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GB1298331A - Improved hydroformylation process - Google Patents

Improved hydroformylation process

Info

Publication number
GB1298331A
GB1298331A GB2096269A GB2096269A GB1298331A GB 1298331 A GB1298331 A GB 1298331A GB 2096269 A GB2096269 A GB 2096269A GB 2096269 A GB2096269 A GB 2096269A GB 1298331 A GB1298331 A GB 1298331A
Authority
GB
United Kingdom
Prior art keywords
catalyst
stibine
arsine
reaction
rhx
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2096269A
Inventor
Geoffrey Wilkinson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Priority to DE19691939322 priority Critical patent/DE1939322B2/en
Priority to JP6137069A priority patent/JPS5317572B1/ja
Priority to NL6911827A priority patent/NL6911827A/xx
Publication of GB1298331A publication Critical patent/GB1298331A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1298331 Oxo process JOHNSON MATTHEY & CO Ltd 3 Nov 1969 [2 Aug 1968 24 April 1969 (2)] 37017/68 20961/69 and 20962/69 Headings C2C and C2P In a process for the hydroformylation of an olefinically-unsaturated compound with a mixture of hydrogen and carbon monoxide there is used as catalyst a hydrido carbonyl bis- (tri - substituted phosphine, arsine or stibine) rhodium (I) or a hydrido carbonyl tris-(trisubstituted phosphine, arsine or stibine) rhodium (I) and the reaction is carried out in a liquid medium in which there is used as solvent an aldehyde (or alcohol corresponding thereto) present in the products of the reaction. Preferably the reaction is carried out with an excess of free trisubstituted phosphine, arsine or stibine. The catalyst may be prepared in situ from a compound of type RhX(CO)(MR 3 ) 3 or RhX(CO)(MR 3 ) 2 where X is halogen or pseudohalogen and M is P, As or Sb. The catalyst may be complexed with an alkanol. A large number of comparative examples using benzene as solvent but with the above catalysts are given. Starting materials include mono- and diolefins, and may be substituted by ether, alcohol, phenol, carboxylic ester or cyano groups or aromatic rings and include cycloolefins. RhH(CO)(PPh 3 ) 3 is isolated from a residual catalyst solution containing excess PPh 3 . Reference has been directed by the Comptroller to Specifications 1,138,601, 1,173,568 and 1,197,847.
GB2096269A 1968-08-02 1968-08-02 Improved hydroformylation process Expired GB1298331A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE19691939322 DE1939322B2 (en) 1968-08-02 1969-08-01 Process for the hydroformylation of olefinically unsaturated compounds
JP6137069A JPS5317572B1 (en) 1968-08-02 1969-08-02
NL6911827A NL6911827A (en) 1968-08-02 1969-08-04

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3701768 1968-08-02

Publications (1)

Publication Number Publication Date
GB1298331A true GB1298331A (en) 1972-11-29

Family

ID=10393055

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2096269A Expired GB1298331A (en) 1968-08-02 1968-08-02 Improved hydroformylation process

Country Status (1)

Country Link
GB (1) GB1298331A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4151209A (en) * 1976-05-13 1979-04-24 Celanese Corporation Reduction of catalyst deactivation in processes for hydroformylation of olefins with rhodium complex catalysts
EP0018161A1 (en) * 1979-04-11 1980-10-29 DAVY McKEE (LONDON) LIMITED Aldehyde-ethers and process for their production
DE3034354A1 (en) * 1979-02-12 1981-02-12 Exxon Research Engineering Co PROCESS FOR THE PREPARATION OF ALDEHYDES
US4260828A (en) * 1980-04-16 1981-04-07 Union Carbide Corporation Hydroformylation process
US4287369A (en) * 1979-03-21 1981-09-01 Davy Mckee (Oil & Chemicals) Limited Hydroformylation of alkenes to aldehydes
US4288634A (en) * 1978-04-10 1981-09-08 Toa Nenryo Kogyo Kabushiki Kaisha Novel rhodium compounds and process for producing the same
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
EP0290075A2 (en) * 1987-05-08 1988-11-09 Shell Internationale Researchmaatschappij B.V. Novel diaryl phosphides

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4151209A (en) * 1976-05-13 1979-04-24 Celanese Corporation Reduction of catalyst deactivation in processes for hydroformylation of olefins with rhodium complex catalysts
US4288634A (en) * 1978-04-10 1981-09-08 Toa Nenryo Kogyo Kabushiki Kaisha Novel rhodium compounds and process for producing the same
US4397788A (en) * 1978-10-04 1983-08-09 Toa Nenryo Kogyo Kabushiki Kaisha Process for producing rhodium compounds
DE3034354A1 (en) * 1979-02-12 1981-02-12 Exxon Research Engineering Co PROCESS FOR THE PREPARATION OF ALDEHYDES
US4287369A (en) * 1979-03-21 1981-09-01 Davy Mckee (Oil & Chemicals) Limited Hydroformylation of alkenes to aldehydes
EP0018161A1 (en) * 1979-04-11 1980-10-29 DAVY McKEE (LONDON) LIMITED Aldehyde-ethers and process for their production
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
US4260828A (en) * 1980-04-16 1981-04-07 Union Carbide Corporation Hydroformylation process
EP0290075A2 (en) * 1987-05-08 1988-11-09 Shell Internationale Researchmaatschappij B.V. Novel diaryl phosphides
EP0290075A3 (en) * 1987-05-08 1989-02-22 Shell Internationale Researchmaatschappij B.V. Novel diaryl phosphides

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years