GB1384439A - Cationic conditioning agents for potash flotation - Google Patents
Cationic conditioning agents for potash flotationInfo
- Publication number
- GB1384439A GB1384439A GB5479772A GB5479772A GB1384439A GB 1384439 A GB1384439 A GB 1384439A GB 5479772 A GB5479772 A GB 5479772A GB 5479772 A GB5479772 A GB 5479772A GB 1384439 A GB1384439 A GB 1384439A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymer
- froth
- potash
- pulp
- flotation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 title abstract 4
- 239000003795 chemical substances by application Substances 0.000 title abstract 4
- 229940072033 potash Drugs 0.000 title abstract 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 title abstract 4
- 235000015320 potassium carbonate Nutrition 0.000 title abstract 4
- 238000005188 flotation Methods 0.000 title abstract 3
- 230000003750 conditioning effect Effects 0.000 title abstract 2
- 125000002091 cationic group Chemical group 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 3
- 238000009291 froth flotation Methods 0.000 abstract 2
- OEYNWAWWSZUGDU-UHFFFAOYSA-N 1-methoxypropane-1,2-diol Chemical compound COC(O)C(C)O OEYNWAWWSZUGDU-UHFFFAOYSA-N 0.000 abstract 1
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 abstract 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000000994 depressogenic effect Effects 0.000 abstract 1
- 238000010586 diagram Methods 0.000 abstract 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 abstract 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 abstract 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
- B03D1/011—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/007—Modifying reagents for adjusting pH or conductivity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/04—Frothers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/10—Potassium ores
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Physical Water Treatments (AREA)
- Treatment Of Sludge (AREA)
Abstract
1384439 Froth flotation CALGON CORP 27 Nov 1972 [3 Dec 1971] 54797/72 Heading B2H A potash froth flotation process comprises grinding a potash ore, mixing the ground ore with an aqueous solution of a salt, e.g. saturated brine solution, to form a pulp, adding to the pulp a collecting agent, a frothing agent and a slime depressant consisting of a watersoluble diallyl dialkyl quaternary ammonium polymer having a molecular weight of at least 1,000, aerating the pulp to form a froth, collecting the froth and recovering potash values, e.g. sylvite, therefrom. The polymer concentration may be between 0.001 and 1.0 pound per ton of dry ore. In a multi-step process the polymer may be added at the conditioning stages prior to any of the flotation steps. The polymer may be one of dimethyl diallyl ammonium chloride. An amine may be used as collector and methoxy propylene glycol and methyl isobutyl carbinol as frothing agents. A flow diagram of a three-step flotation process and results of camparative tests are given.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20464771A | 1971-12-03 | 1971-12-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1384439A true GB1384439A (en) | 1975-02-19 |
Family
ID=22758831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5479772A Expired GB1384439A (en) | 1971-12-03 | 1972-11-27 | Cationic conditioning agents for potash flotation |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3782546A (en) |
| CA (1) | CA968888A (en) |
| DE (1) | DE2259009A1 (en) |
| FR (1) | FR2162178B3 (en) |
| GB (1) | GB1384439A (en) |
| IT (1) | IT973527B (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4441993A (en) * | 1975-11-03 | 1984-04-10 | Fluor Corporation | Flotation process |
| US4141691A (en) * | 1977-12-12 | 1979-02-27 | Calgon Corporation | Use of water soluble polymers in coal flotation circuits |
