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GB1146582A - Polymerisation of ethylenically unsaturated monomers - Google Patents

Polymerisation of ethylenically unsaturated monomers

Info

Publication number
GB1146582A
GB1146582A GB4525266A GB4525266A GB1146582A GB 1146582 A GB1146582 A GB 1146582A GB 4525266 A GB4525266 A GB 4525266A GB 4525266 A GB4525266 A GB 4525266A GB 1146582 A GB1146582 A GB 1146582A
Authority
GB
United Kingdom
Prior art keywords
copolymer
mixture
acid
ethylenically unsaturated
unsaturated monomers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4525266A
Inventor
Peter Vernon Robinson
Peter Earnshaw
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Styrene Co Polymers Ltd
Original Assignee
Styrene Co Polymers Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Styrene Co Polymers Ltd filed Critical Styrene Co Polymers Ltd
Priority to GB4525266A priority Critical patent/GB1146582A/en
Publication of GB1146582A publication Critical patent/GB1146582A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04Acids; Metal salts or ammonium salts thereof
    • C08F220/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,146,582. Polymerizing a mixture of ethylenically unsaturated monomers. STYRENE COPOLYMERS Ltd. 20 Sept., 1967 [10 Oct., 1966], No. 45252/66. Headings C3P and C3R. A copolymer is produced by polymerizing in solution a mixture of ethylenically unsaturated monomers of which one or more is an acid which contains a free carboxyl group and another or others of which is an alkyl ester of acrylic or methacrylic acid in the presence of a polymerization initiator and a mercapto-alkanol, the amounts of the acid and mercapto-alkanol being such that the copolymer has an acid value of 25-30 mgm. KOH/gm. copolymer and a hydroxyl value of 20-40 mgm. KOH/gm. copolymer. In the example a mixture of styrene, itaconic acid, methyl methacrylate and ethyl acrylate was polymerized in a mixture of xylene and n-butanol with 2-mercapto-ethanol and cumene hydroperoxide: the copolymer solution was mixed with a butylated melamineformaldehyde resin to form a coating composition.
GB4525266A 1966-10-10 1966-10-10 Polymerisation of ethylenically unsaturated monomers Expired GB1146582A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB4525266A GB1146582A (en) 1966-10-10 1966-10-10 Polymerisation of ethylenically unsaturated monomers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4525266A GB1146582A (en) 1966-10-10 1966-10-10 Polymerisation of ethylenically unsaturated monomers

Publications (1)

Publication Number Publication Date
GB1146582A true GB1146582A (en) 1969-03-26

Family

ID=10436490

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4525266A Expired GB1146582A (en) 1966-10-10 1966-10-10 Polymerisation of ethylenically unsaturated monomers

Country Status (1)

Country Link
GB (1) GB1146582A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0071116A1 (en) * 1981-07-30 1983-02-09 S.C. Johnson & Son, Inc. Suspension polymerization with cosolvent partitioning
EP0320594A2 (en) * 1987-12-14 1989-06-21 Nippon Shokubai Co., Ltd. Aqeous crosslinkable resin dispersions, method of their production and use thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0071116A1 (en) * 1981-07-30 1983-02-09 S.C. Johnson & Son, Inc. Suspension polymerization with cosolvent partitioning
EP0320594A2 (en) * 1987-12-14 1989-06-21 Nippon Shokubai Co., Ltd. Aqeous crosslinkable resin dispersions, method of their production and use thereof
EP0320594A3 (en) * 1987-12-14 1990-06-06 Nippon Shokubai Kagaku Kogyo Co., Ltd Aqeous crosslinkable resin dispersions, method of their production and use thereof
US5284900A (en) * 1987-12-14 1994-02-08 Nippon Shokubai Co., Ltd. Aqueous crosslinkable resin dispersions, method of their production and use thereof

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