GB1146582A - Polymerisation of ethylenically unsaturated monomers - Google Patents
Polymerisation of ethylenically unsaturated monomersInfo
- Publication number
- GB1146582A GB1146582A GB4525266A GB4525266A GB1146582A GB 1146582 A GB1146582 A GB 1146582A GB 4525266 A GB4525266 A GB 4525266A GB 4525266 A GB4525266 A GB 4525266A GB 1146582 A GB1146582 A GB 1146582A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymer
- mixture
- acid
- ethylenically unsaturated
- unsaturated monomers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1,146,582. Polymerizing a mixture of ethylenically unsaturated monomers. STYRENE COPOLYMERS Ltd. 20 Sept., 1967 [10 Oct., 1966], No. 45252/66. Headings C3P and C3R. A copolymer is produced by polymerizing in solution a mixture of ethylenically unsaturated monomers of which one or more is an acid which contains a free carboxyl group and another or others of which is an alkyl ester of acrylic or methacrylic acid in the presence of a polymerization initiator and a mercapto-alkanol, the amounts of the acid and mercapto-alkanol being such that the copolymer has an acid value of 25-30 mgm. KOH/gm. copolymer and a hydroxyl value of 20-40 mgm. KOH/gm. copolymer. In the example a mixture of styrene, itaconic acid, methyl methacrylate and ethyl acrylate was polymerized in a mixture of xylene and n-butanol with 2-mercapto-ethanol and cumene hydroperoxide: the copolymer solution was mixed with a butylated melamineformaldehyde resin to form a coating composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4525266A GB1146582A (en) | 1966-10-10 | 1966-10-10 | Polymerisation of ethylenically unsaturated monomers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4525266A GB1146582A (en) | 1966-10-10 | 1966-10-10 | Polymerisation of ethylenically unsaturated monomers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1146582A true GB1146582A (en) | 1969-03-26 |
Family
ID=10436490
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4525266A Expired GB1146582A (en) | 1966-10-10 | 1966-10-10 | Polymerisation of ethylenically unsaturated monomers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1146582A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0071116A1 (en) * | 1981-07-30 | 1983-02-09 | S.C. Johnson & Son, Inc. | Suspension polymerization with cosolvent partitioning |
EP0320594A2 (en) * | 1987-12-14 | 1989-06-21 | Nippon Shokubai Co., Ltd. | Aqeous crosslinkable resin dispersions, method of their production and use thereof |
-
1966
- 1966-10-10 GB GB4525266A patent/GB1146582A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0071116A1 (en) * | 1981-07-30 | 1983-02-09 | S.C. Johnson & Son, Inc. | Suspension polymerization with cosolvent partitioning |
EP0320594A2 (en) * | 1987-12-14 | 1989-06-21 | Nippon Shokubai Co., Ltd. | Aqeous crosslinkable resin dispersions, method of their production and use thereof |
EP0320594A3 (en) * | 1987-12-14 | 1990-06-06 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Aqeous crosslinkable resin dispersions, method of their production and use thereof |
US5284900A (en) * | 1987-12-14 | 1994-02-08 | Nippon Shokubai Co., Ltd. | Aqueous crosslinkable resin dispersions, method of their production and use thereof |
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