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GB1212165A - Stable copolymer dispersions - Google Patents

Stable copolymer dispersions

Info

Publication number
GB1212165A
GB1212165A GB5957/69A GB595769A GB1212165A GB 1212165 A GB1212165 A GB 1212165A GB 5957/69 A GB5957/69 A GB 5957/69A GB 595769 A GB595769 A GB 595769A GB 1212165 A GB1212165 A GB 1212165A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
parts
alkyl group
monomers
vinyl ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5957/69A
Inventor
Arthur Carl Frechtling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1212165A publication Critical patent/GB1212165A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1807—C7-(meth)acrylate, e.g. heptyl (meth)acrylate or benzyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/14—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates
    • C08F222/145—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates the ester chains containing seven or more carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1,212,165. Non-aqueous polymer dispersions. UNION CARBIDE CORP. 4 Feb., 1969 [7 Feb., 1968], No. 5957/69. Heading C3P. A non-aqueous dispersion of a vinyl ester copolymer is obtained by heating a mixture of: (a) 100 parts by weight of one or more vinyl ester monomers having from 3 to 5 carbon atoms; (b) from 1 to 120 parts by weight of a dispersing, olefinically unsaturated comonomer selected from alkyl acrylates having 6 to 18 carbon atoms in the alkyl group, dialkyl fumarates having 6 to 18 carbon atoms in each alkyl group, and dialkyl itaconates having 6 to 18 carbon atoms in each alkyl group; (c) from 37 to 900 parts by weight per 100 parts of monomers (a) plus (b) of an organic diluent selected from aliphatic hydrocarbons containing from 4 to 12 carbon atoms and alicyclic hydrocarbons containing from 5 to 8 carbon atoms; and (d) from 0À01 to 1.0 parts by weight per. 100 parts of monomers (a) plus (b) of free radical polymerization initiator at a temperature of from 0‹ to 150‹ C. for at least 2 hours and recovering normally solid vinyl ester copolymer having a particle size of from 0À50 to 50 microns as a non-aqueous dispersion in an organic diluent. The products can be alcoholysed and are used to cast films or as adhesives.
GB5957/69A 1968-02-07 1969-02-04 Stable copolymer dispersions Expired GB1212165A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US70357068A 1968-02-07 1968-02-07

Publications (1)

Publication Number Publication Date
GB1212165A true GB1212165A (en) 1970-11-11

Family

ID=24825908

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5957/69A Expired GB1212165A (en) 1968-02-07 1969-02-04 Stable copolymer dispersions

Country Status (3)

Country Link
DE (1) DE1905093A1 (en)
FR (1) FR2001486B1 (en)
GB (1) GB1212165A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8993668B2 (en) 2007-07-19 2015-03-31 Celanese Emulsions Gmbh Polyvinyl ester dispersions, process for preparation thereof and use thereof
US9175185B2 (en) 2007-07-19 2015-11-03 Celanese Emulsions Gmbh Coating compositions having high weathering resistance, process for preparation thereof and use thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3437920A1 (en) * 1984-10-17 1986-04-17 Basf Ag, 6700 Ludwigshafen Process for the preparation of vinyl propionate copolymer dispersions
DE8912391U1 (en) * 1989-09-14 1991-01-24 Kips, Ricus Cornelius Lawrence Flush-mounted box

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8993668B2 (en) 2007-07-19 2015-03-31 Celanese Emulsions Gmbh Polyvinyl ester dispersions, process for preparation thereof and use thereof
US9175185B2 (en) 2007-07-19 2015-11-03 Celanese Emulsions Gmbh Coating compositions having high weathering resistance, process for preparation thereof and use thereof

Also Published As

Publication number Publication date
FR2001486A1 (en) 1969-09-26
DE1905093A1 (en) 1969-08-28
FR2001486B1 (en) 1975-08-01

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee