GB1296319A - - Google Patents
Info
- Publication number
- GB1296319A GB1296319A GB1296319DA GB1296319A GB 1296319 A GB1296319 A GB 1296319A GB 1296319D A GB1296319D A GB 1296319DA GB 1296319 A GB1296319 A GB 1296319A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen
- dyes
- formula
- amines
- sulphonic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D277/70—Sulfur atoms
- C07D277/76—Sulfur atoms attached to a second hetero atom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/206—Dyes with amino groups substituted by heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/36—Dyes with acylated amino groups
- C09B1/46—Dyes with acylated amino groups the acyl groups being residues of cyanuric acid or an analogous heterocyclic compound
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
- C09B62/343—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a five membered ring
- C09B62/345—Anthracene dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1296319 Anthraquinone dyes BAYER AG 19 April 1971 [28 March 1970] 24843/71 Heading C4P The invention comprises anthraquinine dyes having the formula where R 1 is hydrogen, hydroxyl, halogen er a sulphonic acid group, R 2 is hydrogen or a substituent; R 3 is hydrogen or a sulphonic acid group and R 4 is an optionally substituted alkyl, aralkyl or aryl group. The dyes may be prepared by condensing the required 1-amino-2- sulpho-4-bromoanthraquinone with an amine of formula in the presence of a hydrogen bromide binding agent and copper or a copper compound, at 40-100 C. Alternatively, they may be reacted with amines where R 3 is hydrogen and the produced dyes sulphonated. In a preferred embodiment amines of formula are used and the compounds reacted with a salt of a sulphuric acid of formula R 4 SO 2 H. The dyes are used for dyeing and printing cellulose and nitrogen-containing materials e.g. wool, silk and polyamide fibres, and give greenish blue shades on these materials.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2015157A DE2015157C3 (en) | 1970-03-28 | 1970-03-28 | Anthraquinone dyes, their production and their use |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1296319A true GB1296319A (en) | 1972-11-15 |
Family
ID=5766668
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1296319D Expired GB1296319A (en) | 1970-03-28 | 1971-04-19 |
Country Status (9)
Country | Link |
---|---|
US (1) | US3773779A (en) |
AT (1) | AT300723B (en) |
BE (1) | BE764908A (en) |
CA (1) | CA938288A (en) |
CH (1) | CH602864A5 (en) |
DE (1) | DE2015157C3 (en) |
FR (1) | FR2083654B1 (en) |
GB (1) | GB1296319A (en) |
NL (1) | NL7103744A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3974170A (en) * | 1974-08-26 | 1976-08-10 | Monsanto Company | Preparation of 2-mercaptoazoles |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1318843A (en) * | 1961-02-27 | 1963-02-22 | Bayer Ag | Novel coloring matters, and methods of making and using them |
FR81904E (en) * | 1962-03-09 | 1963-11-29 | Bayer Ag | Novel coloring matters, and methods of making and using them |
BE630929A (en) * | 1963-04-11 |
-
1970
- 1970-03-28 DE DE2015157A patent/DE2015157C3/en not_active Expired
-
1971
- 1971-02-24 CH CH914474A patent/CH602864A5/xx not_active IP Right Cessation
- 1971-03-01 CA CA106489A patent/CA938288A/en not_active Expired
- 1971-03-19 NL NL7103744A patent/NL7103744A/xx unknown
- 1971-03-22 US US00126976A patent/US3773779A/en not_active Expired - Lifetime
- 1971-03-24 AT AT253671A patent/AT300723B/en not_active IP Right Cessation
- 1971-03-26 BE BE764908A patent/BE764908A/en unknown
- 1971-03-29 FR FR7111001A patent/FR2083654B1/fr not_active Expired
- 1971-04-19 GB GB1296319D patent/GB1296319A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE2015157B2 (en) | 1978-02-16 |
DE2015157C3 (en) | 1978-10-12 |
BE764908A (en) | 1971-08-16 |
NL7103744A (en) | 1971-09-30 |
CA938288A (en) | 1973-12-11 |
AT300723B (en) | 1972-08-10 |
CH602864A5 (en) | 1978-08-15 |
DE2015157A1 (en) | 1971-10-21 |
FR2083654A1 (en) | 1971-12-17 |
US3773779A (en) | 1973-11-20 |
FR2083654B1 (en) | 1975-03-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |