GB1386069A - Extraction or iron - Google Patents
Extraction or ironInfo
- Publication number
- GB1386069A GB1386069A GB5417570A GB5417570A GB1386069A GB 1386069 A GB1386069 A GB 1386069A GB 5417570 A GB5417570 A GB 5417570A GB 5417570 A GB5417570 A GB 5417570A GB 1386069 A GB1386069 A GB 1386069A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fecl
- hcl
- iron
- agent containing
- feedstock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract 12
- 229910052742 iron Inorganic materials 0.000 title abstract 5
- 238000000605 extraction Methods 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 230000007812 deficiency Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/10—Hydrochloric acid, other halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/10—Halides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Compounds Of Iron (AREA)
Abstract
1386069 Chemical extraction of iron NATIONAL RESEARCH DEVELOPMENT CORP 14 Feb 1972 54175/70 Heading ClA [Also in Division C7] Iron is extracted in a process which comprises converting iron contained in a feedstock into FeCl 2 in the form of an aqueous solution using an aqueous chloridizing agent containing HCl, precipitating the FeCl 2 from the solution using an agent containing HCl, oxidizing the FeCl 2 to FeCl 3 , and reducing the FeCl 3 to metallic Fe using a gaseous reducing agent containing H 2 . Preferably the oxidation takes place at a temperature at which FeCl 3 is volatile, under anhydrous conditions and with an oxidizing agent containing O 2 . The effluent HCl-containing gas from the reduction stage may be used as a source of HCl for the chloridation and/or precipitation stages, and the heat in the gas may be used to dry the FeCl 2 prior to oxidation. The feedstock preferably contains metallic iron but may be an iron oxide and is preferably chloridated at atmospheric pressure and at 85‹ to 105‹ C. The reduction may be carried out in two stages, the reaction being preferably at 600‹ to 800‹ C. and the product may be in the form of a powder. If the raw material used is Fe 2 O 3 , chloridation yields FeCl 3 and either steps may be taken to avoid this or the FeCl 3 must be reduced to FeCl 2 before continuing. It is also possible to use FeS as feedstock. Cl 2 or FeCl 2 may be added in the oxidation stage where there is an HCl deficiency.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5417570A GB1386069A (en) | 1970-11-13 | 1970-11-13 | Extraction or iron |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5417570A GB1386069A (en) | 1970-11-13 | 1970-11-13 | Extraction or iron |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1386069A true GB1386069A (en) | 1975-03-05 |
Family
ID=10470167
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5417570A Expired GB1386069A (en) | 1970-11-13 | 1970-11-13 | Extraction or iron |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1386069A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1037335C (en) * | 1993-05-07 | 1998-02-11 | 埃勒夫阿托化学有限公司 | Process for the preparation of ferric chloride |
| WO2011072318A1 (en) * | 2009-12-17 | 2011-06-23 | Sms Siemag Process Technologies Gmbh | Method and device for producing an iron(iii) chloride solution |
-
1970
- 1970-11-13 GB GB5417570A patent/GB1386069A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1037335C (en) * | 1993-05-07 | 1998-02-11 | 埃勒夫阿托化学有限公司 | Process for the preparation of ferric chloride |
| WO2011072318A1 (en) * | 2009-12-17 | 2011-06-23 | Sms Siemag Process Technologies Gmbh | Method and device for producing an iron(iii) chloride solution |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |