GB1301477A - - Google Patents
Info
- Publication number
- GB1301477A GB1301477A GB4677969A GB1301477DA GB1301477A GB 1301477 A GB1301477 A GB 1301477A GB 4677969 A GB4677969 A GB 4677969A GB 1301477D A GB1301477D A GB 1301477DA GB 1301477 A GB1301477 A GB 1301477A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- sulphur
- nickel
- catalyst
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 4
- 239000005864 Sulphur Substances 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- 229910052759 nickel Inorganic materials 0.000 abstract 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 238000004227 thermal cracking Methods 0.000 abstract 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 abstract 1
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 abstract 1
- -1 C5E Hydrocarbon Chemical class 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000004113 Sepiolite Substances 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- ZQRGREQWCRSUCI-UHFFFAOYSA-N [S].C=1C=CSC=1 Chemical compound [S].C=1C=CSC=1 ZQRGREQWCRSUCI-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000004523 catalytic cracking Methods 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000011551 heat transfer agent Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 150000005673 monoalkenes Chemical class 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 239000004576 sand Substances 0.000 abstract 1
- 229910052624 sepiolite Inorganic materials 0.000 abstract 1
- 235000019355 sepiolite Nutrition 0.000 abstract 1
- 239000000741 silica gel Substances 0.000 abstract 1
- 229910002027 silica gel Inorganic materials 0.000 abstract 1
- 229930192474 thiophene Natural products 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
- C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
- C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
1301477 Hydrogenation of unsaturated gasolines BRITISH PETROLEUM CO Ltd 4 Sept 1970 [23 Sept 1969] 46779/69 Heading C5E Hydrocarbon fractions boiling in the range 15-225 C. and containing aromatics, monoolefins, 4-35 wt. per cent of di-olefins and 0À01-1À5 wt. per cent of sulphur of which 10-300 p.p.m. by weight is mercaptan sulphur are passed, together with 200-5,000 SCF/B of hydrogen, over a supported nickel catalyst of which a major proportion of the nickel is present as the metal at a temperature of 50- 250 C., a pressure of 200-3000 p.s.i.g. and a space velocity of 0À2-10 v./v./hr. to produce a product having a reduced di-olefin content (excluding dicyclopentadiene) of below 0À5 wt. per cent and a reduced mercaptan sulphur content of below 30 p.p.m. Suitable feeds are gasolines produced from naphtha by catalytic or thermal cracking at below 593 C. or by thermal cracking at 593-900 C. using diluent steam and/or an inert heat transfer agent such as sand. The feed can contain 2,4-dimethyl-6- tert-butyl phenol as an inhibitor and normally contains 0À3-1À0% of thiophene sulphur. The catalyst contains 1-50 wt. per cent of nickel and is supported on a refractory compound of a metal of Group II, III or IV, e.g. chalk, alumina, sepiolite which can contain 0À1-5 wt. per cent of alkali or alkaline earth metal, silica gel or kieselguhr. The catalyst suitably has a sulphur to nickel atomic ratio between 0À01 and 0À4 when in use and can be presulphided before use, e.g. with a thiophene, thiacycloalkane or a dialkyl mono sulphide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4677969 | 1969-09-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1301477A true GB1301477A (en) | 1972-12-29 |
Family
ID=10442563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4677969A Expired GB1301477A (en) | 1969-09-23 | 1969-09-23 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3691066A (en) |
| JP (1) | JPS5028083B1 (en) |
| BE (1) | BE756546A (en) |
| CA (1) | CA938574A (en) |
| CS (1) | CS182762B2 (en) |
| DE (1) | DE2046170A1 (en) |
| DK (1) | DK137281B (en) |
| FR (1) | FR2062962B1 (en) |
| GB (1) | GB1301477A (en) |
| NL (1) | NL7013914A (en) |
| NO (1) | NO127975B (en) |
| SE (1) | SE372034B (en) |
| ZA (1) | ZA706112B (en) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4152250A (en) * | 1975-12-09 | 1979-05-01 | Chiyoda Chemical Engineering & Construction | Demetallation of hydrocarbons with catalysts supported on sepiolite |
| US4131537A (en) * | 1977-10-04 | 1978-12-26 | Exxon Research & Engineering Co. | Naphtha hydrofining process |
| US4113603A (en) * | 1977-10-19 | 1978-09-12 | The Lummus Company | Two-stage hydrotreating of pyrolysis gasoline to remove mercaptan sulfur and dienes |
| DE3038118A1 (en) * | 1980-10-09 | 1982-05-13 | EC Erdölchemie GmbH, 5000 Köln | HIGH OCTANE VEHICLE CUTS, METHOD FOR THEIR PRODUCTION AND THEIR USE |