| US4198288A (en) * | 1979-03-22 | 1980-04-15 | Celanese Polymer Specialties Company | Desliming of potash ores |
| DE3435124C2 (en) * | 1984-09-25 | 1987-03-05 | Kali Und Salz Ag, 3500 Kassel | Process for the production of potassium chloride with more than 55 wt.% K↓2↓O from the fine decomposition salt of carnallite decomposition |
| US5013452A (en) * | 1989-06-23 | 1991-05-07 | Petrolite Corporation | Resolution of emulsions formed in the production of pharmaceuticals |
| GB9106747D0 (en) * | 1991-03-28 | 1991-05-15 | Fospur Ltd | Froth flotation of fine particles |
| CA2124301A1 (en) | 1993-06-09 | 1994-12-10 | Manian Ramesh | Hydrophobic demulsifiers for oil-in-water systems |
| US8757389B2 (en) | 2004-12-23 | 2014-06-24 | Georgia-Pacific Chemicals Llc | Amine-aldehyde resins and uses thereof in separation processes |
| US8127930B2 (en) * | 2004-12-23 | 2012-03-06 | Georgia-Pacific Chemicals Llc | Amine-aldehyde resins and uses thereof in separation processes |
| US7913852B2 (en) | 2004-12-23 | 2011-03-29 | Georgia-Pacific Chemicals Llc | Modified amine-aldehyde resins and uses thereof in separation processes |
| US8011514B2 (en) * | 2004-12-23 | 2011-09-06 | Georgia-Pacific Chemicals Llc | Modified amine-aldehyde resins and uses thereof in separation processes |
| US8702993B2 (en) | 2004-12-23 | 2014-04-22 | Georgia-Pacific Chemicals Llc | Amine-aldehyde resins and uses thereof in separation processes |
| US8092686B2 (en) | 2004-12-23 | 2012-01-10 | Georgia-Pacific Chemicals Llc | Modified amine-aldehyde resins and uses thereof in separation processes |
| US8268975B2 (en) | 2009-04-03 | 2012-09-18 | Dow Agrosciences Llc | Demulsification compositions, systems and methods for demulsifying and separating aqueous emulsions |
| CA2893121A1 (en) * | 2012-12-20 | 2014-06-26 | Akzo Nobel Chemicals International B.V. | Polyquaternary polymer as a depressant in a method for froth flotation of potash ores |
| WO2018045025A1 (en) * | 2016-08-31 | 2018-03-08 | Kemiraoyj | Cationic polymer selective depressants and use thereof in mineral ore purification methods |
| RU2738883C1 (en) * | 2020-03-02 | 2020-12-17 | Публичное акционерное общество "Уралкалий" (ПАО "Уралкалий") | Flotation dressing method of potassium ores |
| CN115961146B (en) * | 2022-12-21 | 2025-02-07 | 中国恩菲工程技术有限公司 | A comprehensive treatment method for potassium-containing fine-grained mixed copper ore |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2923408A (en) * | 1954-12-27 | 1960-02-02 | Dow Chemical Co | Flotation process |
| US3165465A (en) * | 1961-05-04 | 1965-01-12 | Armour & Co | Flocculation and settling of liquid suspensions of finely-divided minerals |
| US3259237A (en) * | 1963-04-22 | 1966-07-05 | Saskatchewan Potash | Phase desliming and concentration of potash ores |
| US3321649A (en) * | 1964-12-28 | 1967-05-23 | Shell Oil Co | Separation of suspended solids by cationic polymeric flocculants |
| US3408292A (en) * | 1966-03-24 | 1968-10-29 | Nalco Chemical Co | Water filtration process |
| US3452867A (en) * | 1967-03-30 | 1969-07-01 | Hercules Inc | Treatment of sylvinite ores |
-
1971
- 1971-12-03 US US00204647A patent/US3782546A/en not_active Expired - Lifetime
-
1972
- 1972-10-20 CA CA154,642A patent/CA968888A/en not_active Expired
- 1972-11-13 IT IT53991/72A patent/IT973527B/en active
- 1972-11-27 GB GB5479772A patent/GB1384439A/en not_active Expired
- 1972-12-01 DE DE2259009A patent/DE2259009A1/en active Pending
- 1972-12-01 FR FR7242856A patent/FR2162178B3/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2259009A1 (en) | 1973-06-14 |
| IT973527B (en) | 1974-06-10 |
| CA968888A (en) | 1975-06-03 |
| FR2162178B3 (en) | 1974-10-31 |
| FR2162178A1 (en) | 1973-07-13 |
| US3782546A (en) | 1974-01-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] |