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GB1434119A - Quaternary polyfluoroalkyl thioalkylamine salts and their use as surfactants - Google Patents

Quaternary polyfluoroalkyl thioalkylamine salts and their use as surfactants

Info

Publication number
GB1434119A
GB1434119A GB5330173A GB5330173A GB1434119A GB 1434119 A GB1434119 A GB 1434119A GB 5330173 A GB5330173 A GB 5330173A GB 5330173 A GB5330173 A GB 5330173A GB 1434119 A GB1434119 A GB 1434119A
Authority
GB
United Kingdom
Prior art keywords
quaternary
thioalkylamine
polyfluoroalkyl
surfactants
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5330173A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1434119A publication Critical patent/GB1434119A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/24Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/25Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02Formic acid
    • C07C53/06Salts thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/122Propionic acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/124Acids containing four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/004Surface-active compounds containing F

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

1434119 Quaternary fluoroalkylthioethers E I DU PONT DE NEMOURS & CO 16 Nov 1973 [20 Nov 1972] 53301/73 Heading C2C Quaternary fluoroalkylthioethers of general formula wherein n is an integer of 4-14; R 1 and R 2 are each C 1-4 alkyl; R 3 is either C 1-4 alkyl and the quaternary cation has a solubilizing anion (X-) associated with it, or is a covalently bonded group -(CH 2 )qSO 3 - or -(CH 2 ) m COO- in which q is integer 2-4 and m is an integer 1-3, are prepared in conventional manner by quaternization of F(CF 2 ) n CH 2 CH 2 -S-CH 2 CH 2 NR 1 R 2 with R 3 X, ClCH 2 COOH or 1,3-propane sultone. Amongst the examples the compounds and in which n = mixture of 4-14, are prepared. C 6 F 13 (CH 2 ) 2 S(CH 2 ) 2 N(CH 3 ) 2 and the corresponding C 8 F 17 -, C 10 F 21 and C 4-14 F 9-29 -derivatives are prepared by reaction of
GB5330173A 1972-11-20 1973-11-16 Quaternary polyfluoroalkyl thioalkylamine salts and their use as surfactants Expired GB1434119A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US30785372A 1972-11-20 1972-11-20

Publications (1)

Publication Number Publication Date
GB1434119A true GB1434119A (en) 1976-05-05

Family

ID=23191457

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5330173A Expired GB1434119A (en) 1972-11-20 1973-11-16 Quaternary polyfluoroalkyl thioalkylamine salts and their use as surfactants

Country Status (5)

Country Link
JP (1) JPS4981287A (en)
DE (1) DE2357916A1 (en)
FR (1) FR2207187B1 (en)
GB (1) GB1434119A (en)
IT (1) IT998936B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4132674A (en) 1977-12-21 1979-01-02 Calgon Corporation Electroconductive coating formulation
EP0002004A1 (en) * 1977-11-07 1979-05-30 Ciba-Geigy Ag Process for the manufacture of fluorinated cationic compounds and their use as surfactants

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54135721A (en) * 1978-04-13 1979-10-22 Daikin Ind Ltd Fluorine-containing betaine compound, its preparation and applications
DE3347378A1 (en) * 1983-12-29 1985-07-11 Hoechst Ag, 6230 Frankfurt FLUORINATED QUATERNAIRE AMMONIUM COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF AS A FLOW ACCELERATOR
JPS6312333A (en) * 1986-07-03 1988-01-19 Matsumoto Yushi Seiyaku Kk Production of amphoteric surface active agent
US4836958A (en) * 1986-07-31 1989-06-06 Ciba-Geigy Corporation Fluorinated cationic compounds
FR2620445B1 (en) * 1987-09-16 1990-07-20 Centre Nat Rech Scient NOVEL FLUORINATED DERIVATIVES OF AMINO ACIDS, IN PARTICULAR FOR USE AS SURFACTANTS OR COTENSIOACTIVES AND BIOMEDICAL PREPARATIONS COMPRISING SUCH DERIVATIVES
FR2647112A1 (en) * 1989-05-22 1990-11-23 Atochem NITROGEN POLYFLUORALKYL COMPOUNDS, PROCESSES FOR THEIR PREPARATION AND THEIR APPLICATIONS
FR2866883B1 (en) * 2004-02-27 2006-03-31 Stephane Szonyi NEW PERFLUOROALKYL, HYDROPHOBIC AND OLEOPHOBIC SURFACTANTS DERIVED FROM SUBSTITUTED AMIDES, THEIR PREPARATION AND THEIR USE
FR3137982A1 (en) 2022-07-13 2024-01-19 Psa Automobiles Sa Method and device for managing a stop of an autonomous vehicle traveling on a traffic lane.

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA962281A (en) * 1971-08-21 1975-02-04 Sameeh S. Toukan Fluorinated alkyl sulfides and process for their preparation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002004A1 (en) * 1977-11-07 1979-05-30 Ciba-Geigy Ag Process for the manufacture of fluorinated cationic compounds and their use as surfactants
US4132674A (en) 1977-12-21 1979-01-02 Calgon Corporation Electroconductive coating formulation

Also Published As

Publication number Publication date
DE2357916A1 (en) 1974-05-22
FR2207187A1 (en) 1974-06-14
IT998936B (en) 1976-02-20
JPS4981287A (en) 1974-08-06
FR2207187B1 (en) 1976-10-01

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee