GB1130846A - Process for the production of oxazole - Google Patents
Process for the production of oxazoleInfo
- Publication number
- GB1130846A GB1130846A GB2080166A GB2080166A GB1130846A GB 1130846 A GB1130846 A GB 1130846A GB 2080166 A GB2080166 A GB 2080166A GB 2080166 A GB2080166 A GB 2080166A GB 1130846 A GB1130846 A GB 1130846A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxazole
- acrolein
- acrylonitrile
- acetonitrile
- products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 title abstract 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 6
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- 239000006227 byproduct Substances 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004508 fractional distillation Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 238000000638 solvent extraction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
- C07D263/30—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D263/32—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
1,130,846. Oxazole; acrylonitrile and acetonitrile; acrolein. BP CHEMICALS (U.K.) Ltd. 21 April, 1967 [11 May, 1966], No. 20801/66. Heading C2C. Oxazole and by-products acrylonitrile, acetonitrile and acrolein are produced by reacting at elevated temperatures in the vapour phase propylene with O 2 and NH 3 over an oxidation catalyst, the proportion of propylene in the feed being at least 4% by volume, the concentration of NH 3 being at least 4% by volume and the molar ratio of O 2 to olefine being at least 2. The oxazole can be separated from the by-products by fractional distillation, solvent extraction or hydroextraction.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2080166A GB1130846A (en) | 1966-05-11 | 1966-05-11 | Process for the production of oxazole |
DE19671670219 DE1670219A1 (en) | 1966-05-11 | 1967-04-28 | Process for the preparation of oxazole |
FR1557636D FR1557636A (en) | 1966-05-11 | 1967-05-11 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2080166A GB1130846A (en) | 1966-05-11 | 1966-05-11 | Process for the production of oxazole |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1130846A true GB1130846A (en) | 1968-10-16 |
Family
ID=10151903
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2080166A Expired GB1130846A (en) | 1966-05-11 | 1966-05-11 | Process for the production of oxazole |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1670219A1 (en) |
FR (1) | FR1557636A (en) |
GB (1) | GB1130846A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4208329A (en) * | 1978-07-31 | 1980-06-17 | E. I. Du Pont De Nemours & Co. | Oxazole removed from acrylonitrile as oxazole sulfate |
WO2004063176A1 (en) * | 2003-01-07 | 2004-07-29 | The Standard Oil Company | Process for the recovery of oxazole |
-
1966
- 1966-05-11 GB GB2080166A patent/GB1130846A/en not_active Expired
-
1967
- 1967-04-28 DE DE19671670219 patent/DE1670219A1/en active Pending
- 1967-05-11 FR FR1557636D patent/FR1557636A/fr not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4208329A (en) * | 1978-07-31 | 1980-06-17 | E. I. Du Pont De Nemours & Co. | Oxazole removed from acrylonitrile as oxazole sulfate |
WO2004063176A1 (en) * | 2003-01-07 | 2004-07-29 | The Standard Oil Company | Process for the recovery of oxazole |
US7211674B2 (en) | 2003-01-07 | 2007-05-01 | Ineos Usa Llc | Process for the recovery of oxazole |
EA009046B1 (en) * | 2003-01-07 | 2007-10-26 | ИНЕОС ЮЭсЭй ЭлЭлСи | Process for the recovery of oxazole |
Also Published As
Publication number | Publication date |
---|---|
FR1557636A (en) | 1969-02-21 |
DE1670219A1 (en) | 1970-08-13 |
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