GB1314578A - Process for the preparation of acrylonitrile - Google Patents
Process for the preparation of acrylonitrileInfo
- Publication number
- GB1314578A GB1314578A GB3763970A GB3763970A GB1314578A GB 1314578 A GB1314578 A GB 1314578A GB 3763970 A GB3763970 A GB 3763970A GB 3763970 A GB3763970 A GB 3763970A GB 1314578 A GB1314578 A GB 1314578A
- Authority
- GB
- United Kingdom
- Prior art keywords
- antimony
- bismuth
- molybdenum
- catalyst
- atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 6
- 229910052787 antimony Inorganic materials 0.000 abstract 6
- 229910052797 bismuth Inorganic materials 0.000 abstract 6
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 6
- 229910052750 molybdenum Inorganic materials 0.000 abstract 6
- 239000011733 molybdenum Substances 0.000 abstract 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- 230000000052 comparative effect Effects 0.000 abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 abstract 1
- 229940010552 ammonium molybdate Drugs 0.000 abstract 1
- 235000018660 ammonium molybdate Nutrition 0.000 abstract 1
- 239000011609 ammonium molybdate Substances 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 abstract 1
- 229910000416 bismuth oxide Inorganic materials 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000012876 carrier material Substances 0.000 abstract 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000008119 colloidal silica Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000006104 solid solution Substances 0.000 abstract 1
- 229910052714 tellurium Inorganic materials 0.000 abstract 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1314578 Olefin ammoxidation catalysts UBE INDUSTRIES Ltd 4 Aug 1970 [5 Aug 1969] 37639/70 Heading B1E [Also in Division C2] A catalyst for use in the conversion of propylene to acrylonitrile comprises a compound (for example a heteropoly salt) of molybdenum, bismuth, antimony and oxygen and/or a mixture (for example a solid solution) of oxides of molybdenum, bismuth and antimony, the catalysyt containing, per 100 atoms of total molybdenum, bismuth and antimony, from 5 to 40 atoms of molybdenum, from 35 to 65 atoms of bismuth and from 5 to 60 atoms of antimony, with the proviso that the catalyst is not a catalyst which contains relative atom percentage proportions of molybdenum (α), bismuth (#) and antimony (y) represented by any point which lies on, or within the area defined by, the lines connecting point A (α:#:y=25:50:25), point B(α:#:y=40:55:5) and point C (α:#:y=40:50:10) in Figure 1. The catalyst may be supported on carrier material, for example selected from silica, alumina, silica-alumina and silicates (none specified) and/or additionally may comprise at least one element selected from phosphorus, arsenic, boron, sulphur, tellurium, vanadium, tin, cerium and lenthenum in combined, for example oxidic, form. Examples relate to the preparation of unsupported catalysts (Examples 1 to 24, 27 and 28 and Comparative Examples 1 to 10) and silica-supported catalysts (Examples 25 and 26 and Comparative Examples 11 to 15) by generally conventional methods from molybdenum trioxide or ammonium molybdate, bismuth oxide or bismuth nitrate, antimony trioxide (provided for example by hydrolysis of antimony trichloride) and colloidal silica, the catalysts of the Comparative Examples containing molybdenum, bismuth and antimony in relative proportions which do not satisfy the aforementioned requirement. Disclaiming reference is made to Specifications 1222946 and 1233491.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6143369 | 1969-08-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1314578A true GB1314578A (en) | 1973-04-26 |
Family
ID=13170915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3763970A Expired GB1314578A (en) | 1969-08-05 | 1970-08-04 | Process for the preparation of acrylonitrile |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE2039011C3 (en) |
| FR (1) | FR2056617A5 (en) |
| GB (1) | GB1314578A (en) |
| NL (1) | NL7011532A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0032618B1 (en) * | 1979-12-17 | 1983-06-15 | Monsanto Company | Oxidation and ammoxidation catalysts and their uses |
-
1970
- 1970-08-04 GB GB3763970A patent/GB1314578A/en not_active Expired
- 1970-08-04 NL NL7011532A patent/NL7011532A/xx unknown
- 1970-08-05 DE DE2039011A patent/DE2039011C3/en not_active Expired
- 1970-08-05 FR FR7028889A patent/FR2056617A5/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0032618B1 (en) * | 1979-12-17 | 1983-06-15 | Monsanto Company | Oxidation and ammoxidation catalysts and their uses |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2039011B2 (en) | 1974-07-11 |
| DE2039011C3 (en) | 1975-03-13 |
| NL7011532A (en) | 1971-02-09 |
| DE2039011A1 (en) | 1971-03-04 |
| FR2056617A5 (en) | 1971-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3766092A (en) | Catalyst for preparation of unsaturated nitriles | |
| US3956181A (en) | Oxidation catalyst | |
| US6458742B1 (en) | Catalyst for the manufacture of acrylonitrile | |
| US3988359A (en) | Catalyst for use in and process for preparing acrylonitrile | |
| GB1495303A (en) | Process for producing antimony-containing catalysts | |
| CA1189844A (en) | Process for improving activity of tellurium containing metal oxide catalysts | |
| US4767878A (en) | Process for the manufacture of acrylonitrile and methacrylonitrile | |
| GB1390525A (en) | Process for preparing unsaturated carboxylic acids from corres ponding unsaturated aldehydes | |
| GB1174777A (en) | Process for Oxidising Olefins to Aldehydes | |
| GB1330074A (en) | Process for the manufature of acrylonitrile and methacrylo nitrile | |
| US3551470A (en) | Process for the ammoxidation of olefins to unsaturated nitriles | |
| ES263690A1 (en) | Process for the manufacture of unsaturated nitriles | |
| US3280166A (en) | Process for the oxidation of olefin-ammonia mixtures to unsaturated nitriles | |
| CA1135243A (en) | Oxidation and ammoxidation catalysts | |
| US3135807A (en) | Manufacture of methyl t-butyl ether | |
| GB1412059A (en) | Process for production of acrylic acid | |
| US4174354A (en) | Oxidative dehydrogenation using chromium-containing catalysts | |
| JPS57134454A (en) | Preparation of unsaturated aliphatic dinitrile | |
| EP0358411A1 (en) | Ammoxidation of paraffins and catalyst therefor | |
| US4036901A (en) | Process for producing styrene | |
| GB1314578A (en) | Process for the preparation of acrylonitrile | |
| US4009194A (en) | Catalytic ammoxidation of olefins to nitriles | |
| US3959384A (en) | Oxidation catalyst and process for oxidation of olefins to unsaturated aldehydes | |
| GB1267221A (en) | ||
| CA1202948A (en) | Catalysts for the oxidation and ammoxidation of alcohols |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |