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GB1408611A - Titanium trichloride - Google Patents

Titanium trichloride

Info

Publication number
GB1408611A
GB1408611A GB4622272A GB4622272A GB1408611A GB 1408611 A GB1408611 A GB 1408611A GB 4622272 A GB4622272 A GB 4622272A GB 4622272 A GB4622272 A GB 4622272A GB 1408611 A GB1408611 A GB 1408611A
Authority
GB
United Kingdom
Prior art keywords
ticl
temperature
catalyst
aluminium halide
dialkyl aluminium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4622272A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB4622272A priority Critical patent/GB1408611A/en
Priority to BR6475/73A priority patent/BR7306475D0/en
Priority to AU59487/73A priority patent/AU484234B2/en
Priority to FR7330465A priority patent/FR2202107B1/fr
Priority to IT52121/73A priority patent/IT990394B/en
Priority to DE19732342416 priority patent/DE2342416A1/en
Priority to JP48093392A priority patent/JPS49123999A/ja
Priority to NL7311562A priority patent/NL7311562A/xx
Priority to ZA735763A priority patent/ZA735763B/en
Priority to BE1005314A priority patent/BE803978A/en
Publication of GB1408611A publication Critical patent/GB1408611A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

1408611 Titanium trichloride polymerization catalyst SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 22 Aug 1973 [6 Oct 1972] 46222/72 Heading C3P Unsaturated hydrocarbons are polymerized in the presence of a catalyst obtained by (a) reducing TiCl 4 by gradually adding at least 0À9 molar parts of TiCl 4 to 1 molar part of a trialkylaluminium at a temperature below 220‹ K., (b) bringing the temperature to between 220‹ K. and 270‹ K., (c) adding and reducing at this temperature range more TiCl 4 and adjusting, if necessary, the total amount of dialkyl aluminium halide so as to obtain a molar ratio of TiCl 4 to dialkyl aluminium halide of from 2 : 1 to 1 : 2, and (d) subsequently raising the temperature to between 350‹ and 570‹ K. to convert the beta-TiCl 3 to gamma-TiCl 3 . The catalyst is activated by addition of further dialkyl aluminium halide. Optionally the above procedure may be modified by raising the temperature of the reaction mixture between steps (a) and (b) to above 290‹ K. and below 350‹ K. and the product of step (d) may be treated with Lewis bases such as ethers, alkanes or trialkyl aluminiums, or may be treated with sufficient propene, in liquid diluent and with heating, to produce a small amount of polymer associated with the catalyst, prior to the polymerization proper. In the examples catalysts are prepared according to the above procedures and used to prepare polypropylene and propylene-b-ethylene-co-propylene copolymer.
GB4622272A 1972-10-06 1972-10-06 Titanium trichloride Expired GB1408611A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
GB4622272A GB1408611A (en) 1972-10-06 1972-10-06 Titanium trichloride
BR6475/73A BR7306475D0 (en) 1972-10-06 1973-08-22 PROCESS FOR PREPARING A TITANIUM TRICHORIDE COMPOSITION
AU59487/73A AU484234B2 (en) 1972-10-06 1973-08-22 Titanium trichloride composition
FR7330465A FR2202107B1 (en) 1972-10-06 1973-08-22
IT52121/73A IT990394B (en) 1972-10-06 1973-08-22 PROCEDURE FOR PREPARING A COM POSITION OF TITANIUM TRICHLORIDE
DE19732342416 DE2342416A1 (en) 1972-10-06 1973-08-22 PROCESS FOR THE PRODUCTION OF TITANIUM TRICHLORIDE COMPOUNDS AND THEIR USE FOR THE POLYMERIZATION OF UNSATURATED HYDROCARBONS
JP48093392A JPS49123999A (en) 1972-10-06 1973-08-22
NL7311562A NL7311562A (en) 1972-10-06 1973-08-22
ZA735763A ZA735763B (en) 1972-10-06 1973-08-22 Titanium trichloride composition
BE1005314A BE803978A (en) 1972-10-06 1973-08-24 PROCESS FOR PREPARING TITANRIC TRICHLORIDE CONTAINING COMPOSITIONS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4622272A GB1408611A (en) 1972-10-06 1972-10-06 Titanium trichloride

Publications (1)

Publication Number Publication Date
GB1408611A true GB1408611A (en) 1975-10-01

Family

ID=10440360

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4622272A Expired GB1408611A (en) 1972-10-06 1972-10-06 Titanium trichloride

Country Status (9)

Country Link
JP (1) JPS49123999A (en)
BE (1) BE803978A (en)
BR (1) BR7306475D0 (en)
DE (1) DE2342416A1 (en)
FR (1) FR2202107B1 (en)
GB (1) GB1408611A (en)
IT (1) IT990394B (en)
NL (1) NL7311562A (en)
ZA (1) ZA735763B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4431569A (en) * 1979-12-12 1984-02-14 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE887698A (en) * 1980-02-27 1981-08-26 Exxon Research Engineering Co IMPROVED TIC1 CATALYTIC SYSTEM FOR THE POLYMERIZATION OF ALPHA-OLEFINS
DE19843858A1 (en) 1998-09-25 2000-04-06 Ticona Gmbh Process for the production of a polymer

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1529318A (en) * 1966-06-30 1968-06-14 Shell Int Research Process for the preparation of compositions comprising titanium trichloride and process for the polymerization of unsaturated hydrocarbons of the ethylenic type, these compositions being used as a catalyst component

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4431569A (en) * 1979-12-12 1984-02-14 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof

Also Published As

Publication number Publication date
BR7306475D0 (en) 1974-07-18
JPS49123999A (en) 1974-11-27
ZA735763B (en) 1974-07-31
DE2342416A1 (en) 1974-04-11
BE803978A (en) 1974-02-25
IT990394B (en) 1975-06-20
FR2202107B1 (en) 1977-02-25
FR2202107A1 (en) 1974-05-03
NL7311562A (en) 1974-04-09
AU5948773A (en) 1975-02-27

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee