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GB1438806A - Catalysts and processes using them - Google Patents

Catalysts and processes using them

Info

Publication number
GB1438806A
GB1438806A GB4935473A GB4935473A GB1438806A GB 1438806 A GB1438806 A GB 1438806A GB 4935473 A GB4935473 A GB 4935473A GB 4935473 A GB4935473 A GB 4935473A GB 1438806 A GB1438806 A GB 1438806A
Authority
GB
United Kingdom
Prior art keywords
aldehyde
carboxylic acids
unsaturated carboxylic
suitably
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4935473A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP9197673A priority Critical patent/JPS5529061B2/ja
Priority to FR7337589A priority patent/FR2248257B1/fr
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to NL7314507A priority patent/NL169067C/en
Priority to GB4935473A priority patent/GB1438806A/en
Priority to DE2353131A priority patent/DE2353131C3/en
Priority to NO742842A priority patent/NO142217C/en
Priority to BE147570A priority patent/BE818803A/en
Priority to SE7410384A priority patent/SE412380B/en
Priority to IT26308/74A priority patent/IT1030549B/en
Priority to CA207,101A priority patent/CA1015374A/en
Priority to BR6751/74A priority patent/BR7406751D0/en
Priority to DK436074A priority patent/DK155932C/en
Priority to ES74429309A priority patent/ES429309A1/en
Priority to IE1712/74A priority patent/IE39880B1/en
Priority to US05/545,905 priority patent/US3998876A/en
Publication of GB1438806A publication Critical patent/GB1438806A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1438806 Unsaturated carboxylic acids MITSUBISHI RAYON CO Ltd 23 Oct 1973 49354/73 Heading C2C [Also in Division B1] Unsaturated carboxylic acids, e.g. acrylic or methacrylic acids are produced by the gas phase oxidation of unsaturated aldehydes with molecular oxygen at 240-390‹ C. in the presence of a catalyst in the form of an oxidic complex of formula P a Mo b As c (NH 4 ) d X e Z f O g wherein: X is V, W, Cu, Fe, Mn and/or Sn; Z is alkali metal; a =0.03 to 0.2; b=1; c=0-015 to 0.15; d=0.01 to 0.3 ; e = 0.003 to 1; f=0 to 0.17; and g has a value to satisfy valency requirements. Specified aldehyde feeds are acrolein and methacrolein (the latter suitably having been obtained by catalytic oxidation of isobutylene or tertbutanol). Suitably, the reaction mixture contains 1 to 20% vol. of aldehyde and a mole ratio of oxygen to aldehyde of 0.3 to 4 and is fed at a space velocity of 300-10,000 hr.<SP>-1</SP> under a pressure of atmospheric or above.
GB4935473A 1973-08-16 1973-10-23 Catalysts and processes using them Expired GB1438806A (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
JP9197673A JPS5529061B2 (en) 1973-08-16 1973-08-16
FR7337589A FR2248257B1 (en) 1973-08-16 1973-10-22
NL7314507A NL169067C (en) 1973-08-16 1973-10-23 PROCESS FOR PREPARING UNSATURATED CARBONIC ACIDS AND PROCESS FOR PREPARING AN IDEAL CATALYST.
GB4935473A GB1438806A (en) 1973-08-16 1973-10-23 Catalysts and processes using them
DE2353131A DE2353131C3 (en) 1973-08-16 1973-10-23 Catalyst for the gas phase oxidation of unsaturated aldehydes to unsaturated carboxylic acids
NO742842A NO142217C (en) 1973-08-16 1974-08-07 PROCEDURE FOR THE PREPARATION OF ACRYLIC ACID OR METACRYLIC ACID BY CATALYTIC OXIDATION OF ACROLEIN OR METACROLEIN
BE147570A BE818803A (en) 1973-08-16 1974-08-13 CATALYTIC PROCESS FOR THE PREPARATION OF UNSATURATED CARBOXYLIC ACIDS FROM UNSATURATED ALDEHYDES AND NEW PRODUCTS THUS OBTAINED
SE7410384A SE412380B (en) 1973-08-16 1974-08-14 CATALYTIC PROCEDURE FOR THE PREPARATION OF UNSATATED CARBOXYLIC ACIDS.
IT26308/74A IT1030549B (en) 1973-08-16 1974-08-14 CATALYTIC PROCESS FOR THE PREPARATION OF SATURATED CARBOXYLIC ACIDS
CA207,101A CA1015374A (en) 1973-08-16 1974-08-15 Catalytic process for preparation of unsaturated carboxylic acids
BR6751/74A BR7406751D0 (en) 1973-08-16 1974-08-15 CATALYTIC PROCESS FOR PREPARING Unsaturated CARBOXYLIC ACIDS
DK436074A DK155932C (en) 1973-08-16 1974-08-15 METHOD OF PREPARING ACRYLIC ACID OR METHACRYLIC ACID
ES74429309A ES429309A1 (en) 1973-08-16 1974-08-16 Catalysts and processes using them
IE1712/74A IE39880B1 (en) 1973-08-16 1974-08-16 Catalysts and precesses using them
US05/545,905 US3998876A (en) 1973-08-16 1975-01-31 Catalytic process for preparation of unsaturated carboxylic acids

