GB1287050A - pi-ALLYLIC PALLADIUM COMPLEXES - Google Patents
pi-ALLYLIC PALLADIUM COMPLEXESInfo
- Publication number
- GB1287050A GB1287050A GB4418370A GB4418370A GB1287050A GB 1287050 A GB1287050 A GB 1287050A GB 4418370 A GB4418370 A GB 4418370A GB 4418370 A GB4418370 A GB 4418370A GB 1287050 A GB1287050 A GB 1287050A
- Authority
- GB
- United Kingdom
- Prior art keywords
- allylic
- palladium complexes
- cns
- methallyl
- palladium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical class [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 239000002685 polymerization catalyst Substances 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- 239000002879 Lewis base Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 125000001518 isoselenocyanato group Chemical group *N=C=[Se] 0.000 abstract 1
- 150000007527 lewis bases Chemical class 0.000 abstract 1
- 125000005394 methallyl group Chemical group 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1287050 #-Allylic paladium polymerization catalysts ESSO RESEARCH & ENG CO 19 April 1971 [16 Sept 1970] 44183/70 Heading C3P [Also in Division C2] A polymerization catalyst comprises one or more #-allylic palladium complexes of formula #-all-PdX where "all" is an allyl group which may contain hydrocarbyl substituents and X is CN, CNO, CNS or CNSe, with the restriction that X is not CNS when "all" is methallyl, optionally in combination with a Lewis base YR 3 or Y(OR) 3 where Y is a Group Vb element excluding nitrogen and R is hydrocarbyl. In Example 14, polymethylmethacrylate is prepared using #-methallyl palladium cyanate as catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4418370A GB1287050A (en) | 1970-09-16 | 1970-09-16 | pi-ALLYLIC PALLADIUM COMPLEXES |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4418370A GB1287050A (en) | 1970-09-16 | 1970-09-16 | pi-ALLYLIC PALLADIUM COMPLEXES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1287050A true GB1287050A (en) | 1972-08-31 |
Family
ID=10432154
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4418370A Expired GB1287050A (en) | 1970-09-16 | 1970-09-16 | pi-ALLYLIC PALLADIUM COMPLEXES |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1287050A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5808121A (en) * | 1993-03-26 | 1998-09-15 | Bp Chemicals Limited | Catalyst compositions and process of making polyketones therewith |
| CN112250715A (en) * | 2020-10-29 | 2021-01-22 | 西安凯立新材料股份有限公司 | Preparation method of chloro (crotyl) (3-tert-butylphosphoryl) palladium (II) |
| CN114437142A (en) * | 2022-02-28 | 2022-05-06 | 北京格林凯默科技有限公司 | Preparation method of crotyl palladium chloride dimer |
-
1970
- 1970-09-16 GB GB4418370A patent/GB1287050A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5808121A (en) * | 1993-03-26 | 1998-09-15 | Bp Chemicals Limited | Catalyst compositions and process of making polyketones therewith |
| CN112250715A (en) * | 2020-10-29 | 2021-01-22 | 西安凯立新材料股份有限公司 | Preparation method of chloro (crotyl) (3-tert-butylphosphoryl) palladium (II) |
| CN114437142A (en) * | 2022-02-28 | 2022-05-06 | 北京格林凯默科技有限公司 | Preparation method of crotyl palladium chloride dimer |
| CN114437142B (en) * | 2022-02-28 | 2024-02-23 | 北京格林凯默科技有限公司 | Preparation method of crotyl palladium chloride dimer |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NL7610267A (en) | CATALYSTS FOR POLYMERIZING (ALPHA) ALKINES. | |
| GB1483821A (en) | Macrocyclic polyamines and complexes with selected metals | |
| ZA71813B (en) | Olefin(co)polymerisation catalysts | |
| NL170212C (en) | BASE BAND TO DI PHASE CONVERTER AND DATA TRANSFER SYSTEM USING THIS BASE BELT TO DI PHASE CONVERTER. | |
| NL152269B (en) | PROCEDURE FOR THE PPOLYMERIZATION OR COPOLYMERIZATION OF ETHENE, ARTICLES CONTAINING WHOLLY OR PARTLY OF A POLYMER OR COPOLYMER SO OBTAINED, AND PROCESS FOR PREPARING A CATALYST MIXTURE OR COPOLYMER MIXED FOR USE FOR USE. | |
| GB1264254A (en) | ||
| SE410793B (en) | RETENTION AND FLOCKING AGENTS, BASED ON HIGH MOLECULAR POLYACRYLAMIDES | |
| GB1287050A (en) | pi-ALLYLIC PALLADIUM COMPLEXES | |
| ES431700A1 (en) | Cyanide free bath for electrodeposition of silver | |
| ES8106915A1 (en) | Olefin polymerization | |
| GB1188378A (en) | Dibenzonaphthacridine-5,11,16-Trione Derivatives and processes for their manufacture and use | |
| GB1424629A (en) | Process for preparing a ruthenium catalyst and product produced thereby | |
| NL162668B (en) | PROCESS FOR PREPARING AN AMORPH, LINEAR, ATACTICALLY INTERACTING COPOLYMER FROM UNITS DERIVED FROM ALKYL ACRYLATE, ETHYLENE AND ANOTHER MONOMER. | |
| ES415100A1 (en) | Catalyst for the polymerization of olefins based upon magnesium and transition metal | |
| GB1410894A (en) | Process for producing synthetic lubricants | |
| IT969763B (en) | NON-WOVEN ARTICLES BASED ON THERMOSTABLE RESIN | |
| OA04887A (en) | Time-switched electronic telephone system. | |
| ES394855A1 (en) | Process for the polymerisation of olefins | |
| JPS52134689A (en) | Process for combining polymer carrier with ligand of high and low molecular weight | |
| GB1192349A (en) | Improvements in or relating to Cationic Polymerisations | |
| ES413535A1 (en) | Certain n-substituted scopolammonium compounds | |
| IT1069872B (en) | TITANIUM COMPLEXES WITH NITROGEN | |
| GB1251854A (en) | ||
| CA924436A (en) | Lactam polymerization with n,n'-dialkyl-azetidinedione initiators | |
| BE798026R (en) | POLYMERS CONTAINING NITROGEN |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |