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GB1271445A - Polymerization process - Google Patents

Polymerization process

Info

Publication number
GB1271445A
GB1271445A GB4565669A GB4565669A GB1271445A GB 1271445 A GB1271445 A GB 1271445A GB 4565669 A GB4565669 A GB 4565669A GB 4565669 A GB4565669 A GB 4565669A GB 1271445 A GB1271445 A GB 1271445A
Authority
GB
United Kingdom
Prior art keywords
alpha
catalyst
olefin
sept
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4565669A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of GB1271445A publication Critical patent/GB1271445A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1,271,445. Polymerization process. STANDARD OIL CO. 16 Sept., 1969 [17 Sept., 1968], No. 45656/69. Heading C3P. A process for polymerizing C 2-4 alpha-olefins comprises subjecting a reaction mixture comprising (a) an inert liquid hydrocarbon reaction medium, (b) an alpha-olefin monomer feedstock, and (c) a catalyst slurry comprising a suspension in the reaction medium of a supported oxide of a Group Va or Via metal and a compound AlR 3 wherein R is a monovalent hydrocarbon radical, to conditions of temperature and pressure such that polymerization of the alpha olefin takes place; flashing off unreacted alpha olefin monomer; separating the residual mixture into liquid and solid phases; and recovering the dissolved polymerized alpha-olefin from the liquid phase. In the examples ethylene is polymerized in a batch process utilizing chromia dispersed on silica promoted by aluminium triisobutyl as catalyst and cyclohexane as solvent, and an ethylene-propylene copolymer is prepared by a continuous process utilizing the same catalyst and solvent.
GB4565669A 1968-09-17 1969-09-16 Polymerization process Expired GB1271445A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US76033268A 1968-09-17 1968-09-17

Publications (1)

Publication Number Publication Date
GB1271445A true GB1271445A (en) 1972-04-19

Family

ID=25058781

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4565669A Expired GB1271445A (en) 1968-09-17 1969-09-16 Polymerization process

Country Status (5)

Country Link
BE (1) BE739002A (en)
DE (1) DE1946888A1 (en)
FR (1) FR2018261A1 (en)
GB (1) GB1271445A (en)
NL (1) NL6914079A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006001936A1 (en) 2004-06-14 2006-01-05 Exxonmobil Chemical Patents Inc. Supported chromium polymerization catalyst and process using the same
US7192901B2 (en) 2004-10-27 2007-03-20 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US7381778B2 (en) 2002-06-06 2008-06-03 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US7632901B2 (en) 2002-06-06 2009-12-15 Exxonmobil Chemical Patents Inc. Catalyst system and process

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7223823B2 (en) 2002-06-06 2007-05-29 Exxon Mobil Chemical Patents Inc. Catalyst system and process
US7381778B2 (en) 2002-06-06 2008-06-03 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US7632901B2 (en) 2002-06-06 2009-12-15 Exxonmobil Chemical Patents Inc. Catalyst system and process
WO2006001936A1 (en) 2004-06-14 2006-01-05 Exxonmobil Chemical Patents Inc. Supported chromium polymerization catalyst and process using the same
US7192901B2 (en) 2004-10-27 2007-03-20 Exxonmobil Chemical Patents Inc. Method of preparing a treated support

Also Published As

Publication number Publication date
DE1946888A1 (en) 1970-03-26
BE739002A (en) 1970-03-02
NL6914079A (en) 1970-03-19
FR2018261A1 (en) 1970-05-29

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