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GB1364965A - Glass fibres materials - Google Patents

Glass fibres materials

Info

Publication number
GB1364965A
GB1364965A GB3711672A GB3711672A GB1364965A GB 1364965 A GB1364965 A GB 1364965A GB 3711672 A GB3711672 A GB 3711672A GB 3711672 A GB3711672 A GB 3711672A GB 1364965 A GB1364965 A GB 1364965A
Authority
GB
United Kingdom
Prior art keywords
size
filaments
strand
sizing
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3711672A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Inc
Original Assignee
PPG Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PPG Industries Inc filed Critical PPG Industries Inc
Publication of GB1364965A publication Critical patent/GB1364965A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/36—Epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/14—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length of filaments or wires
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

1364965 Sizing glass fibres PPG INDUSTRIES Inc 9 Aug 1972 [10 Aug 1971] 37116/72 Heading D1P Filaments drawn as a strand from molten glass are treated with a size comprising starch (cooked to the swelling stage but not to the bursting stage) as 15 to 25% by weight of the non-aqueous portion of the size and the size dried on the filaments. The strands may be used in continuous or chopped form as a reinforment for polyester or epoxy resins. Preferably the non-aqueous portion of the size also comprises 25 to 35% of epoxy resin, 5 to 10% of melamine formaldehyde resin, 1 to 6% of ethylene oxidepolypropylene glycol condensate, 8 to 16% gamma methacryloxypropyltrimethoxy silane and 8 to 16% gammaglycidoxypropyltrimethoxy silane. The starch should be 50 to 60% by weight amylose, obtained from corn, wheat, potato, tapioca, waxy maze, sago or rice. The size may contain 3.4 to 3.8% polyethylene glycol monoleate emulsifier, 1.8 to 2.2% octylphenoxypolyoxyethylenethanol as nonionic surfactant up to 8% polyvinylpyrrolidone as a film former, a cationic fatty acid amide lubricant and acetic acid. A plurality of glass filaments may, be sized just after extrusion by a roller which is partly submerged in sizing solution, or by a pad applicator, and then grouped into a strand. Size comprises 0.5 to 5% of the strand weight. A strand having 6700 yards/pound and comprising 400 filaments of diameter 0.00036 inch is split after sizing into four groups of 100 filaments.
GB3711672A 1971-08-10 1972-08-09 Glass fibres materials Expired GB1364965A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US17042771A 1971-08-10 1971-08-10

Publications (1)

Publication Number Publication Date
GB1364965A true GB1364965A (en) 1974-08-29

Family

ID=22619810

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3711672A Expired GB1364965A (en) 1971-08-10 1972-08-09 Glass fibres materials

Country Status (9)

Country Link
JP (1) JPS5433320B1 (en)
BE (1) BE787378A (en)
BR (1) BR7205024D0 (en)
CA (1) CA993283A (en)
DE (1) DE2237902A1 (en)
FR (1) FR2148505A1 (en)
GB (1) GB1364965A (en)
IT (1) IT964631B (en)
NL (1) NL7209753A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4244844A (en) 1977-01-19 1981-01-13 Saint-Gobain Industries Aqueous size for glass fibers
US5633075A (en) * 1988-01-12 1997-05-27 Raychem Limited Composite material
US11001525B2 (en) 2016-06-17 2021-05-11 Owens Corning Intellectual Capital, Llc Sizing composition for wet use chopped strand glass fibers

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4391876A (en) * 1980-04-02 1983-07-05 Ppg Industries, Inc. Aqueous peroxide emulsion for use with glass fibers
US5258227A (en) * 1987-12-03 1993-11-02 Ppg Industries, Inc. Chemically treated glass fibers with improved reinforcement properties
NL1003581C2 (en) * 1996-07-12 1998-01-15 Dsm Nv Deformable and thermosettable composition and process for the preparation thereof under the influence of temperature and pressure.
CN114523597B (en) * 2022-01-26 2023-02-03 苏州金纬片板膜智能装备有限公司 Intelligent single preimpregnation apparatus for producing

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4244844A (en) 1977-01-19 1981-01-13 Saint-Gobain Industries Aqueous size for glass fibers
US4246145A (en) 1977-01-19 1981-01-20 Saint-Gobain Industries Aqueous size for glass fibers
US5633075A (en) * 1988-01-12 1997-05-27 Raychem Limited Composite material
US5645906A (en) * 1988-01-12 1997-07-08 Raychem Limited Radially-recoverable sleeve of composite
US11001525B2 (en) 2016-06-17 2021-05-11 Owens Corning Intellectual Capital, Llc Sizing composition for wet use chopped strand glass fibers

Also Published As

Publication number Publication date
BR7205024D0 (en) 1973-08-21
FR2148505A1 (en) 1973-03-23
CA993283A (en) 1976-07-20
JPS5433320B1 (en) 1979-10-19
BE787378A (en) 1973-02-09
NL7209753A (en) 1973-02-13
DE2237902A1 (en) 1973-02-15
IT964631B (en) 1974-01-31

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee