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GB1125730A - Process for the production of glycol hemiethers - Google Patents

Process for the production of glycol hemiethers

Info

Publication number
GB1125730A
GB1125730A GB182166A GB182166A GB1125730A GB 1125730 A GB1125730 A GB 1125730A GB 182166 A GB182166 A GB 182166A GB 182166 A GB182166 A GB 182166A GB 1125730 A GB1125730 A GB 1125730A
Authority
GB
United Kingdom
Prior art keywords
hydroxyethoxy
hemiethers
glycol
hydrogen
jan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB182166A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Huels AG filed Critical Chemische Werke Huels AG
Publication of GB1125730A publication Critical patent/GB1125730A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/13—Saturated ethers containing hydroxy or O-metal groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,125,730. Glycol hemiethers. CHEMISCHE WERKE HULS A.G. 14 Jan., 1966 [15 Jan., 1965], No. 1821/66. Heading C2C. Glycol hemiethers having the formula and/or are prepared by hydrogenating in the presence of a hydrogenation catalyst containing copper, nickel or cobalt, or an oxide or chromite thereof a dioxolane derivative of formula where each of R<SP>1</SP> to R<SP>6</SP> denotes a hydrogen atom or an alkyl, cycloalkyl, aryl or aralkyl group or two of the alkyl groups bound to the same carbon atom are joined to form a cycloalkane group. Preferred hemiethers are those in which R<SP>1</SP> and R<SP>2</SP> are n-alkyl groups of eight to fifteen carbon atoms and R<SP>3</SP> to R<SP>6</SP> are hydrogen. The preferred catalyst is a copper-chromium oxide catalyst. The catalysts may be supported, e.g. on alumina or silica. The process is preferably carried out at 50‹ to 350‹ C. and at a hydrogen pressure of 20 to 350 atmospheres. Examples describe the preparation of 2-(#-hydroxyethoxy) - n - tetradecane, 3 - (# - hydroxyethoxy) - n - undecane, 1 - (# - hydroxyethoxy)- n - hexane, # - hydroxyethyl benzyl ether, 2 - (# - hydroxyethoxy) - n - butane, 2 - (α- methyl - # - hydroxyethoxy) - n - propane, #- hydroxydimethyldiphenylethylcyclohexyl ether and # - - hydroxyethoxycyclohexane. Tetradecanol-(2), undecanol-(3) and n-hexanol are obtained as side products and may be reconverted to the starting products by dehydrogenation.
GB182166A 1965-01-15 1966-01-14 Process for the production of glycol hemiethers Expired GB1125730A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC0034862 1965-01-15

Publications (1)

Publication Number Publication Date
GB1125730A true GB1125730A (en) 1968-08-28

Family

ID=7021527

Family Applications (1)

Application Number Title Priority Date Filing Date
GB182166A Expired GB1125730A (en) 1965-01-15 1966-01-14 Process for the production of glycol hemiethers

Country Status (3)

Country Link
BE (1) BE675033A (en)
FR (1) FR1462916A (en)
GB (1) GB1125730A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8829229B2 (en) 2008-08-25 2014-09-09 Dow Global Technologies Llc Polyol ethers and process for making them

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU70720A1 (en) * 1974-08-12 1976-08-19
FR2525211A1 (en) * 1982-04-20 1983-10-21 Ugine Kuhlmann PROCESS FOR THE PRODUCTION OF MONOETHYLENEGLYCOL MONO-ETHER BY HYDROGENOLYSIS OF CYCLIC ACETALS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8829229B2 (en) 2008-08-25 2014-09-09 Dow Global Technologies Llc Polyol ethers and process for making them

Also Published As

Publication number Publication date
BE675033A (en) 1966-05-16
FR1462916A (en) 1966-12-16

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