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP9197673A JPS5529061B2 (en) 1973-08-16 1973-08-16
FR7337589A FR2248257B1 (en) 1973-08-16 1973-10-22
NL7314507A NL169067C (en) 1973-08-16 1973-10-23 PROCESS FOR PREPARING UNSATURATED CARBONIC ACIDS AND PROCESS FOR PREPARING AN IDEAL CATALYST.
GB4935473A GB1438806A (en) 1973-08-16 1973-10-23 Catalysts and processes using them
DE2353131A DE2353131C3 (en) 1973-08-16 1973-10-23 Catalyst for the gas phase oxidation of unsaturated aldehydes to unsaturated carboxylic acids

Publications (1)

Publication Number Publication Date
GB1438806A true GB1438806A (en) 1976-06-09

Family

ID=27510326

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4935473A Expired GB1438806A (en) 1973-08-16 1973-10-23 Catalysts and processes using them

Country Status (14)

Country Link
JP (1) JPS5529061B2 (en)
BE (1) BE818803A (en)
BR (1) BR7406751D0 (en)
CA (1) CA1015374A (en)
DE (1) DE2353131C3 (en)
DK (1) DK155932C (en)
ES (1) ES429309A1 (en)
FR (1) FR2248257B1 (en)
GB (1) GB1438806A (en)
IE (1) IE39880B1 (en)
IT (1) IT1030549B (en)
NL (1) NL169067C (en)
NO (1) NO142217C (en)
SE (1) SE412380B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0088327A2 (en) * 1982-03-10 1983-09-14 BASF Aktiengesellschaft Process for the preparation of methacrylic acid
EP0092023A1 (en) * 1982-04-21 1983-10-26 Bridgestone Tire Company Limited Use of a catalyst for cleaning exhaust gas particulates
EP1253132A1 (en) * 2001-04-25 2002-10-30 Nippon Shokubai Co., Ltd. Process for producing (meth)acrylic acid

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57297B2 (en) * 1974-01-19 1982-01-06
JPS5946934B2 (en) * 1976-02-09 1984-11-15 東ソー株式会社 Method for manufacturing methacrylic acid
US4110369A (en) * 1976-10-19 1978-08-29 The Standard Oil Company Process for the preparation of unsaturated acids from unsaturated aldehydes
IN147123B (en) * 1976-10-19 1979-11-17 Standard Oil Co Ohio
US4169070A (en) 1978-04-12 1979-09-25 Halcon Research And Development Corporation Catalyst and process for producing unsaturated acids by using same
EP0113156B1 (en) * 1983-01-05 1987-03-04 Mitsubishi Rayon Co., Ltd. Process for the calcination of phosphorus-molybdenum catalyst
JPH0791212B2 (en) * 1988-07-11 1995-10-04 三菱レイヨン株式会社 Method for producing methacrylic acid

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0088327A2 (en) * 1982-03-10 1983-09-14 BASF Aktiengesellschaft Process for the preparation of methacrylic acid
EP0088327A3 (en) * 1982-03-10 1984-06-06 Basf Aktiengesellschaft Process and catalyst for the preparation of methacrylic acid
US4925823A (en) * 1982-03-10 1990-05-15 Basf Aktiengesellschaft Process and catalyst for the preparation of methacrylic acid
EP0092023A1 (en) * 1982-04-21 1983-10-26 Bridgestone Tire Company Limited Use of a catalyst for cleaning exhaust gas particulates
EP1253132A1 (en) * 2001-04-25 2002-10-30 Nippon Shokubai Co., Ltd. Process for producing (meth)acrylic acid
US6664416B2 (en) 2001-04-25 2003-12-16 Nippon Shokubai Co., Ltd. Process for producing (meth)acrylic acid

Also Published As

Publication number Publication date
ES429309A1 (en) 1976-10-01
SE412380B (en) 1980-03-03
DK436074A (en) 1975-04-28
DK155932C (en) 1989-10-30
FR2248257B1 (en) 1977-09-09
DE2353131B2 (en) 1979-06-13
IE39880B1 (en) 1979-01-17
DK155932B (en) 1989-06-05
NL7314507A (en) 1975-04-25
BR7406751D0 (en) 1975-06-03
DE2353131C3 (en) 1980-02-14
NL169067C (en) 1982-01-04
FR2248257A1 (en) 1975-05-16
JPS5041811A (en) 1975-04-16
NO142217C (en) 1980-07-30
DE2353131A1 (en) 1975-04-24
NO742842L (en) 1975-03-17
CA1015374A (en) 1977-08-09
IT1030549B (en) 1979-04-10
JPS5529061B2 (en) 1980-07-31
BE818803A (en) 1974-12-02
NO142217B (en) 1980-04-08
SE7410384L (en) 1975-02-17
IE39880L (en) 1975-02-16

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years

Effective date: 19931022