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GB1195428A - Production of Synthesis Gas by Catalytic Cracking of Hydrocarbons with Steam - Google Patents

Production of Synthesis Gas by Catalytic Cracking of Hydrocarbons with Steam

Info

Publication number
GB1195428A
GB1195428A GB4999867A GB4999867A GB1195428A GB 1195428 A GB1195428 A GB 1195428A GB 4999867 A GB4999867 A GB 4999867A GB 4999867 A GB4999867 A GB 4999867A GB 1195428 A GB1195428 A GB 1195428A
Authority
GB
United Kingdom
Prior art keywords
catalyst
reactor
stage
steam
synthesis gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4999867A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB1195428A publication Critical patent/GB1195428A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Multi-step processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1,195,428. Making combustible gas. BADISCHE ANILIN- & SODA-FABRIK A.G. 3 Nov., 1967 [4 Nov., 1966], No. 49998/67. Heading C5E. [Also in Division B1] Synthesis gas containing mainly H 2 and CO, with some CH 4 and C0 2 , is made by a two-stage catalytic cracking with steam of a hydrocarbon feedstock. The first stage, which produces a CH 4 -rich gas, is carried out in an unheated reactor at 350‹ to 550‹ C., and the second at 400‹ to 900‹ C. in an externally heated tubular reactor. Both stages employ Ni and/or Co catalysts. The internal surface area of the Ni or Co in the first catalyst is more than 20 sq.m./gram, preferably 30 to 300 sq.m/ gram, and the carrier is a precipitated oxide and/or silicate of Mg, Ca, Ba, Zn, Al and/or Ti. The catalyst at the inlet to the second stage contains a hydraulic binder, e.g. calcium aluminate, and the catalyst at the outlet to that stage may be the same as the first-stage catalyst. Feedstocks having 2 to 30 C atoms per molecule may be cracked, especially those having a B.R. of 30‹ to 200‹ C. The reactants are preheated, and if methanol synthesis gas is required, C0 2 may be added to the steam. Gas from the first reactor may be heated by heat exchange with flue gases from the second reactor, and the throughput of the first reactor is at least 2 kg of hydrocarbon per litre of catalyst per hour.
GB4999867A 1966-11-04 1967-11-03 Production of Synthesis Gas by Catalytic Cracking of Hydrocarbons with Steam Expired GB1195428A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB0089685 1966-11-04

Publications (1)

Publication Number Publication Date
GB1195428A true GB1195428A (en) 1970-06-17

Family

ID=6984884

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4999867A Expired GB1195428A (en) 1966-11-04 1967-11-03 Production of Synthesis Gas by Catalytic Cracking of Hydrocarbons with Steam

Country Status (4)

Country Link
BE (1) BE706032A (en)
ES (1) ES346776A1 (en)
GB (1) GB1195428A (en)
NL (1) NL6714992A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3828474A (en) * 1973-02-01 1974-08-13 Pullman Inc Process for producing high strength reducing gas
EP0279389A1 (en) * 1987-02-18 1988-08-24 Süd-Chemie Ag Catalyst for the steam-reforming of hydrocarbons
WO2009054830A1 (en) 2007-10-25 2009-04-30 Utc Power Corporation Reduced generation of ammonia in nickel catalyst of reformer

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3828474A (en) * 1973-02-01 1974-08-13 Pullman Inc Process for producing high strength reducing gas
EP0279389A1 (en) * 1987-02-18 1988-08-24 Süd-Chemie Ag Catalyst for the steam-reforming of hydrocarbons
WO2009054830A1 (en) 2007-10-25 2009-04-30 Utc Power Corporation Reduced generation of ammonia in nickel catalyst of reformer
EP2212959A1 (en) * 2007-10-25 2010-08-04 UTC Power Corporation, LLC Reduced generation of ammonia in nickel catalyst of reformer
EP2212959A4 (en) * 2007-10-25 2012-01-25 Utc Power Corp Llc Reduced generation of ammonia in nickel catalyst of reformer

Also Published As

Publication number Publication date
BE706032A (en) 1968-05-03
NL6714992A (en) 1968-05-06
ES346776A1 (en) 1969-01-01

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Legal Events

Date Code Title Description
CSNS Application of which complete specification have been accepted and published, but patent is not sealed