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GB1371440A - Process for preparing a wide-pore adsorbent for use in chromato graphy - Google Patents

Process for preparing a wide-pore adsorbent for use in chromato graphy

Info

Publication number
GB1371440A
GB1371440A GB2626572A GB2626572A GB1371440A GB 1371440 A GB1371440 A GB 1371440A GB 2626572 A GB2626572 A GB 2626572A GB 2626572 A GB2626572 A GB 2626572A GB 1371440 A GB1371440 A GB 1371440A
Authority
GB
United Kingdom
Prior art keywords
silica
xerogel
suspension
modifying agent
polyphenyldisiloxane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2626572A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MO G UNI IM MV LOMONOSOVA
Moskovsky Gosudarstvenny Universitet Imeni M V Lomonosova
Original Assignee
MO G UNI IM MV LOMONOSOVA
Moskovsky Gosudarstvenny Universitet Imeni M V Lomonosova
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE19722226587 priority Critical patent/DE2226587C3/en
Priority claimed from DE19722226587 external-priority patent/DE2226587C3/en
Application filed by MO G UNI IM MV LOMONOSOVA, Moskovsky Gosudarstvenny Universitet Imeni M V Lomonosova filed Critical MO G UNI IM MV LOMONOSOVA
Priority to GB2626572A priority patent/GB1371440A/en
Priority to FR7221559A priority patent/FR2187382B1/fr
Publication of GB1371440A publication Critical patent/GB1371440A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/16—Preparation of silica xerogels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3021—Milling, crushing or grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/324—Inorganic material layers containing free carbon, e.g. activated carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3268—Macromolecular compounds
    • B01J20/3272—Polymers obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/54—Sorbents specially adapted for analytical or investigative chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/58—Use in a single column

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicon Compounds (AREA)
  • Glass Compositions (AREA)

Abstract

1371440 Silica adsorbant MOSKOVSKY GOSUDARSTVENNY UNIVERSITET IMENI MV LONONOSOVA 6 June 1972 26265/72 Heading C1A [Also in Division B1] A wide pore silica adsorbent for use in chromatography is made by forming a suspension of non-porous silica, adding a modifying agent to the suspension, drying to form a gel and then a xerogel and grinding the xerogel. The suspension of silica may be in water, in which case the modifying agent is selected from hydroxides of metals or of ammonia salts of alkali or alkaline earth metals or carbon black or the dispersion agents may be an organic solvent and thus the modifying agent may be polyphenyldisiloxane or a polycondensation product of phenolphthalein and phthalic acid. After drying the xerogel but prior to grinding it may be calcined in air or an inert atmosphere at a temperature of from 250‹ to 900‹ C. The concentration of hydroxides or ammonium salts may be from 1 to 40%, carbon content 1 to 60% and the polyphenyldisiloxane or said poly condensation product from 2 to 10%, all by weight of silica.
GB2626572A 1972-05-31 1972-06-06 Process for preparing a wide-pore adsorbent for use in chromato graphy Expired GB1371440A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE19722226587 DE2226587C3 (en) 1972-05-31 Process for the production of large-pore adsorbent for chromatography purposes
GB2626572A GB1371440A (en) 1972-05-31 1972-06-06 Process for preparing a wide-pore adsorbent for use in chromato graphy
FR7221559A FR2187382B1 (en) 1972-05-31 1972-06-15

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19722226587 DE2226587C3 (en) 1972-05-31 Process for the production of large-pore adsorbent for chromatography purposes
GB2626572A GB1371440A (en) 1972-05-31 1972-06-06 Process for preparing a wide-pore adsorbent for use in chromato graphy
FR7221559A FR2187382B1 (en) 1972-05-31 1972-06-15

Publications (1)

Publication Number Publication Date
GB1371440A true GB1371440A (en) 1974-10-23

Family

ID=27184455

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2626572A Expired GB1371440A (en) 1972-05-31 1972-06-06 Process for preparing a wide-pore adsorbent for use in chromato graphy

Country Status (2)

Country Link
FR (1) FR2187382B1 (en)
GB (1) GB1371440A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2398022A1 (en) * 1977-07-18 1979-02-16 Stamicarbon PROCESS FOR THE PREPARATION OF PURE AND POROUS SILICON BIOXIDE
FR2398021A1 (en) * 1977-07-18 1979-02-16 Stamicarbon PROCESS FOR THE PREPARATION OF PURE AND POROUS SILICON BIOXIDE
GB2142616A (en) * 1983-06-24 1985-01-23 Enea Chromatography stationary phases and process for preparing the same
US5951962A (en) * 1996-09-23 1999-09-14 Basf Aktiengesellschaft Mesoporous silica, its preparation and its use
WO2005070513A1 (en) * 2004-01-09 2005-08-04 Alltech Associates Inc. Improved recovery of analytes for process chromatography
CN104583771A (en) * 2012-08-27 2015-04-29 信和化工株式会社 Porous silica powder
CN114247180A (en) * 2021-12-24 2022-03-29 亚洲硅业(青海)股份有限公司 Application of active carbon containing oxygen groups in removal of impurities in silicon tetrachloride
US11628381B2 (en) 2012-09-17 2023-04-18 W.R. Grace & Co. Conn. Chromatography media and devices

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1531804A (en) * 1976-03-09 1978-11-08 British Petroleum Co Oil separation method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1368765A (en) * 1963-03-30 1964-08-07 Degussa Process for water-repellent finely dispersed oxides and installation for its implementation
BE709608A (en) * 1967-01-27 1968-05-30
DE2042910A1 (en) * 1970-08-29 1972-03-02 Merck Patent Gmbh Silicas with a macroporous structure

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2398022A1 (en) * 1977-07-18 1979-02-16 Stamicarbon PROCESS FOR THE PREPARATION OF PURE AND POROUS SILICON BIOXIDE
FR2398021A1 (en) * 1977-07-18 1979-02-16 Stamicarbon PROCESS FOR THE PREPARATION OF PURE AND POROUS SILICON BIOXIDE
GB2142616A (en) * 1983-06-24 1985-01-23 Enea Chromatography stationary phases and process for preparing the same
US5951962A (en) * 1996-09-23 1999-09-14 Basf Aktiengesellschaft Mesoporous silica, its preparation and its use
WO2005070513A1 (en) * 2004-01-09 2005-08-04 Alltech Associates Inc. Improved recovery of analytes for process chromatography
CN104583771A (en) * 2012-08-27 2015-04-29 信和化工株式会社 Porous silica powder
EP2829873A4 (en) * 2012-08-27 2015-10-21 Shinwa Kako Kk Porous silica powder
US9738534B2 (en) 2012-08-27 2017-08-22 Shinwa Chemical Industries Ltd. Porous silica powder
US11628381B2 (en) 2012-09-17 2023-04-18 W.R. Grace & Co. Conn. Chromatography media and devices
CN114247180A (en) * 2021-12-24 2022-03-29 亚洲硅业(青海)股份有限公司 Application of active carbon containing oxygen groups in removal of impurities in silicon tetrachloride

Also Published As

Publication number Publication date
DE2226587B2 (en) 1977-01-27
FR2187382A1 (en) 1974-01-18
DE2226587A1 (en) 1973-12-20
FR2187382B1 (en) 1976-06-11

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee