GB1271191A - Ammoxidation process for the production of acrylonitrile or methacrylonitrile - Google Patents
Ammoxidation process for the production of acrylonitrile or methacrylonitrileInfo
- Publication number
- GB1271191A GB1271191A GB33019/70A GB3301970A GB1271191A GB 1271191 A GB1271191 A GB 1271191A GB 33019/70 A GB33019/70 A GB 33019/70A GB 3301970 A GB3301970 A GB 3301970A GB 1271191 A GB1271191 A GB 1271191A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bismuth
- oxides
- moo
- molybdate
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 229910052797 bismuth Inorganic materials 0.000 abstract 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000012876 carrier material Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 235000009120 camo Nutrition 0.000 abstract 1
- 244000213578 camo Species 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract 1
- CJJMLLCUQDSZIZ-UHFFFAOYSA-N oxobismuth Chemical class [Bi]=O CJJMLLCUQDSZIZ-UHFFFAOYSA-N 0.000 abstract 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1,271,191. Olefin ammoxidation catalysts. UBE INDUSTRIES Ltd. 7 July, 1970 [11 July, 1969; 23 Dec., 1969; 5 June, 1970], No. 33019/70. Heading B1E. [Also in Division C2] An olefin ammoxidation catalyst consists of (a) from 10 to 95 parts by weight of a bismuth antimonate having an Sb:Bi atomic ratio of 1:1 and, correspondingly (b) from 90 to 5 parts by weight of a molybdate of tin, lead, manganese or of a metal of Group IB, for example copper or silver, or Group IIA, for example magnesium, calcium or barium, or Group IIB, for example zinc, cadmium or mercury, or Group VIII, for example iron, cobalt or nickel, up to 10 weight per cent of the bismuth antimonate (a) optionally consisting of material selected from other bismuth antimonates, for example Bi(SbO 3 ) 3 and (BiO) 3 SbO 4 , antimony oxides and bismuth oxides and up to (but not including) 20 weight per cent of the molybdate (b) optionally consisting of material selected from other molybdates, molybdenum oxides and oxides of the aforementioned metals. The molybdate (b) preferably has the formula M(MoO 4 ) m/2 or M(Mo 2 O 10 )m/a wherein M is an aforementioned metal having valency m; exemplified molybdates are Ag 2 MoO 4 , CaMoO 4 , CaMo 3 O 10 , BaMoO 4 , BaMo 3 O 10 , ZnMoO 4 , CdMoO 4 , PbMoO 4 , MnMoO 4 , Fe 2 (MoO 4 ) 3 , Fe 2 (Mo 3 0 10 ) 3 and CoMo 2 O 10 . The catalyst may be in the form of a composition comprising solid carrier material which may constitute from 10 to 90 weight per cent of the composition; exemplified carrier materials are silica, alumina, silica-alumina, silicates (none specified) and silicon carbide. The catalyst or composition may have a surface area of from 1 to 3m<SP>2</SP>/g.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5456469 | 1969-07-11 | ||
| JP44103002A JPS4810776B1 (en) | 1969-12-23 | 1969-12-23 | |
| JP45047933A JPS4928494B1 (en) | 1970-06-05 | 1970-06-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1271191A true GB1271191A (en) | 1972-04-19 |
Family
ID=27293133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB33019/70A Expired GB1271191A (en) | 1969-07-11 | 1970-07-07 | Ammoxidation process for the production of acrylonitrile or methacrylonitrile |
Country Status (6)
| Country | Link |
|---|---|
| DE (1) | DE2034396C3 (en) |
| FR (1) | FR2051702B1 (en) |
| GB (1) | GB1271191A (en) |
| NL (1) | NL146796B (en) |
| SE (1) | SE372763B (en) |
| SU (1) | SU400084A3 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111203251A (en) * | 2020-02-26 | 2020-05-29 | 递铂国际贸易(大连)有限公司 | Wear-resistant mixed metal oxide catalyst for synthesizing unsaturated nitrile by ammoxidation of low-carbon hydrocarbon and preparation method thereof |
-
1970
- 1970-07-07 SU SU1453999A patent/SU400084A3/ru active
- 1970-07-07 GB GB33019/70A patent/GB1271191A/en not_active Expired
- 1970-07-09 SE SE7009543A patent/SE372763B/xx unknown
- 1970-07-10 FR FR707025806A patent/FR2051702B1/fr not_active Expired
- 1970-07-10 NL NL707010270A patent/NL146796B/en not_active IP Right Cessation
- 1970-07-10 DE DE2034396A patent/DE2034396C3/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111203251A (en) * | 2020-02-26 | 2020-05-29 | 递铂国际贸易(大连)有限公司 | Wear-resistant mixed metal oxide catalyst for synthesizing unsaturated nitrile by ammoxidation of low-carbon hydrocarbon and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2034396C3 (en) | 1974-10-03 |
| FR2051702A1 (en) | 1971-04-09 |
| DE2034396B2 (en) | 1974-02-28 |
| FR2051702B1 (en) | 1973-04-27 |
| DE2034396A1 (en) | 1971-02-11 |
| NL7010270A (en) | 1971-01-13 |
| SE372763B (en) | 1975-01-13 |
| NL146796B (en) | 1975-08-15 |
| SU400084A3 (en) | 1973-10-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0223877B1 (en) | Process for the production of methacrolein and methacrylic acid | |
| US3642930A (en) | Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor | |
| GB1374460A (en) | Catalyst composition | |
| DE69216390D1 (en) | Catalyst and process for the oxidation or ammoxidation of olefins | |
| GB1390525A (en) | Process for preparing unsaturated carboxylic acids from corres ponding unsaturated aldehydes | |
| GB1249290A (en) | Catalyst and process for oxidising olefins | |
| GB1518447A (en) | Catalyst and process for the preparation of unsaturated carboxylic acids | |
| SE464798B (en) | CATALYST CONTAINING A SUBSTRATE, AN INTERMEDIATE OXID LAYER AND A CATALYTIC LAYER | |
| JP2006507937A (en) | Mixed oxide catalyst of Rb, Ce, Cr, Ni, Fe, Bi and Mo used for acrylonitrile production | |
| EP0476579A1 (en) | Iron antimony-containing metal oxide catalyst composition and process for producing the same | |
| ATE22401T1 (en) | PROCESS FOR REGENERATION OF IRON ANTIMONY METAL OXIDE CATALYSTS. | |
| DE3365703D1 (en) | Process for regeneration of iron-antimony metallic oxide catalysts | |
| GB1412059A (en) | Process for production of acrylic acid | |
| US4292203A (en) | Oxidation catalysts | |
| GB1447098A (en) | Superior catalyst prepared by impregnation of preformed matrix and processes using said catalyst | |
| US3200081A (en) | Mixed antimony oxide-manganese oxide oxidation catalyst | |
| GB1271191A (en) | Ammoxidation process for the production of acrylonitrile or methacrylonitrile | |
| GB1467865A (en) | Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles | |
| US3907859A (en) | Coproduction of acrylonitrile and acrylic acid | |
| GB2105605A (en) | Process for producing an antimony containing metal oxide catalyst | |
| EP0350862B1 (en) | Process for producing methacrylic acid | |
| AU729717B2 (en) | Process for production of prussic acid | |
| GB1247594A (en) | Production of pyridine | |
| CA1117930A (en) | Synthesis of maleic anhydride | |
| GB1456752A (en) | Catalyst and process for the production of unsaturated carbonyl compounds |