GB1402582A - Process for the manufacture of phosphorus-containing conden sation products the products and their use as flameproofing agents - Google Patents
Process for the manufacture of phosphorus-containing conden sation products the products and their use as flameproofing agentsInfo
- Publication number
- GB1402582A GB1402582A GB4110272A GB4110272A GB1402582A GB 1402582 A GB1402582 A GB 1402582A GB 4110272 A GB4110272 A GB 4110272A GB 4110272 A GB4110272 A GB 4110272A GB 1402582 A GB1402582 A GB 1402582A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fabrics
- condensation products
- formaldehyde
- products
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007859 condensation product Substances 0.000 title abstract 5
- 239000003795 chemical substances by application Substances 0.000 title abstract 2
- 239000000047 product Substances 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 9
- 239000004744 fabric Substances 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 2
- 150000002830 nitrogen compounds Chemical class 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- SUPOBRXPULIDDX-UHFFFAOYSA-N [[4-amino-6-(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound NC1=NC(NCO)=NC(NCO)=N1 SUPOBRXPULIDDX-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- -1 tetrakis(hydroxymethyl)-phosphonium compound Chemical class 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/667—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain
- D06M15/673—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain containing phosphorus and nitrogen in the main chain
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/34—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds and acyclic or carbocyclic compounds
- C08G12/36—Ureas; Thioureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/40—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
- C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
- C08G16/0212—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds
- C08G16/0218—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen
- C08G16/0243—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/32—Modified amine-aldehyde condensates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/667—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/15—Impregnating involving polymerisation including use of polymer-containing impregnating agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
1402582 Flame-proofing materials CIBAGEIGY AG 5 Sept 1972 [14 Jan 1972] 41102/ 72 Heading DIP [Also in Division C3] Materials especiallly fabrics are flameproofed with condensation products obtained by condensing 1 mol of a tetrakis(hydroxymethyl)-phosphonium compound with 0.02 to 1 mol of a compound of formula or its salt, where R is hydrogen, hydroxyl or an optionally substituted aliphatic, cycloalipha'tic, aromatic or heterocyclic radical, at 40 to 120C, optionally with formaldehyde or a formaldehyde-releasing agent and optionally in an inert organic solvent. The condensation may have been continued at 100 to 150C and free hydroxyl groups may have been etherified. The fabrics are flameproofed by applying to them aqueous compositions containing the condensation products together with polyfunctional epoxides or polyfunctional nitrogen compounds. In examples te'trakis-(hydroxymethyl)- phosphonium chloride and hydroxide are condensed with hydrochloric acid salts of compounds of the above formula where R is hydrogen and where R is methyl: in one instance formaldehyde is present and in another the product is etherified with methanol: aqueous compositions containing the condensation products together with dimethylolmelamine as a polyfunctional nitrogen compound, are applied to fabrics of polyester mixed with cotton, and of wool and cotton, the fabrics then being dried and heated, heated while moist and partially dried and then contacted with ammonia, to cure the condensation products.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH51972A CH547904B (en) | 1972-01-14 | 1972-01-14 | USE OF WATER-SOLUBLE, PHOSPHORUS CONTAINING CONDENSATION PRODUCTS TOGETHER WITH POLYFUNCTIONAL COMPOUNDS FOR FLAME RETAINING TEXTILE MATERIALS. |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1402582A true GB1402582A (en) | 1975-08-13 |
Family
ID=4188854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4110272A Expired GB1402582A (en) | 1972-01-14 | 1972-09-05 | Process for the manufacture of phosphorus-containing conden sation products the products and their use as flameproofing agents |
Country Status (16)
Country | Link |
---|---|
JP (1) | JPS4880894A (en) |
AR (1) | AR195974A1 (en) |
AT (1) | AT317835B (en) |
AU (1) | AU470268B2 (en) |
BE (1) | BE788593A (en) |
CA (1) | CA997347A (en) |
CH (2) | CH547904B (en) |
CS (1) | CS161666B2 (en) |
DE (1) | DE2242676A1 (en) |
FR (1) | FR2167496B1 (en) |
GB (1) | GB1402582A (en) |
IL (1) | IL40241A (en) |
IT (1) | IT965270B (en) |
NL (1) | NL7212265A (en) |
SU (1) | SU526296A3 (en) |
ZA (1) | ZA725952B (en) |
-
0
- BE BE788593D patent/BE788593A/en unknown
-
1972
- 1972-01-14 CH CH51972A patent/CH547904B/en not_active IP Right Cessation
- 1972-01-14 CH CH51972D patent/CH51972A4/xx unknown
- 1972-08-29 IL IL40241A patent/IL40241A/en unknown
- 1972-08-30 ZA ZA725952A patent/ZA725952B/en unknown
- 1972-08-30 DE DE2242676A patent/DE2242676A1/en active Pending
- 1972-08-31 AU AU46192/72A patent/AU470268B2/en not_active Expired
- 1972-08-31 CA CA150,645A patent/CA997347A/en not_active Expired
- 1972-09-05 GB GB4110272A patent/GB1402582A/en not_active Expired
- 1972-09-06 SU SU1825121A patent/SU526296A3/en active
- 1972-09-07 FR FR7231665A patent/FR2167496B1/fr not_active Expired
- 1972-09-08 CS CS6180A patent/CS161666B2/cs unknown
- 1972-09-08 NL NL7212265A patent/NL7212265A/xx unknown
- 1972-09-08 AR AR243984A patent/AR195974A1/en active
- 1972-09-08 IT IT52624/72A patent/IT965270B/en active
- 1972-09-08 AT AT772272A patent/AT317835B/en not_active IP Right Cessation
- 1972-09-09 JP JP47090050A patent/JPS4880894A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
AU470268B2 (en) | 1976-03-11 |
FR2167496B1 (en) | 1974-12-06 |
BE788593A (en) | 1973-03-08 |
FR2167496A1 (en) | 1973-08-24 |
ZA725952B (en) | 1973-06-27 |
CS161666B2 (en) | 1975-06-10 |
IL40241A0 (en) | 1972-10-29 |
IL40241A (en) | 1976-06-30 |
AR195974A1 (en) | 1973-11-23 |
AU4619272A (en) | 1974-03-07 |
NL7212265A (en) | 1973-07-17 |
CA997347A (en) | 1976-09-21 |
CH51972A4 (en) | 1973-08-15 |
SU526296A3 (en) | 1976-08-25 |
JPS4880894A (en) | 1973-10-29 |
DE2242676A1 (en) | 1973-07-19 |
CH547904B (en) | 1974-04-11 |
AT317835B (en) | 1974-09-10 |
IT965270B (en) | 1974-01-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |