GB1195428A - Production of Synthesis Gas by Catalytic Cracking of Hydrocarbons with Steam - Google Patents
Production of Synthesis Gas by Catalytic Cracking of Hydrocarbons with SteamInfo
- Publication number
- GB1195428A GB1195428A GB4999867A GB4999867A GB1195428A GB 1195428 A GB1195428 A GB 1195428A GB 4999867 A GB4999867 A GB 4999867A GB 4999867 A GB4999867 A GB 4999867A GB 1195428 A GB1195428 A GB 1195428A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- reactor
- stage
- steam
- synthesis gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1,195,428. Making combustible gas. BADISCHE ANILIN- & SODA-FABRIK A.G. 3 Nov., 1967 [4 Nov., 1966], No. 49998/67. Heading C5E. [Also in Division B1] Synthesis gas containing mainly H 2 and CO, with some CH 4 and C0 2 , is made by a two-stage catalytic cracking with steam of a hydrocarbon feedstock. The first stage, which produces a CH 4 -rich gas, is carried out in an unheated reactor at 350‹ to 550‹ C., and the second at 400‹ to 900‹ C. in an externally heated tubular reactor. Both stages employ Ni and/or Co catalysts. The internal surface area of the Ni or Co in the first catalyst is more than 20 sq.m./gram, preferably 30 to 300 sq.m/ gram, and the carrier is a precipitated oxide and/or silicate of Mg, Ca, Ba, Zn, Al and/or Ti. The catalyst at the inlet to the second stage contains a hydraulic binder, e.g. calcium aluminate, and the catalyst at the outlet to that stage may be the same as the first-stage catalyst. Feedstocks having 2 to 30 C atoms per molecule may be cracked, especially those having a B.R. of 30‹ to 200‹ C. The reactants are preheated, and if methanol synthesis gas is required, C0 2 may be added to the steam. Gas from the first reactor may be heated by heat exchange with flue gases from the second reactor, and the throughput of the first reactor is at least 2 kg of hydrocarbon per litre of catalyst per hour.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEB0089685 | 1966-11-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1195428A true GB1195428A (en) | 1970-06-17 |
Family
ID=6984884
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4999867A Expired GB1195428A (en) | 1966-11-04 | 1967-11-03 | Production of Synthesis Gas by Catalytic Cracking of Hydrocarbons with Steam |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE706032A (en) |
ES (1) | ES346776A1 (en) |
GB (1) | GB1195428A (en) |
NL (1) | NL6714992A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3828474A (en) * | 1973-02-01 | 1974-08-13 | Pullman Inc | Process for producing high strength reducing gas |
EP0279389A1 (en) * | 1987-02-18 | 1988-08-24 | Süd-Chemie Ag | Catalyst for the steam-reforming of hydrocarbons |
WO2009054830A1 (en) | 2007-10-25 | 2009-04-30 | Utc Power Corporation | Reduced generation of ammonia in nickel catalyst of reformer |
-
1967
- 1967-11-03 BE BE706032D patent/BE706032A/xx unknown
- 1967-11-03 GB GB4999867A patent/GB1195428A/en not_active Expired
- 1967-11-03 NL NL6714992A patent/NL6714992A/xx unknown
- 1967-11-04 ES ES346776A patent/ES346776A1/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3828474A (en) * | 1973-02-01 | 1974-08-13 | Pullman Inc | Process for producing high strength reducing gas |
EP0279389A1 (en) * | 1987-02-18 | 1988-08-24 | Süd-Chemie Ag | Catalyst for the steam-reforming of hydrocarbons |
WO2009054830A1 (en) | 2007-10-25 | 2009-04-30 | Utc Power Corporation | Reduced generation of ammonia in nickel catalyst of reformer |
EP2212959A1 (en) * | 2007-10-25 | 2010-08-04 | UTC Power Corporation, LLC | Reduced generation of ammonia in nickel catalyst of reformer |
EP2212959A4 (en) * | 2007-10-25 | 2012-01-25 | Utc Power Corp Llc | Reduced generation of ammonia in nickel catalyst of reformer |
Also Published As
Publication number | Publication date |
---|---|
BE706032A (en) | 1968-05-03 |
NL6714992A (en) | 1968-05-06 |
ES346776A1 (en) | 1969-01-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
CSNS | Application of which complete specification have been accepted and published, but patent is not sealed |