywords
isomerization
give
catalyst
hydrocarbon
dimethylbutane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4527873A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UOP LLC filed Critical UOP LLC
Publication of GB1443008A publication Critical patent/GB1443008A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/226Catalytic processes not covered by C07C5/23 - C07C5/31 with metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2791Catalytic processes with metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06Halogens; Compounds thereof
    • C07C2527/125Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126Aluminium chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1443008 Isomerizing hydrocarbons; catalyst for cracking hydrocarbons UOP Inc 27 Sept 1973 [28 Sept 1972 (3)] 45278/73 Heading C5E [Also in Division B1] Hydrocarbon feeds are converted, e.g. hydrocracked, hydrotreated and, in particular, isomerized in contact with a catalyst formed by reacting an alumina composite containing 0À1 to 5% wt. of a platinum group metal or nickel firstly with a Friedel-Crafts metal halide then, in a non-reducing atmosphere at 100-600‹ C., with a polyhalo compound which contains at least two halogen atoms on the same carbon or sulphur atom or is a boron trihalide. The isomerization may be effected at 65-235‹ C., a pressure of 1 to 140 atmos., a LHSV of 0À5 to 10 and a hydrogen to hydrocarbon mole ratio of 0À25 :1 to 20 : 1. The feed may be a C 4 -C 8 straight chain paraffin hydrocarbon, 2- or 3- methylpentane (to give 2,2- and 2,3-dimethylbutane) or a naphthene, e.g. dimethylcyclopentane (to give methylcyclohexane) or methylcyclopentane to cyclohexane. The Examples describe the isomerization of butane and of a mixed n-pentane/n-hexane feed to give isopentane and 2,2-dimethylbutane. Catalysts containing nickel as the Group VIII metal are suited to C 4 isomerization but not C 5 isomerization. The use of the catalyst for hydrocracking of heavy oils to form petroleum and LPG at up to 300‹ C. and a pressure of 5 to 70 atm. is also mentioned.
GB4527873A 1972-09-28 1973-09-27 Hydrocarbon isomerization catalyst and method of preparation and use thereof Expired GB1443008A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US29323772A 1972-09-28 1972-09-28
US29323272A 1972-09-28 1972-09-28
US29322972A 1972-09-28 1972-09-28
US29323072A 1972-09-28 1972-09-28

Publications (1)

Publication Number Publication Date
GB1443008A true GB1443008A (en) 1976-07-21

Family

ID=27501587

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4527873A Expired GB1443008A (en) 1972-09-28 1973-09-27 Hydrocarbon isomerization catalyst and method of preparation and use thereof

Country Status (18)

Country Link
AR (1) AR218597A1 (en)
AU (1) AU482013B2 (en)
BR (1) BR7307563D0 (en)
CA (1) CA1019718A (en)
CS (1) CS186712B2 (en)
DD (2) DD114055A5 (en)
FR (1) FR2201128B1 (en)
GB (1) GB1443008A (en)
HU (1) HU173538B (en)
IT (1) IT997570B (en)
NL (1) NL7313325A (en)
NO (1) NO138932C (en)
PH (1) PH10794A (en)
PL (1) PL100008B1 (en)
RO (1) RO62663A (en)
SE (1) SE400712B (en)
SU (1) SU520882A3 (en)
YU (1) YU257073A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5151400A (en) * 1989-07-18 1992-09-29 Compagnie De Raffinage Et De Distribution Total France Process for the activation of halogenated catalysts and catalysts obtained by said process for utilization in hydrocarbon conversion processes

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3227658A (en) * 1962-03-09 1966-01-04 Phillips Petroleum Co Activation of group viii metal-containing catalysts

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5151400A (en) * 1989-07-18 1992-09-29 Compagnie De Raffinage Et De Distribution Total France Process for the activation of halogenated catalysts and catalysts obtained by said process for utilization in hydrocarbon conversion processes

Also Published As

Publication number Publication date
YU257073A (en) 1982-02-25
NO138932B (en) 1978-09-04
FR2201128A1 (en) 1974-04-26
PH10794A (en) 1977-09-07
SE7313180L (en) 1974-03-29
RO62663A (en) 1978-05-15
CA1019718A (en) 1977-10-25
DE2348618B2 (en) 1976-09-09
AR218597A1 (en) 1980-06-30
HU173538B (en) 1979-06-28
AU482013B2 (en) 1975-03-27
NO138932C (en) 1978-12-13
PL100008B1 (en) 1978-08-31
AU6070073A (en) 1975-03-27
NL7313325A (en) 1974-04-01
SU520882A3 (en) 1976-07-05
DE2348618A1 (en) 1974-04-11
SE400712B (en) 1978-04-10
DD114055A5 (en) 1975-07-12
FR2201128B1 (en) 1976-10-01
BR7307563D0 (en) 1974-08-22
CS186712B2 (en) 1978-12-29
DD109371A5 (en) 1974-11-05
IT997570B (en) 1975-12-30

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee