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GB1158718A - Process for the Manufacture of Modified Polymers of Fatty Acids - Google Patents

Process for the Manufacture of Modified Polymers of Fatty Acids

Info

Publication number
GB1158718A
GB1158718A GB51290/66A GB5129066A GB1158718A GB 1158718 A GB1158718 A GB 1158718A GB 51290/66 A GB51290/66 A GB 51290/66A GB 5129066 A GB5129066 A GB 5129066A GB 1158718 A GB1158718 A GB 1158718A
Authority
GB
United Kingdom
Prior art keywords
reacted
copolymer
styrene
esterified
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB51290/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JAEGER FABRIK CHEM ERNST
Original Assignee
JAEGER FABRIK CHEM ERNST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JAEGER FABRIK CHEM ERNST filed Critical JAEGER FABRIK CHEM ERNST
Publication of GB1158718A publication Critical patent/GB1158718A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
    • C08G18/4233—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups derived from polymerised higher fatty acids or alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/627—Polymers of hydroxylated esters of unsaturated higher fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
    • C08G63/42—Cyclic ethers; Cyclic carbonates; Cyclic sulfites; Cyclic orthoesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

1,158,718. Modified fatty acid copolymers. ERNST J€GER FABRIK CHEM. ROHSTOFFE G.m.b.H. 16 Nov., 1966 [16 Nov., 1965], No. 51290/66. Heading C3P. A copolymer of an unsaturated fatty acid derived from a drying or semi-drying oil and a vinyl or vinylidene monomer is reacted with a monoepoxy compound having a molecular weight of more than 70 in an amount such that the free carboxyl groups in the polymer are partially or fully reacted with the epoxy groups. Specified acids are those obtained from natural oils e.g. linseed, soya, safflower, wood, fish, castor and tall oils. The comonomer may be styrene, vinyl toluene, methyl styrene, divinyl benzene or (meth)acrylic acid and its derivatives. The monoepoxy compound is e.g. cyclohexene oxide, styrene oxide, a glycidyl ester or ether or epichlorohydrin The hydroxyl groups produced on reaction with the epoxy group may be esterified by carboxyl groups remaining in the copolymer or present in additional compounds. In Example I an oleic acid/linoleic acid mixture is copolymerized with styrene and acrylic acid using benzoyl peroxide as catalyst. The copolymer produced is reacted with 1-n-butoxy-2, 3-epoxypropane and may be reacted subsequently with a polyisocyanate to yield a polyurethane. The epoxy compound used in Example II is cyclohexene oxide and the esterified copolymer is post-esterified and also, if desired, cured by heating. In Example III, castor oil fatty acid is copolymerized with methacrylic acid and vinyl toluene, the copolymer produced being reacted with epichlorhydrin.
GB51290/66A 1965-11-16 1966-11-16 Process for the Manufacture of Modified Polymers of Fatty Acids Expired GB1158718A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEJ0029402 1965-11-16

Publications (1)

Publication Number Publication Date
GB1158718A true GB1158718A (en) 1969-07-16

Family

ID=7203599

Family Applications (1)

Application Number Title Priority Date Filing Date
GB51290/66A Expired GB1158718A (en) 1965-11-16 1966-11-16 Process for the Manufacture of Modified Polymers of Fatty Acids

Country Status (5)

Country Link
BE (1) BE689770A (en)
DE (1) DE1570825B2 (en)
FR (1) FR1505634A (en)
GB (1) GB1158718A (en)
NL (1) NL149510B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009007296A1 (en) * 2007-07-12 2009-01-15 Cytec Surface Specialties, S.A. Acrylated natural oil compositions
EP2113010A1 (en) * 2007-02-22 2009-11-04 M-Il.L.C., Hydroxy polyesters and uses as demulsifiers
CN112745455A (en) * 2020-12-25 2021-05-04 广东科德环保科技股份有限公司 Oleic acid copolymer dispersion resin and preparation method and application thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2113010A1 (en) * 2007-02-22 2009-11-04 M-Il.L.C., Hydroxy polyesters and uses as demulsifiers
EP2113010A4 (en) * 2007-02-22 2012-05-23 Mi Llc Hydroxy polyesters and uses as demulsifiers
WO2009007296A1 (en) * 2007-07-12 2009-01-15 Cytec Surface Specialties, S.A. Acrylated natural oil compositions
US8524354B2 (en) 2007-07-12 2013-09-03 Cytec Surface Specialties S.A. Acrylated natural oil compositions
US8802222B2 (en) 2007-07-12 2014-08-12 Allnex Belgium S.A. Acrylated natural oil compositions
CN112745455A (en) * 2020-12-25 2021-05-04 广东科德环保科技股份有限公司 Oleic acid copolymer dispersion resin and preparation method and application thereof
CN112745455B (en) * 2020-12-25 2022-11-08 广东科德环保科技股份有限公司 Oleic acid copolymer dispersion resin and preparation method and application thereof

Also Published As

Publication number Publication date
FR1505634A (en) 1967-12-15
BE689770A (en) 1967-05-02
NL149510B (en) 1976-05-17
DE1570825B2 (en) 1973-10-04
NL6616153A (en) 1967-05-17
DE1570825A1 (en) 1970-03-12

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Legal Events

Date Code Title Description
PS Patent sealed
PE Patent expired