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GB1284030A - Cutting tool materials - Google Patents

Cutting tool materials

Info

Publication number
GB1284030A
GB1284030A GB08998/70A GB1899870A GB1284030A GB 1284030 A GB1284030 A GB 1284030A GB 08998/70 A GB08998/70 A GB 08998/70A GB 1899870 A GB1899870 A GB 1899870A GB 1284030 A GB1284030 A GB 1284030A
Authority
GB
United Kingdom
Prior art keywords
coated
tic
substrate
top layer
carbide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB08998/70A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUISSE DE RECH S HORLOGERES LA
Centre Suisse dElectronique et Microtechnique SA CSEM
Original Assignee
SUISSE DE RECH S HORLOGERES LA
Laboratoire Suisse de Recherches Horlogeres
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUISSE DE RECH S HORLOGERES LA, Laboratoire Suisse de Recherches Horlogeres filed Critical SUISSE DE RECH S HORLOGERES LA
Publication of GB1284030A publication Critical patent/GB1284030A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/90—Carbides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/90—Carbides
    • C01B32/907—Oxycarbides; Sulfocarbides; Mixture of carbides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
    • C23C16/08—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metal halides
    • C23C16/10—Deposition of chromium only
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
    • C23C16/08—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metal halides
    • C23C16/14—Deposition of only one other metal element
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/32—Carbides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/38—Borides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40—Oxides
    • C23C16/403—Oxides of aluminium, magnesium or beryllium
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/42—Silicides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Chemical Vapour Deposition (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)

Abstract

1284030 Coated cutting tools LABORATOIRE SUISSE DE RECHERCHES HORLOGERES 21 April 1970 [2 June 1969] 18998/70 Heading C7F A bonded material suitable for use as a cutting tool comprises a substrate and at least two coating layers chemically deposited on the substrate, the top layer being a carbide of one of the transition metals of Groups 4 to 6 of the Periodic Table or alumina, and the or each intermediate layer having the following characteristics (a) its hardness is between the hardness of the substrate and that of the top layer, (b) it is more ductile than the top layer (c) its co-efficient of thermal expansion is between those of the substrate and top layer and (d) it is partly diffused in both the lower and upper adjacent substance. Coating is by a halide diffusion process or from gaseous compounds, and the following examples are given (1) ledeburitic chromium steel coated with Cr which is coated with TiC (2) WC, TiC, NbC or VC with a Co binder coated with Cr/Cr carbide which is coated with TiC (3) 80% Ni 20% Cr coated with Ni 3 Al coated with NiAl coated with Al 2 O 3 (4) 20 Cr 15 W 51Co 10 Ni 1À4 Mn 1À7 Fe coated with Cr carbides coated with ZrC (5) Cr-Mo-C steel with 33% TiC coated with Mo coated with MoC coated with B 4 C and (6) Al 2 O 3 + Ni binder coated with Cr coated with TiC.
GB08998/70A 1969-06-02 1970-04-21 Cutting tool materials Expired GB1284030A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH835469A CH542678A (en) 1969-06-02 1969-06-02 Composite material for cutting tools

Publications (1)

Publication Number Publication Date
GB1284030A true GB1284030A (en) 1972-08-02

Family

ID=4339037

Family Applications (1)

Application Number Title Priority Date Filing Date
GB08998/70A Expired GB1284030A (en) 1969-06-02 1970-04-21 Cutting tool materials

Country Status (4)

Country Link
CH (1) CH542678A (en)
DE (1) DE2018662A1 (en)
FR (1) FR2045776B1 (en)
GB (1) GB1284030A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3318999A1 (en) * 1983-05-25 1984-11-29 M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 8000 München COATED METAL OBJECT AND METHOD FOR THE PRODUCTION THEREOF
US4490191A (en) * 1981-12-16 1984-12-25 General Electric Company Coated product and process
US4610931A (en) * 1981-03-27 1986-09-09 Kennametal Inc. Preferentially binder enriched cemented carbide bodies and method of manufacture
US5073411A (en) * 1981-12-16 1991-12-17 Carboloy, Inc. Process for forming a surface oxidized binding layer on hard substrates
USRE34180E (en) * 1981-03-27 1993-02-16 Kennametal Inc. Preferentially binder enriched cemented carbide bodies and method of manufacture
GB2308134A (en) * 1995-12-12 1997-06-18 Kennametal Inc Multi-layered coated cutting tool
GB2308133A (en) * 1995-12-13 1997-06-18 Kennametal Inc Cutting tool with coating of boron carbide or tungsten carbide for machining titanium
GB2323856A (en) * 1997-03-12 1998-10-07 Kennametal Inc Cutting tool for milling titanium and titanium alloys
US7264883B2 (en) 2002-12-27 2007-09-04 Kobe Steel, Ltd. Hard coating film excellent in adhesion and manufacturing method thereof
EP1253124B2 (en) † 2001-04-17 2011-06-15 Tungaloy Corporation Highly adhesive surface-coated cemented carbide and method for producing the same

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE32110E (en) * 1971-05-26 1986-04-15 General Electric Co. Aluminum oxide coated cemented carbide product
DE2265603C2 (en) * 1971-05-26 1983-02-03 General Electric Co., Schenectady, N.Y. Cutting insert with a non-metallic intermediate layer between the base body and the top coating and method for its manufacture
CH540990A (en) * 1971-07-07 1973-08-31 Battelle Memorial Institute Method for increasing the wear resistance of the surface of a cutting tool
SE357984B (en) * 1971-11-12 1973-07-16 Sandvik Ab
DE2317447C2 (en) * 1973-04-06 1984-11-22 Sandvik Ab, Sandviken Cutting inserts
AT336905B (en) * 1975-02-10 1977-06-10 Plansee Metallwerk WEAR PART FOR CHIPPING AND CHANDELESS FORMING
DE2525185C3 (en) * 1975-06-06 1986-04-17 Fried. Krupp Gmbh, 4300 Essen Hard metal body
US4018631A (en) * 1975-06-12 1977-04-19 General Electric Company Coated cemented carbide product
FR2447612A1 (en) * 1979-01-26 1980-08-22 Thomson Csf HETEROJUNCTION SEMICONDUCTOR COMPONENT
CH639598A5 (en) * 1979-05-04 1983-11-30 Sulzer Ag METAL PART PROVIDED WITH A WEAR AND CORROSION-RESISTANT TUNGSTEN CARBIDE PROTECTIVE LAYER.
US4517217A (en) * 1980-09-09 1985-05-14 Westinghouse Electric Corp. Protective coating means for articles such as gold-plated jewelry and wristwatch components
US4594294A (en) * 1983-09-23 1986-06-10 Energy Conversion Devices, Inc. Multilayer coating including disordered, wear resistant boron carbon external coating
DE3515919A1 (en) * 1985-05-03 1986-11-06 Fried. Krupp Gmbh, 4300 Essen WEAR-RESISTANT COATED HARD METAL BODY AND METHOD FOR THE PRODUCTION THEREOF
DE10109523A1 (en) * 2001-02-28 2002-09-05 Ceram Tec Ag Innovative Cerami Component used for processing workpieces has hard material coating comprising intermediate layer between layers
CN112846259B (en) * 2021-01-05 2022-09-30 崇义章源钨业股份有限公司 Cutter for steel turning and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3368914A (en) * 1964-08-05 1968-02-13 Texas Instruments Inc Process for adherently depositing a metal carbide on a metal substrate

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4610931A (en) * 1981-03-27 1986-09-09 Kennametal Inc. Preferentially binder enriched cemented carbide bodies and method of manufacture
USRE34180E (en) * 1981-03-27 1993-02-16 Kennametal Inc. Preferentially binder enriched cemented carbide bodies and method of manufacture
US4490191A (en) * 1981-12-16 1984-12-25 General Electric Company Coated product and process
US5073411A (en) * 1981-12-16 1991-12-17 Carboloy, Inc. Process for forming a surface oxidized binding layer on hard substrates
DE3318999A1 (en) * 1983-05-25 1984-11-29 M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 8000 München COATED METAL OBJECT AND METHOD FOR THE PRODUCTION THEREOF
GB2308134B (en) * 1995-12-12 1999-09-29 Kennametal Inc Coated cutting tool
US5879823A (en) * 1995-12-12 1999-03-09 Kennametal Inc. Coated cutting tool
GB2308134A (en) * 1995-12-12 1997-06-18 Kennametal Inc Multi-layered coated cutting tool
GB2308133A (en) * 1995-12-13 1997-06-18 Kennametal Inc Cutting tool with coating of boron carbide or tungsten carbide for machining titanium
GB2308133B (en) * 1995-12-13 2000-06-21 Kennametal Inc Cutting tool for machining titanium and titanium alloys
GB2323856A (en) * 1997-03-12 1998-10-07 Kennametal Inc Cutting tool for milling titanium and titanium alloys
GB2323856B (en) * 1997-03-12 2002-03-13 Kennametal Inc Cutting insert for milling titanium and titanium alloys
EP1253124B2 (en) † 2001-04-17 2011-06-15 Tungaloy Corporation Highly adhesive surface-coated cemented carbide and method for producing the same
US7264883B2 (en) 2002-12-27 2007-09-04 Kobe Steel, Ltd. Hard coating film excellent in adhesion and manufacturing method thereof

Also Published As

Publication number Publication date
FR2045776B1 (en) 1974-06-14
CH542678A (en) 1973-10-15
DE2018662A1 (en) 1970-12-10
FR2045776A1 (en) 1971-03-05

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Legal Events

Date Code Title Description
414F Notice of opposition given (sect. 14/1949)
414E Application relinquished (sect. 14/1949)
CSNS Application of which complete specification have been accepted and published, but patent is not sealed