| US5211839A (en) * | 1989-07-26 | 1993-05-18 | Texaco Inc. | Controlling hydrogen partial pressure to yield 650 ° F.- boiling range material in an ebullated bed process |
| SA95160068B1 (en) * | 1994-12-13 | 2006-05-28 | كيميكال ريسيرتش اند ليسنسنج كومباني | PROCESS TO REMOVE MERCAPTANS AND HYDROGEN SULFIDE FROM HYDROCARBON STREAMS |
| US5807477A (en) * | 1996-09-23 | 1998-09-15 | Catalytic Distillation Technologies | Process for the treatment of light naphtha hydrocarbon streams |
| DE69812225T2 (en) * | 1997-06-09 | 2003-12-04 | Institut Francais Du Petrole, Rueil Malmaison | Process for the treatment of diolefins, styrene compounds and gasoline cuts optionally containing mercaptans |
| FR2764210B1 (en) | 1997-06-09 | 1999-07-16 | Inst Francais Du Petrole | SELECTIVE HYDROGENATION CATALYST FOR USE IN THE TREATMENT OF ESSENCE CUTTINGS CONTAINING DIOLEFINS AND STYRENIC COMPOUNDS |
| FR2764299B1 (en) * | 1997-06-09 | 1999-07-16 | Inst Francais Du Petrole | PROCESS FOR TREATING ESSENCE CUTTINGS CONTAINING DIOLEFINS, STYRENIC COMPOUNDS AND MERCAPTANS |
| FR2797639B1 (en) | 1999-08-19 | 2001-09-21 | Inst Francais Du Petrole | PROCESS FOR PRODUCING LOW SULFUR ESSENCE |
| FR2807061B1 (en) * | 2000-03-29 | 2002-05-31 | Inst Francais Du Petrole | PROCESS FOR FUEL DESULFURIZATION COMPRISING DESULFURIZATION OF HEAVY AND INTERMEDIATE FRACTIONS FROM A FRACTIONATION IN AT LEAST THREE CUT |
| US20020175108A1 (en) * | 2001-03-12 | 2002-11-28 | Institut Francais Du Petrole | Process for the production of a desulfurized gasoline from a gasoline fraction that contains conversion gasoline |
| US6824676B1 (en) * | 2002-03-08 | 2004-11-30 | Catalytic Distillation Technologies | Process for the selective desulfurization of a mid range gasoline cut |
| US6984312B2 (en) * | 2002-11-22 | 2006-01-10 | Catalytic Distillation Technologies | Process for the desulfurization of light FCC naphtha |
| US7078577B2 (en) * | 2003-08-11 | 2006-07-18 | Equistar Chemicals, Lp | DihydroDicyclopentadiene production |
| RU2010115346A (en) * | 2007-09-18 | 2011-10-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | METHOD FOR DEEP DESULFURIZATION OF HEAVY Pyrolysis GASOLINE |
| RU2543717C2 (en) | 2009-06-11 | 2015-03-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Method for selective hydration and hydrodesulphurisation of pyrolysis gasoline as source material |
| CN102911714B (en) * | 2011-08-01 | 2014-06-25 | 中国石油化工股份有限公司 | Selective hydrogenation method for C5 fraction of ethylene cracking by-product |
| US20150231611A1 (en) * | 2014-02-19 | 2015-08-20 | Uop Llc | Methods and apparatuses for regenerating catalysts for hydrocarbon production |
| PH12017501355B1 (en) | 2015-01-29 | 2023-05-24 | Lummus Technology Inc | Producing c5 olefins from steam cracker c5 feeds |
| AU2020314880B2 (en) * | 2019-07-15 | 2023-03-09 | Sabic Global Technologies B.V. | System and method for producing un-hydrogenated and hydrogenated C9+ compounds |
| WO2024165222A1 (en) | 2023-02-08 | 2024-08-15 | Topsoe A/S | Low temperature stabilization of liquid oils |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB942493A (en) * | 1961-05-10 | 1963-11-20 | British Petroleum Co | Improvements relating to the hydrogenation of petroleum hydrocarbons |
| NL284526A (en) * | 1961-10-20 |
-
0
- BE BE756546D patent/BE756546A/en unknown
-
1969
- 1969-09-23 GB GB4677969A patent/GB1301477A/en not_active Expired
-
1970
- 1970-09-08 ZA ZA706112A patent/ZA706112B/en unknown
- 1970-09-09 CA CA092629A patent/CA938574A/en not_active Expired
- 1970-09-10 US US71197A patent/US3691066A/en not_active Expired - Lifetime
- 1970-09-18 DE DE19702046170 patent/DE2046170A1/en active Pending
- 1970-09-21 NL NL7013914A patent/NL7013914A/xx not_active Application Discontinuation
- 1970-09-21 JP JP45082872A patent/JPS5028083B1/ja active Pending
- 1970-09-22 FR FR707034265A patent/FR2062962B1/fr not_active Expired
- 1970-09-22 SE SE7012853A patent/SE372034B/xx unknown
- 1970-09-22 CS CS7000006442A patent/CS182762B2/en unknown
- 1970-09-22 NO NO03595/70A patent/NO127975B/no unknown
- 1970-09-23 DK DK486670AA patent/DK137281B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA938574A (en) | 1973-12-18 |
| CS182762B2 (en) | 1978-05-31 |
| SE372034B (en) | 1974-12-09 |
| JPS5028083B1 (en) | 1975-09-12 |
| BE756546A (en) | 1971-03-23 |
| US3691066A (en) | 1972-09-12 |
| ZA706112B (en) | 1971-05-27 |
| FR2062962B1 (en) | 1973-07-13 |
| NL7013914A (en) | 1971-03-25 |
| DE2046170A1 (en) | 1971-03-25 |
| DK137281C (en) | 1978-07-10 |
| DK137281B (en) | 1978-02-13 |
| NO127975B (en) | 1973-09-10 |
| FR2062962A1 (en) | 1971-07-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |