GB1184166A - Treatment of Color-Degradable Sour Hydrocarbon Distillates - Google Patents
Treatment of Color-Degradable Sour Hydrocarbon DistillatesInfo
- Publication number
- GB1184166A GB1184166A GB08073/68A GB1807368A GB1184166A GB 1184166 A GB1184166 A GB 1184166A GB 08073/68 A GB08073/68 A GB 08073/68A GB 1807368 A GB1807368 A GB 1807368A GB 1184166 A GB1184166 A GB 1184166A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkaline reagent
- oils
- oxygen
- feed
- hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 4
- 229930195733 hydrocarbon Natural products 0.000 title abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 4
- 239000003153 chemical reaction reagent Substances 0.000 abstract 4
- 239000001301 oxygen Substances 0.000 abstract 4
- 229910052760 oxygen Inorganic materials 0.000 abstract 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract 2
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 abstract 2
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- PYPQFOINVKFSJD-UHFFFAOYSA-N S[S] Chemical class S[S] PYPQFOINVKFSJD-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000002283 diesel fuel Substances 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000000295 fuel oil Substances 0.000 abstract 1
- 239000010687 lubricating oil Substances 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- -1 mercapto compounds Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000005608 naphthenic acid group Chemical group 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000010742 number 1 fuel oil Substances 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- TWEGKFXBDXYJIU-UHFFFAOYSA-M sodium;2-methylpropanoate Chemical compound [Na+].CC(C)C([O-])=O TWEGKFXBDXYJIU-UHFFFAOYSA-M 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/06—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
1,184,166. Sweetening hydrocarbon distillates. UNIVERSAL OIL PRODUCTS CO. 17 April, 1968 [20 April, 1967], No. 18073/68. Heading C5E, Mercapto sulphur compounds contained in a hydrocarbon distillate are oxidized in the presence of an alkaline reagent, a phthalocyanine catalyst and oxygen in an amount of less than 1'4 times that stoichiometrically necessary to oxidize all the mercapto compounds to the corresponding disulphides. The distillates treated are kerosenes, stove oils, furnace oils, solvent oils, diesel fuels, lubricating oils, jet fuels, straight-run gasolines, cracked gasolines and heavy naphthas. Naphthenic acids and hydrogen sulphide can be washed from the feed with dilute caustic solution. The catalyst comprises either 0À005-10 wt. per cent of a phthalocyanine of Co, Va, Fe, Cu, Ni or Cr on a carrier of activated charcoal, coke, silica, alumina or magnesia or an aqueous solution of the sulphonated or carboxylated derivatives of these metal phthalocyanines. The alkaline reagent generally comprises an aqueous solution of 1- 50 wt. per cent of caustic soda, caustic potash, lithium hydroxide, rubidium hydroxide or cesium hydroxide but alcoholicalkalicanbeused.Sodium isobutyrate, ammonium hydroxide or dimethylsulphoxidemay be included in the alkaline reagent as a solutizer. The oxygen content can be controlled by removing excess dissolved or entrained oxygen from the distillate feed with nitrogen or by adding oxygen as air or dissolved in the hydrocarbon feed or alkaline reagent. The reaction is carried out at up to 204 C. and 0 68 to 10.2 atm. gauge.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63220367A | 1967-04-20 | 1967-04-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1184166A true GB1184166A (en) | 1970-03-11 |
Family
ID=24534514
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08073/68A Expired GB1184166A (en) | 1967-04-20 | 1968-04-17 | Treatment of Color-Degradable Sour Hydrocarbon Distillates |
Country Status (12)
| Country | Link |
|---|---|
| AT (1) | AT286475B (en) |
| BE (1) | BE713904A (en) |
| CH (1) | CH524679A (en) |
| DE (1) | DE1770224C3 (en) |
| DK (1) | DK131475B (en) |
| ES (1) | ES352913A1 (en) |
| FR (1) | FR1564185A (en) |
| GB (1) | GB1184166A (en) |
| IL (1) | IL29827A (en) |
| NL (1) | NL6805604A (en) |
| NO (1) | NO119286B (en) |
| SE (1) | SE346804B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019093890A1 (en) * | 2017-11-10 | 2019-05-16 | Wrt B.V. | Process for preparing a sweetened hydrocarbon liquid composition with reduced tendency to form gums, a scavenger composition for use in said process, and the sweetened hydrocarbon liquid composition with reduced tendency to form gums so prepared |
| NL2019890B1 (en) * | 2017-11-10 | 2019-05-17 | Wrt B V | Process for preparing a sweetened hydrocarbon liquid composition with reduced tendency to form gums, a scavenger composition for use in said process, and the sweetened hydrocarbon liquid composition with reduced tendency to form gums so prepared. |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4003827A (en) * | 1975-06-12 | 1977-01-18 | Universal Oil Products Company | Mercaptan conversion process for a petroleum distillate charge stock |
-
1968
- 1968-04-16 IL IL29827A patent/IL29827A/en unknown
- 1968-04-17 GB GB08073/68A patent/GB1184166A/en not_active Expired
- 1968-04-18 AT AT380768A patent/AT286475B/en not_active IP Right Cessation
- 1968-04-18 DE DE1770224A patent/DE1770224C3/en not_active Expired
- 1968-04-19 BE BE713904D patent/BE713904A/xx unknown
- 1968-04-19 CH CH581468A patent/CH524679A/en not_active IP Right Cessation
- 1968-04-19 FR FR1564185D patent/FR1564185A/fr not_active Expired
- 1968-04-19 SE SE05285/68A patent/SE346804B/xx unknown
- 1968-04-19 NO NO1481/68A patent/NO119286B/no unknown
- 1968-04-19 NL NL6805604A patent/NL6805604A/xx unknown
- 1968-04-19 DK DK176868AA patent/DK131475B/en unknown
- 1968-04-19 ES ES352913A patent/ES352913A1/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019093890A1 (en) * | 2017-11-10 | 2019-05-16 | Wrt B.V. | Process for preparing a sweetened hydrocarbon liquid composition with reduced tendency to form gums, a scavenger composition for use in said process, and the sweetened hydrocarbon liquid composition with reduced tendency to form gums so prepared |
| NL2019890B1 (en) * | 2017-11-10 | 2019-05-17 | Wrt B V | Process for preparing a sweetened hydrocarbon liquid composition with reduced tendency to form gums, a scavenger composition for use in said process, and the sweetened hydrocarbon liquid composition with reduced tendency to form gums so prepared. |
Also Published As
| Publication number | Publication date |
|---|---|
| DK131475C (en) | 1975-12-08 |
| SE346804B (en) | 1972-07-17 |
| IL29827A0 (en) | 1968-06-20 |
| DE1770224B2 (en) | 1974-07-11 |
| ES352913A1 (en) | 1969-10-01 |
| NO119286B (en) | 1970-04-27 |
| FR1564185A (en) | 1969-04-18 |
| NL6805604A (en) | 1968-10-21 |
| CH524679A (en) | 1972-06-30 |
| DE1770224A1 (en) | 1971-10-07 |
| DK131475B (en) | 1975-07-21 |
| DE1770224C3 (en) | 1975-03-13 |
| BE713904A (en) | 1968-09-16 |
| IL29827A (en) | 1972-02-29 |
| AT286475B (en) | 1970-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3164545A (en) | Desulfurization process | |
| US4062762A (en) | Process for desulfurizing and blending naphtha | |
| Byrns et al. | Catalytic desulfurization of gasolines by cobalt molybdate process | |
| GB1386129A (en) | Desulphurization process | |
| US3708421A (en) | Process to remove mercaptan sulfur from sour oils | |
| US2432301A (en) | Conversion of hydrosulfides to neutral sulfur compounds | |
| US2472473A (en) | Conversion of hydrosulfides to neutral sulfur substances | |
| US3383304A (en) | Alkali-desulfurization process | |
| US3413307A (en) | Desulfurization process | |
| GB1184166A (en) | Treatment of Color-Degradable Sour Hydrocarbon Distillates | |
| US2575989A (en) | Treatment of petroleum distillates | |
| US2543953A (en) | Sweetening hydrocarbon mixtures | |
| US2560374A (en) | Treatment of sour petroleum distillates | |
| US2556836A (en) | Method of treating sour petroleum distillates | |
| US3162598A (en) | Removing nitrogen compounds by oxidation | |
| US3244618A (en) | Sweetening process using nitrogen oxide catalyst | |
| US3449239A (en) | Diazine in a hydrocarbon sweetening process | |
| US2872412A (en) | Process for the finish sweetening of mercaptan-containing petroleum hydrocarbons with air and caustic alkali treated charcoal | |
| GB1509003A (en) | Desulphurisation catalysts | |
| US2455061A (en) | Treatment of liquid hydrocarbons | |
| US2769759A (en) | Production of non-corrosive naphthas by reacting refined naphtha with molybdate | |
| US4018705A (en) | Reactivation of a spent liquid phthalocyanine catalytic composite | |
| US2037791A (en) | Treatment of hydrocarbon oils | |
| US3398086A (en) | Process for treating hydrocarbon distillates containing mercaptan and color-forming components | |
| US3141842A (en) | Sweetening of sour hydrocarbons with transition metal compounds |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |